不同沉淀法处理含铬废水的比较

含铬废水具有有机物含量高,难降解物质浓度高,色度大,悬浮物多,水质、水量变化大,含有微量毒性物质等特点。本文探讨了在不同参数条件下,硫酸亚铁、铁、硫化亚铁三种还原剂对含铬废水处理效果的影响,实验表明:硫酸亚铁具有明显的优越性,在同等条件下其去除率达到99%以上。     

中国区域气溶胶对东亚夏季风的可能影响(Ⅱ)：黑碳气溶胶及其与硫酸盐气溶胶的综合影响

 利用NCAR的新一代GCM CAM3.0模式耦合一个气溶胶同化系统,研究了中国区域黑碳气溶胶的直接气候效应。结果显示,中国区域黑碳气溶胶引起全球平均辐射强迫为0.13 W/m2,导致除了青藏高原和广西以外的中国大部分地区降温,其中东北、四川和内蒙古中北部降温最显著。由此造成海陆温差缩小,气压差降低,从而总体上使东亚夏季风减弱。但与硫酸盐气溶胶的影响相比,黑碳气溶胶使季风减弱的程度较小,长江中下游地区的降水有所增加。黑碳气溶胶加强了中国东南部地区的对流活动,这与硫酸盐气溶胶的作用相反。同时,探讨了中国区域硫酸盐和黑碳气溶胶的综合直接气候效应。结果表明,硫酸盐和黑碳气溶胶的综合作用与仅有硫酸盐气溶胶的情形十分相似,降水变化的区域也和硫酸盐的保持一致。     

Multiple sulfur isotope chemostratigraphy across the Permian–Triassic boundary at Chaotian,China: Implications for a shoaling model of toxic deep-waters

Previous studies on multiple sulfur isotopes (³²S, ³³S, and ³⁴S) in sedimentary pyrite at the end-Permian suggested a shoaling of anoxic/sulfidic deep-water contributing to the extinction. This scenario is based on an assumption that the sedimentary sulfur cycle was largely controlled by benthos activity, though a stratigraphic correlation between the sulfur records and ichnofabrics of the sediments at the end-Permian has not yet been examined. We report the multiple sulfur isotopic composition of pyrite in the Permian–Triassic boundary interval at Chaotian, South China. Our data can be generally explained by a mixing of sulfur in sulfide from two different sources: one produced via sulfate reduction in an open system with respect to sulfate and the other produced in a closed system. In particular, the former with the substantially low δ³⁴S (<−40 ‰) and high ∆³³S (up to +0.100 ‰) values was likely produced via water-mass sulfate reduction or via sulfate reduction in oxic sediments with common burrows. The frequent occurrence of small pyrite framboids (mostly <5 μm in diameter) in the Lopingian (Late Permian) Dalong Formation of deep-water facies supports the enhanced water-mass sulfate reduction in an anoxic deep-water mass. The negative ∆³³S values are observed only in the oxic limestones, and no substantial ∆³³S change is observed across the extinction horizon despite of the disappearance of bioturbation. Our results are apparently inconsistent with the previous shoaling model. We expand the model and infer that, when the deep-water was sulfidic and its shoaling rate was high, a substantial amount of hydrogen sulfide (H₂S) was supplied onto the shelf via the shoaling; that resulted in the positive ∆³³S value of the bulk sediments. The observed ∆³³S variation on a global scale suggests a substantial variation in H₂S concentration and/or in upwelling rate of shoaling deep-waters during the Permian–Triassic transition.     

云贵高原斜坡地带典型地下水富硫酸盐地区“越层找水”模式及其机理研究

地下水是中国西南云贵高原斜坡地带重要的饮用水源,其中黔中镇宁县北部存在大面积地下水中硫酸盐超标地区,导致了当地出现水质性缺水问题。本次研究通过岩相古地理分析、水化学分析、D、18O、34S同位素测试、岩样测试、岩心观察等技术手段,查明了研究区内地下水的补给源主要为大气降水,地下水中硫酸盐(SO_4~(2-))浓度在30～1100 mg/L,平均值为221.78 mg/L,呈现高度富集SO_4~(2-)的特点;在区域相对隔水层以上,不同类型地下水中SO_4~(2-)浓度大体具有机井上升泉下降泉溶潭地下河出口基岩裂隙泉表层岩溶泉的规律;探讨了地表水、地下水中SO_4~(2-)的来源,表层岩溶泉中硫酸根的来源主要为大气降水,高硫酸盐样品中硫酸根的来源主要为石膏溶解。在此基础上,结合钻井资料,掌握了研究区膏岩层分布及含水层结构特征,通过建立"越层找水"模式,采取下层低硫酸盐含水层,获取合格饮用水源,可有效解决当地水质性缺水问题。     

伊犁蒙其古尔铀矿床含矿层砂岩中黄铁矿形成机制及对铀成矿的指示意义

蒙其古尔铀矿床为伊犁盆地南缘大型层间氧化带砂岩型铀矿床,为查明该矿床含矿层中黄铁矿成因及其形成机制,探讨微生物参与铀成矿过程。文章对含矿层砂岩中黄铁矿与铀矿物矿物学特征、黄铁矿S同位素与碳酸盐胶结物的C-O同位素开展细致研究。研究表明:①蒙其古尔铀矿床中铀主要以铀矿物与吸附铀形式存在,吸附铀主要为有机质吸附铀,铀矿物以沥青铀矿为主,多与黄铁矿、炭屑共生;②蒙其古尔铀矿床含矿层砂岩中黄铁矿主要以自形晶、草莓状和不规则状集合体产出,多与沥青铀矿、碳酸盐胶结物共生,其中黄铁矿S同位素(δ~(34)S_(V-CDT)=-68.4‰～22.1‰)与碳酸盐胶结物的C-O同位素(δ~(13)C_(V-PDB)=-10.2‰～-7.4‰,δ~(18)O_(V-PDB)=-9.6‰～-5.8‰)分析表明黄铁矿具有细菌硫酸盐还原(BSR)与有机物热解2种成因,并探讨了这2种不同成因黄铁矿的形成机制。③结合前人研究成果,认为硫酸盐还原菌(SRB)参与蒙其古尔铀矿床铀成矿过程,以间接还原方式为主,在有机质、黏土矿物与颗粒表面吸附U(Ⅵ)的基础上,通过硫酸盐还原菌(SRB)还原SO_4~(2-)产生的H_2S将U(Ⅵ)被还原成U(Ⅳ),形成铀矿物。     

Researches on the Internal Molecular Weight Uniformity of Chitosan Biomaterials

Uniform molecular weight(Mw)chitosan(CS)is highly demanded in medical biomaterial industry.This present article described heterogeneous degradation of CS in aqueous HCl/ethanol solution,in which progress uniform Mw CS was successfully prepared.The Mw distribution of CS was measured by gel permeation chromatography(GPC)analysis.Moreover,the structure and properties of degraded CS were characterized by Fourier transform infrared spectroscopy(FT-IR),nuclear magnetic resonance spectroscopy(^1H NMR),X-ray diffraction(XRD)and thermogravimetric(TG)analysis.In addition,the biocompatibility of degraded CS was also assessed by hemolysis rate(HR)measurement.The Mw of CS dramatically decreased from 246 KDa to 76 k Da at the initial 30 min,and stabilized at 18 kDa after 24 h.GPC analysis results showed that the degraded CS molecular become homogenization.FT-IR and 1 H NMR analysis confirmed the basic structure of CS molecular backbone was not destroyed during this progress.Besides,the water solubility of CS was not significantly influenced by this reaction.Moreover,the XRD analysis revealed that crystallinity of degraded CS increased from 70.32% to 99.25%with time.The TG analysis showed improved thermal stability of degraded CS.HR measurement demonstrated the degraded CS possessed excellent biocompatibility.This simple and efficient heterogeneous degradation would open up a new route to produce uniform Mw CS.     

Geochemistry of Flooded Underground Mine Workings Influenced by Bacterial Sulfate Reduction

Unlike the majority of the water in the flooded mine complex of Butte Montana, which includes the highly acidic Berkeley pit lake, groundwater in the flooded West Camp underground mine workings has a circum-neutral pH and contains at least 8 μM aqueous sulfide. This article examines the geochemistry and stable isotope composition of this unusual H₂S-rich mine water, and also discusses problems related to the colorimetric analysis of sulfide in waters that contain FeS_(aq) cluster compounds. The West Camp mine pool is maintained at a constant elevation by continuous pumping, with discharge water that contains elevated Mn (90 μM), Fe (16 μM), and As (1.3 μM) but otherwise low metal concentrations. Dissolved inorganic carbon in the mine water is in chemical and isotopic equilibrium with rhodochrosite in the mineralized veins. The mine water is under-saturated with mackinawite and amorphous FeS, but is supersaturated with Cu- and Zn-sulfides. However, voltammetry studies show that much of the dissolved sulfide and ferrous iron are present as FeS_(aq) cluster molecules: as a result, the free concentration of the West Camp water is poorly constrained. Concentrations of dissolved sulfide determined by colorimetry were lower than gravimetric assays obtained by AgNO₃ addition, implying that the FeS_(aq) clusters are not completely extracted by the Methylene Blue reagent. In contrast, the clusters are quantitatively extracted as Ag₂S after addition of AgNO₃. Isotopic analysis of co-existing aqueous sulfide and sulfate confirms that the sulfide was produced by sulfate-reducing bacteria (SRB). The H₂S-rich mine water is not confined to the immediate vicinity of the extraction well, but is also present in flooded mine shafts up to 3 km away, and in samples bailed from mine shafts at depths up to 300 m below static water level. This illustrates that SRB are well established throughout the southwestern portion of the extensive (>15 km³) Butte flooded mine complex.     

壳聚糖分离膜的研制

近年来,膜分离材料及膜分离技术是一个相当受重视的研究开发和应用的领域[1,2]。反渗透法是一项新型的膜分离技术。     

二异氰酸酯与壳聚糖交联产物对金属离子的吸附性能

研究了二异氰酸酯与壳聚糖的交联反应,其产物与壳聚糖相比,酸溶解度由82.04％降到58.08％。DSC曲线表明,交联产物的热稳定性明显提高,对低价重金属离子(Hg     

陆相咸化湖泊沉积硫酸盐岩硫同位素组成及其地质意义

现代海洋中的硫酸盐矿物和海水硫酸盐本身常有相似的硫同位素组成,因而可根据现代蒸发岩的硫酸盐同位素来判断古环境。据李任伟［１］引用Ｈｏｌｓｅｒ和Ｋａｐｌａｎ及格里年科的资料报道,海相蒸发岩及其所反映的古海洋硫酸盐的硫同位素组成只在较狭窄的范围内变化,现...