High‐Precision Measurement of 187Os/188Os Isotope Ratios of Nanogram to Picogram Amounts of Os in Geological Samples by N‐TIMS using Faraday Cups Equipped with 1013 Ω Amplifiers

N(¹⁸⁷Os)/N(¹⁸⁸Os) ratios of six geological reference materials were measured using static Faraday cups (FCs) with 10¹³ Ω amplifiers by N‐TIMS. Our results show that the repeatability precision was 2–3‰ (2 RSD, n = 3), when taking ~ 1 g of BHVO‐2 with 76 pg g^?1 of Os mass fraction and ~ 2 g of BCR‐2 with 21 pg g^?1 of Os mass fraction for each sample, whether measured by FCs or by secondary electron multiplier. The repeatability precision measured by FCs was 1–0.2‰ (2 RSD, n = 3) when taking ~ 1 g of BIR‐2 with 350 pg g^?1 of Os mass fraction, ~ 1 g of WGB‐1 with 493 pg g^?1 of Os mass fraction or ~ 0.5 g of WPR‐1 with 13.3 ng g^?1 of Os mass fraction for each sample, which is much better than those measured by secondary electron multiplier. Instead, when taking ~ 2 g of AGV‐2 with 4 pg g^?1 Os mass fraction, the repeatability precision measured by secondary electron multiplier is 3–4‰ (RSD, n = 3), which is better than those measured by FCs. Of the six reference materials analysed, WPR‐1 and BIR‐1a are the most homogeneous with regard to Os isotopic composition (2 RSD of 0.08% and 0.23%, respectively) when test portion masses are 0.5–1 g.     

Determination of trace and rare-earth elements in Chinese soil and clay reference materials by ICP-MS

Inductively coupled plasma mass spectrometry(ICP-MS) has become a powerful tool for providing reliable analytical results in many laboratories around the word. In this study, the mixture of HF and HNO3 acids in high-temperature and high-pressure closed-vessel digestion technique were used to decompose some Chinese reference materials, and thirty seven elements were determined by ICP-MS. Most of the results for Chinese soil reference materials were found to be in reasonable agreement with the reference values, except Cs, Ta, Li, Ge, Zn, Nd, Tb and Ta whose values need to be revised. Their precisions were typically lower than 5% RSD. However, the Precisions of Chinese clay reference materials, especially for GBW03102 and GBW03102a, were significantly different with reference values, probably reflecting the existence of a coarser-grained fraction(70 μm) in samples, and the formation of fluorides in Al-rich samples during sample decomposition by using the mixture of HF and HNO3 acids. Moreover, thirty-seven trace elements covering the mass range from Li to U in four Chinese clay reference materials were firstly provided with good precision and accuracy in this study.     

Calcium,Na, K and Mg Concentrations in Seawater by Inductively Coupled Plasma‐Atomic Emission Spectrometry: Applications to IAPSO Seawater Reference Material,Hydrothermal Fluids and Synthetic Seawater Solutions

We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q^® water. We obtained an average reference value r_K (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg^?1)/(g kg^?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to r_Na, r_Ca and r_Mg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids.     

Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.     

Ultra-rapid landscape response and sediment yield following glacier retreat, Icy Bay, southern Alaska

The páramo is a neotropical alpine ecosystem that covers more than 75,000 km² of the northern Andes of Colombia, Ecuador, Venezuela, and Peru. It provides important environmental services: more than 10 million people in the Andean highlands benefit from the water supply and regulation function, which is attributed to the volcanic soils that underlie the ecosystem. The soils are also major carbon sinks of global significance. Severe land use changes and soil degradation threaten both the hydrology and carbon sink function. Nevertheless, soil genesis and properties in the páramo is rather poorly understood, nor are their ecological functions well documented. The impact of the geomorphology of the páramo on soil genesis was studied in the rio Paute basin, south Ecuador. Two toposequences were described and analysed. In each toposequence, four pedons were selected representing summit, backslope, undrained plain situation, and valley bottom positions in the landscape. The soils are classified as Hydric Andosols in the World Reference Base for Soil Resources and Epiaquands or Hydrudands in Soil Taxonomy. They are very acidic and have a high organic matter content, high P deficiency, and Al toxicity. Their water content ranges from 2.64 g g^− 1 at saturation, down to 1.24 g g^− 1 at wilting point, resulting in a large water storage capacity. Two major soil forming processes are identified: (1) volcanic ash deposition and (2) accumulation of organic carbon. Volcanic ash deposits may vary in depth as a result of regional geomorphological factors such as parent material, orientation, slope, and altitude. Organic carbon accumulation is an interaction of both waterlogging, which depends on the position in the landscape, and the formation of organometallic complexes with Al and Fe released during volcanic ash breakdown. Despite the high variability in parent material and topography, the soil is characterised by a notable homogeneity in physico-chemical properties. Statistical analysis reveals that only topographic location has a slight but significant influence on soil pH as well as the organic matter content, saturated conductivity and water retention at high pressure. Finally, the exceptional properties of these soils provide useful insights to improve classification of the Andosols reference group of the FAO World reference Base for Soil Resources.     

现今绝对板块运动

根据热点假设,热点对于中间层是固定的.相对热点的板块运动叫做绝对板块运动.绝对板块运动模型可以通过反演火山链传播的速率和走向数据以确定相对板块运动在角速度空间的原点来得到.利用一组近来(0～7.8 Ma)全球分布的热点的迁移速率和走向数据,结合板块运动模型NNR-NUVEL1A,已研制出一个叫做APM2的现今绝对板块运动模型.按照该模型,太平洋板块围绕60.063°S、102.210°E处的极以(0.833 0°±0.013 3°)/Ma的速率运动,非洲板块围绕46.849°N、44.372°W的极以(0.101 5°±0.013 4°)/Ma的速率运动,南极板块的运动则以46.871°N、146.942°E为极,速率为(0.084 6°±0.017 7°)/Ma,欧亚板块的运动更慢,极为27.291°N、171.925°W,速率为(0.065 5°±0.020 6°)/Ma.这一模型表明,岩石圈相对深部地幔有一个以49.423°S、90.625°E为极,速率为(0.198 3°±0.013 5°)/Ma的净旋转.表明太平洋热点同印度-大西洋热点不一致,显示太平洋热点的运动也不一致.为了分析和比较,还给出了仅用全球分布的热点的走向数据和仅用印度-大西洋热点的走向数据得到的板块绝对运动的角速度.     

我院教师文献信息需求调查与分析

作者对该院教师的文献信息使用及需求情况进行了９个方面的调查分析，其结果对学校教学科研的改革和深化具有现实的参考意义。     

浙江省地质遗迹保护工作现状与面临的任务

本文以浙江省地质遗迹的展布特点 ,根据目前地质遗迹保护工作现状和存在的主要问题 ,提出了我省地质遗迹保护工作的任务与拟建地质遗迹保护区参考名录     

柴油机轴承设计、使用和维修的几个问题

在保证轴承安全而经济的运转条件下,轴承装配间隙取最小值,根据流体润滑理论,选择合适的润滑油;对于厚壁轴瓦,在磨合之后应调整到运转间隙。这样就可以充分利用轴承的使用寿命。     

农业资源信息标准参考模型研究

为满足全社会对农业资源信息共享的迫切需求,使农业资源信息标准化的工作在统一的框架下进行,借鉴国际地理信息标准制定的思路,初步提出了农业资源信息标准化的技术框架--农业资源信息标准参考模型。该标准参考模型是由指导标准、通用标准、专用标准和领域标准等三个部分组成。本文重点阐述了5个指导标准、4类通用标准的标准组成和要点,提出依据基础标准制定专用标准作为农业资源信息较低层次标准制定的重要原则与方法。农业资源信息标准参考模型对于以信息的积累与服务为主的行业信息标准化具有普遍的指导意义。