Factors influencing the oxidation,reduction, methylation and demethylation of mercury species in coastal waters

The objective of this study was to examine the redox reactions and other transformations of mercury (Hg) species in surface waters, and the factors determining the rates of these reactions. For the redox studies completed at the Chesapeake Biological Laboratory (CBL), two isotopes (¹⁹⁹Hg^II and ²⁰²Hg⁰) were added into different types of filtered water (fresh to seawater) to examine the oxidation and reduction reactions. Further studies of both the redox reactions and methylation/demethylation reactions of Hg were conducted with unfiltered water on board research vessels during cruises in May and July 2005 on the Chesapeake Bay and shelf. While CH₃¹⁹⁹Hg^II was added to allow the examination of demethylation, ²⁰¹Hg^II was used to examine both reduction and methylation, and ²⁰²Hg⁰ was used to examine oxidation. Overall, the results showed that both Hg oxidation and reduction were simultaneously occurring and were photochemically mediated in the waters investigated. In contrast to the previously assumed “unreactive” nature of Hg⁰, the studies found that the magnitude of the rate constant for Hg⁰ oxidation was greater than that for reduction, indicating its importance in estuarine and coastal waters. In addition, both experiments at CBL and on board ship showed that Hg^II reduction was similar in magnitude, suggesting that biotic processes were relatively unimportant. While no measurable methylation occurred during the incubation period during the on board studies, concentration of CH₃¹⁹⁹Hg^II decreased over the time during the experiments. It appeared that the demethylation processes were not dominantly photochemically driven, but could be microbially mediated. Further studies are needed in order to help better understand Hg redox and transformations in natural water systems.     

福建闽江口外海岸植物生态

记录了福建闽江口266种海岸高等植物,其中草本占70.2%、灌木占21.4%、藤本和乔木占8.4%.喜盐种在河口的内侧、中区和外侧占总数的百分比分别为5.7%,6.8%和11.8%.二叶红薯、南方碱蓬和番杏是盐碱土的指示种.在内侧近淡水区有繁茂的咸水草、芦苇和芦竹     

Circalittoral Macrobenthic Assemblages of Strymonikos Gulf (North Aegean Sea)

Abstract. Six macrobenthic assemblages of the circalittoral zone found in Strymonikos Gulf, North Aegean Sea, are described and compared with the corresponding ones from other Mediterranean and Atlantic areas. For the delimination of these assemblages and the evaluation of the major environmental gradients governing their distribution, several numerical techniques were used.     

The Vema Transverse Ridge (Central Atlantic)

Transverse ridges are elongate reliefs running parallel and adjacent to transform/fracture zones offsetting mid-ocean ridges. A major transverse ridge runs adjacent to the Vema transform (Central Atlantic), that offsets the Mid-Atlantic Ridge by 320 km. Multibeam morphobathymetric coverage of the entire Vema Transverse ridge shows it is an elongated (300 km), narrow (<30 km at the base) relief that constitutes a topographic anomaly rising up to 4 km above the predicted thermal contraction level. Morphology and lithology suggest that the Vema Transverse ridge is an uplifted sliver of oceanic lithosphere. Topographic and lithological asymmetry indicate that the transverse ridge was formed by flexure of a lithospheric sliver, uncoupled on its northern side by the transform fault. The transverse ridge can be subdivided in segments bound by topographic discontinuities that are probably fault-controlled, suggesting some differential uplift and/or tilting of the different segments. Two of the segments are capped by shallow water carbonate platforms, that formed about 3–4 m.y. ago, at which time the crust of the transverse ridge was close to sea level. Sampling by submersible and dredging indicates that a relatively undisturbed section of oceanic lithosphere is exposed on the northern slope of the transverse ridge. Preliminary studies of mantle-derived ultramafic rocks from this section suggest temporal variations in mantle composition. An inactive fracture zone scarp (Lema fracture zone) was mapped south of the Vema Transverse ridge. Based on morphology, a fossil RTI was identified about 80 km west of the presently active RTI, suggesting that a ridge jump might have occurred about 2.2 m.a. Most probable causes for the formation of the Vema Transverse ridge are vertical motions of lithospheric slivers due to small changes in the direction of spreading of the plates bordering the Vema Fracture Zone.     

Modeling erosion of sedimentary coasts in the western Russian Arctic

Morphodynamic modeling is employed in the present work to predict the long-term evolution (over the next 100 years) of typical sedimentary coasts in the western Russian Arctic. The studied objects are the coasts of Varandey (the Barents Sea), Baydaratskaya Bay and Harasavey (the Kara Sea). The model developed takes into account both the short-term processes (storm events) and long-term factors (for example, changes in sea level, inter-annual variations in gross sediment flux, lack or excess of sediment supply). Predicted and observed morphological changes in coastal profiles are shown to agree well for time scales ranging from weeks to decades. It is revealed that under given environmental conditions, the morphological evolution is strongly influenced by storm surges and associated wind-driven circulation. The water level gradient created by a surge generates a seaward flow at the bed. This outflow is shown to be an important destructive mechanism contributing to the erosion and recession of Arctic coasts. The rate of change is found to depend on both the exposure of the coast (relative to the direction of dominant winds) and its height above the sea. The open coast of Varandey is expected to retreat as much as 300–500 m over 100 years, while recession of the less exposed coasts of Baydaratskaya Bay would not exceed about 100 m/century. If long-term sediment losses are insignificant, the rate of erosion decays with time and the morphodynamic system may tend toward equilibrium. It is concluded that the expected relative sea-level rise (up to 1 m over the nearest 100 years) is non-crucial to the future coastal evolution if an erosion activity is already high enough.     

The Deep-Water Peyssonnelia Beds from the Balearic Islands (Western Mediterranean)

Abstract. Peyssonnelia bed distribution on continental shelf bottoms of the Balearic Islands (Western Mediterranean) ranges from 40 to 90 m depth. Different species of Peyssonnelia dominate these bottoms and, according to multivariate techniques, two main assemblages have been distinguished: the Peyssonnelia rosa-marina beds and the Peyssonnelia sp. beds, together with some transition samples between Peyssonnelia and maërl beds. Erect red algae are always abundant. Although average yearly irradiance reaching these beds is only 6.4-0.3% of subsurface irradiance, the species richness averages 45 species per sample (1600 cm²) and mean biomass is 2835 g dw. m^-2. The high carbonate content of the living algae of these bottoms suggests that they are important contributors to the production of sediments in the Balearic continental shelf.     

福建晚更新世海侵问题探讨

福建沿海在晚更新世大约距今90—80ka、70—60ka、44—39ka和34—20ka期间分别发生过4次海侵。最末一次海侵(距今34—20Ka)期间有过明显的海面下降波动,时间大约在距今28ka前后。     

Annual Anthropogenic Carbon Transport into the North Pacific Intermediate Water through the Kuroshio/Oyashio Interfrontal Zone: An Estimation from CFCs Distribution

Vertical distribution of anthropogenic carbon content of the water (exDIC) in the Oyashio area just outside of the Kuroshio/Oyashio Interfrontal Zone (K/O Zone) was estimated by the simple 1-D advection-diffusion model calibrated by the distribution of chlorofluorocarbons (CFCs). The average concentration of exDIC for = 26.60–27.00 is multiplied by the volume transport of Oyashio water into the North Pacific Intermediate Water (NPIW) to estimate the annual transport of exDIC into NPIW through K/O Zone. The estimated transport of exDIC was 0.018–0.020 GtC/y, which corresponds to 15% of the whole total exDIC accumulation in the temperate North Pacific. A simple assessment using the NPIW 1-box model indicates that the current study explains at least 70% of the total annual transport of exDIC into NPIW, and that small exDIC sources for NPIW still exists in addition to K/O Zone.     

威海地区高压岩石组合及其成因演化

利用矿物地质温压计估算变质高峰期温压条件、退变质作用温压条件。研究表明,本区为鲁苏构造带的北延部分,代表本区晚元古代华南陆块与华北陆块的碰撞及三叠纪华北陆块向华南陆块推覆事件的发生和演化。     

山东省海岸工程可持续发展的若干问题

从风暴潮、黄河口治理、海水地下入侵与咸水侵染、海岸及沿海污染、沿海滩涂与黄河三角洲开发、海上交通和港口发展、海岸和海上石油开采、海岸工业基地建设、沿海旅游和海岛开发 ,以及沿岸淡水资源开发与海水利用等 1 0个方面 ,对山东省海岸工程的可持续发展问题进行了分析和讨论 ,并针对具体问题 ,提出了解决可持续发展问题的对策与措施。