南海北部台西南盆地973-4岩芯碳的地球化学特征

对南海北部台西南盆地天然气水合物潜在区(973-4岩芯)碳的形态、含量和稳定同位素组成进行了分析,并探讨了成岩环境因素和细菌种群与碳地球化学行为的关系。结果显示:(1)TOC含量为0.4%~1.3%,δ~(13)CTOC为–26.7‰~–23.9‰,说明973-4岩芯主要为陆源有机质,能够满足微生物产甲烷的需要;DIC和δ~(13)CIC的垂向变异及其显著负相关,指示:973-4岩芯560~890 cm深度段有SO42–驱动的AOM反应。(2)p H、Eh、沉积物粒径等成岩环境参数与TOC、IC、δ~(13)CTOC、δ~(13)CIC等碳地化参数显著相关。(3)细菌种群与DIC、δ~(13)CIC显著相关。结论认为:(1)973-4岩芯碳的地化行为与天然气水合物成藏存在明显响应关系。(2)成岩环境参数的垂向变异与碳的地球化学特征密切相关。(3)细菌种群对碳的地化参数变异有着显著影响。     

遥感反演和站点观测的地气温度分布特征差异

地表温度和近地表大气温度是地球系统、大气系统以及地—气相互作用物理过程的重要参量。在陆地—大气的相互作用过程中,水汽含量、NDVI指数、下垫面变化等因素会对地—气热量传输造成一定的影响。本文首先利用地表温度产品（MYD11A1）以及气温站点数据（GSOD）获得全国尺度下地表温度年最大值、近地面气温年最大值。在此基础上,使用趋势分析法分析2003年—2018年地、气温度年最大值时空分布特征及变化趋势,以及地—气温差气候倾向率变化趋势。最后,结合大气总水汽含量产品（MYD05）、NDVI指数（MYD13A3）、二氧化碳平均浓度增长率分析导致地表温度年最大值与近地面气温年最大值趋势发生变化的原因。研究结果表明：（1）在全国尺度下,2003年—2018年地表温度年最大值呈现北高南低的空间分布特征。近地面气温年最大值的空间分布与地表温度年最大值相反。大气总水汽含量年最大值在热带、亚热带季风气候区内总体较高。水汽含量既影响近地面气温的大小,同时也受到近地面气温的影响,因此,水汽含量年最大值与近地面气温年最大值表现出一定的空间分布一致性特征。（2）在2003年—2018年期间,地表温度年最大值的气候倾向率在空间上表现出北高南低的分布特征。近地面气温年最大值的气候倾向率在空间上也表现为北高南低,与地表温度年最大值的气候倾向率变化基本一致。但地表温度年最大值的变化幅度要大于近地面气温年最大值,并且在个别区域表现不一致。主要分布在天山地区、三江平原以及秦岭南侧地区,地—气年最大值变化趋势相反即地—气差减小。（3）大气总水汽含量年最大值的增加可造成近地面气温年最大值的增加,而植被覆盖度的上升可造成地表温度年最大值下降。但在天山地区大气总水汽含量与地—气差的响应不明显,但天山地区的近地面气温年最大值与CO₂平均浓度增长率的关系较为明显。（4）遥感数据反演的地表温度年最大值和站点观测的近地面气温年最大值空间分布表现出差异,但时间变化趋势基本一致。     

Quantifying sedimentation patterns of small landslide-dammed lakes in the central Oregon Coast Range

Understanding sedimentation patterns in small coastal watersheds due to landscape perturbations is critical for connecting hillslope and fluvial processes, in addition to managing aquatic habitats for anadromous fish and other aquatic species in the Oregon Coast Range (OCR). Changes in sedimentation patterns spanning the last 250 years are preserved in two landslide-dammed lakes in small watersheds (< 10 km²) underlain by the Tyee Formation in the central OCR. Dendrochronology of drowned Douglas-fir stumps in both lakes provided precise timing of the damming and formation of the lakes, with Klickitat Lake forming in winter ad 1751/52 and Wasson Lake in winter ad 1819/20. Perturbations from wildfires, logging and road development, and previously underappreciated snow events affect sedimentation rates in the lakes to different degrees, and are identified in the sediment record using cesium-137 (¹³⁷Cs), high-resolution charcoal stratigraphy, local fire records, and aerial photography. Each lake has variable sedimentation accumulation rates (0.05–4.4 cm yr⁻¹) and mass accumulation rates (0.02–1.42 g cm⁻² yr⁻¹). Sedimentation rates remained low from the landslide-damming events until the mid-19th century, when they increased following stand-replacing wildfires. Aside from a sediment remobilization triggered by human modification of the landslide dam at Klickitat Lake around 1960, the largest peaks in mass accumulation rates in the mid-20th century at both lakes in the early 1950s precede major road construction and logging activity in the watersheds. Subsequent sedimentation rates are lower, but variable, and possible effects of logging and road development might be exacerbated by abnormal precipitation and heavy snow events. A comparison of previous studies of landslide-dammed lakes in larger watershed of the OCR are consistent with our findings of increased sedimentation in the mid-20th century, as well as higher sedimentation rates in the debris-flow dominated southern Tyee Formation than in the lower-relief northern Tyee Formation.     

Improved understanding of dynamic water and mass budgets of high-alpine karst systems obtained from studying a well-defined catchment area

Large areas of Europe, especially in the Alps, are covered by carbonate rocks and in many alpine regions, karst springs are important sources for drinking water supply. Because of their high variability and heterogeneity, the understanding of the hydrogeological functioning of karst aquifers is of particular importance for their protection and utilisation. Climate change and heavy rainfall events are major challenges in managing alpine karst aquifers which possess an enormous potential for future drinking water supply. In this study, we present research from a high-alpine karst system in the UNESCO Biosphere Reserve Großes Walsertal in Austria, which has a clearly defined catchment and is drained by only one spring system. Results show that (a) the investigated system is a highly dynamic karst aquifer with distinct reactions to rainfall events in discharge and electrical conductivity; (b) the estimated transient atmospheric CO₂ sink is about 270 t/a; (c) the calculated carbonate rock denudation rate is between 23 and 47 mm/1000a and (d) the rainfall-discharge behaviour and the internal flow dynamics can be successfully simulated using the modelling package KarstMod. The modelling results indicate the relevance of matrix storage in determining the discharge behaviour of the spring, particularly during low-flow periods. This research and the consequent results can contribute and initiate a better understanding and management of alpine karst aquifers considering climate change with more heavy rainfall events and also longer dry periods.     

BIFoR FACE: Water–soil–vegetation–atmosphere data from a temperate deciduous forest catchment,including under elevated CO2

The ecosystem services provided by forests modulate runoff generation processes, nutrient cycling and water and energy exchange between soils, vegetation and atmosphere. Increasing atmospheric CO₂ affects many linked aspects of forest and catchment function in ways we do not adequately understand. Global levels of atmospheric CO₂ will be around 40% higher in 2050 than current levels, yet estimates of how water and solute fluxes in forested catchments will respond to increased CO₂ are highly uncertain. The Free Air CO₂ Enrichment (FACE) facility of the University of Birmingham's Institute of Forest Research (BIFoR) is the only FACE in mature deciduous forest. The site specializes in fundamental studies of the response of whole ecosystem patches of mature, deciduous, temperate woodland to elevated CO₂ (eCO₂). Here, we describe a dataset of hydrological parameters – seven weather parameters at each of three heights and four locations, shallow soil moisture and temperature, stream hydrology and CO₂ enrichment – retrieved at high frequency from the BIFoR FACE catchment.     

依兰—伊通断裂带黑龙江段构造运动特征

为研究依兰—伊通断裂带黑龙江段构造运动特征,基于2016—2019年GPS和地质资料,解算了该断裂的三维速度场,通过构建断层模型反演了滑动速率。结果显示:依兰—伊通断裂带黑龙江段总体呈下沉趋势,沉降速率在1~2 mm/a,断裂呈右旋走滑态势,闭锁层15 km以下走滑速率为(1.7±0.4)mm/a。佳木斯—萝北段以右旋走滑为主、拉张为辅;五常—佳木斯段以拉张为主、右旋走滑为辅。     

The δ13C–δ18O variations in marble in the Hida Belt,Japan

Marble has a great potential to understand a history of various geological events occurring during tectonic processes. In order to decode metamorphic–metasomatic records on C–O isotope compositions of marble at mid-crustal conditions, we conducted a C–O–Sr isotope study on upper amphibolite-facies marbles and a carbonate–silicate rock from the Hida Belt, which was once a part of the crustal basement of the East Asian continental margin. Carbon and oxygen isotope analyses of calcite from marbles (Kamioka area) and a carbonate–silicate rock (Wadagawa area) show a large variation of δ¹³C [VPDB] and δ¹⁸O [VSMOW] values (from −4.4 to +4.2 ‰ and +1.6 to +20.8 ‰, respectively). The low δ¹³C values of calcites from the carbonate–silicate rock (from −4.4 to −2.9 ‰) can be explained by decarbonation (CO₂ releasing) reactions; carbon–oxygen isotope modeling suggests that a decrease of δ¹³C strongly depends on the amount of silicate reacting with carbonates. The occurrence of metamorphic clinopyroxene in marbles indicates that all samples have been affected by decarbonation reactions. All δ¹⁸O values of calcites are remarkably lower than the marine-carbonate values. The large δ¹⁸O variation can be explained by the isotope exchange via interactions between marble, external fluids, and/or silicates. Remarkably low δ¹⁸O values of marbles that are lower than mantle value (~+5 ‰) suggest the interaction with meteoric water at a later stage. Sr isotope ratios (⁸⁷Sr/⁸⁶Sr = 0.707255–0.708220) might be close to their protolith values. One zircon associated with wollastonite in a marble thin-section yields a U–Pb age of 222 ± 3 Ma, which represents the timing of the recrystallization of marble, triggered by H₂O-rich fluid infiltration at a relatively high-temperature condition. Our isotope study implies that the upper amphibolite-facies condition, like the Hida Belt, might be appropriate to cause decarbonation reactions which can modify original isotope compositions of marble if carbonates react with silicates.     

Multiple sulfur isotope chemostratigraphy across the Permian–Triassic boundary at Chaotian,China: Implications for a shoaling model of toxic deep-waters

Previous studies on multiple sulfur isotopes (³²S, ³³S, and ³⁴S) in sedimentary pyrite at the end-Permian suggested a shoaling of anoxic/sulfidic deep-water contributing to the extinction. This scenario is based on an assumption that the sedimentary sulfur cycle was largely controlled by benthos activity, though a stratigraphic correlation between the sulfur records and ichnofabrics of the sediments at the end-Permian has not yet been examined. We report the multiple sulfur isotopic composition of pyrite in the Permian–Triassic boundary interval at Chaotian, South China. Our data can be generally explained by a mixing of sulfur in sulfide from two different sources: one produced via sulfate reduction in an open system with respect to sulfate and the other produced in a closed system. In particular, the former with the substantially low δ³⁴S (<−40 ‰) and high ∆³³S (up to +0.100 ‰) values was likely produced via water-mass sulfate reduction or via sulfate reduction in oxic sediments with common burrows. The frequent occurrence of small pyrite framboids (mostly <5 μm in diameter) in the Lopingian (Late Permian) Dalong Formation of deep-water facies supports the enhanced water-mass sulfate reduction in an anoxic deep-water mass. The negative ∆³³S values are observed only in the oxic limestones, and no substantial ∆³³S change is observed across the extinction horizon despite of the disappearance of bioturbation. Our results are apparently inconsistent with the previous shoaling model. We expand the model and infer that, when the deep-water was sulfidic and its shoaling rate was high, a substantial amount of hydrogen sulfide (H₂S) was supplied onto the shelf via the shoaling; that resulted in the positive ∆³³S value of the bulk sediments. The observed ∆³³S variation on a global scale suggests a substantial variation in H₂S concentration and/or in upwelling rate of shoaling deep-waters during the Permian–Triassic transition.     

基于InVEST模型的辽宁省海岸带碳储量时空变化研究

陆地生态系统碳储量与全球气候变化密切相关,研究海岸带地区土地利用变化对生态系统服务碳储量的影响,对于区域生态系统保护及社会经济可持续发展具有重要意义.以辽宁省海岸带地区为例,分析了1995—2018年海岸带地区的土地利用变化特征,运用InVEST模型碳储量模块估算了1995—2018年区域生态系统的碳储量,结果表明:(...     

俯冲带中大理岩与榴辉岩的Mg-Fe-C-O同位素迁移

碳酸盐岩和碳酸盐化岩石是俯冲带中碳的主要地质载体.俯冲-折返的超高压变质岩记录了俯冲隧道中流体-岩石的相互作用与元素迁移,是研究地球内部元素循环的重要媒介.本文采集了大别造山带罗家岭互层状产出的大理岩和榴辉岩,建立了横跨岩性界面的矿物组成、显微结构和Mg-Fe-C-O同位素剖面.大理岩中主要组成矿物为白云石,其次为方解...