Low-temperature thermodynamic properties of disordered zeolites of the natrolite group

 The heat capacity of paranatrolite and tetranatrolite with a disordered distribution of Al and Si atoms has been measured in the temperature range of 6–309 K using the adiabatic calorimetry technique. The composition of the samples is represented with the formula (Na_1.90K_0.22Ca_0.06)[Al_2.24Si_2.76O₁₀]·nH₂O, where n=3.10 for paranatrolite and n=2.31 for tetranatrolite. For both zeolites, thermodynamic functions (vibrational entropy, enthalpy, and free energy function) have been calculated. At T=298.15 K, the values of the heat capacity and entropy are 425.1 ± 0.8 and 419.1 ±0.8 J K⁻¹ mol⁻¹ for paranatrolite and 381.0 ± 0.7 and 383.2 ± 0.7 J K⁻¹ mol⁻¹ for tetranatrolite. Thermodynamic functions for tetranatrolite and paranatrolite with compositions corrected for the amount of extraframework cations and water molecules have also been calculated. The calculation for tetranatrolite with two water molecules and two extraframework cations per formula yields: C _p (298.15)=359.1 J K⁻¹ mol⁻¹, S(298.15) −S(0)=362.8 J K⁻¹ mol⁻¹. Comparing these values with the literature data for the (Al,Si)-ordered natrolite, we can conclude that the order in tetrahedral atoms does not affect the heat capacity. The analysis of derivatives dC/dT for natrolite, paranatrolite, and tetranatrolite has indicated that the water- cations subsystem within the highly hydrated zeolite may become unstable at temperatures above 200 K. Received: 30 July 2001 / Accepted: 15 November 2001     

吉林腰英台油田油水分布特征及成因探讨

腰英台油田是东北地区新发现的油田，目前刚开始勘探开发，在勘探开发初期遇到不少问题。其中之一是开采时高含水：就油田的实际油水分布特征进行了分析，分析油水同出的可能原因，认为这是受油藏储层物性及构造幅度和实际油柱高度的影响，由于储层低孔、特低渗。实际构造幅度低，实际油柱高度大多低于油藏产纯油所需的油柱高度，致使油藏大都处于油水过渡带。故开采时多含水，油水同出。根据这一分析，认为进一步的油气勘探重点考虑西部水下冲积扇的有利部位。此处储层物性好，有利于接受更多油源。     

蒙脱石、高岭石、伊利石对重金属离子吸附容量的实验研究

在pH=4,t=23℃和微量浓度条件下,不改变离子浓度,通过增加吸附液体积进而增加体系中重金属离子含量的方法进行了蒙脱石、伊利石、高岭石对Cu2+、Pb2+、Zn2+、Cd2+、Cr3+等重金属离子吸附容量的实验研究,结果表明,3种矿物吸附容量大小顺序为蒙脱石>伊利石>高岭石,与其阳离子交换容量密切相关.Cu-蒙脱石和Cr-蒙脱石的X射线衍射结果表明,Cu2+、Cr3+通过离子交换作用进入了蒙脱石的层间.同一矿物对不同重金属离子也有不同的吸附容量蒙脱石Cr3+>Cu2+>Zn2+>Cd2+>Pb2+;高岭石Cr3+>Pb2+>Zn2+>Cu2+>Cd2+;伊利石Cr3+>Zn2+>Cd2+>Cu2+>Pb2+.     

乌东德高拱坝极限抗震能力研究

乌东德水电站是金沙江下游河段上4个水电梯级的最上游梯级,大坝为265 m高的双曲拱坝。采用非线性有限元法,将拱坝坝体-坝基作为一个整体系统,在考虑坝体横缝影响及无限地基辐射阻尼影响基础上,模拟坝肩控制性滑块各滑裂面在地震作用下张开、滑移的非线性力学行为,研究设计与校核地震作用下大坝的抗震性能,探讨大坝-坝基整体系统在强震作用下的抗震潜力。研究结果表明：设计地震条件下,坝体仅在拱端应力集中区域拉应力超过抗拉强度,压应力则均满足强度要求,坝肩块体稳定,大坝-坝基体系的整体安全性可以保证;校核地震条件下,坝体应力值略有增加,能够满足不溃坝的设防要求;以大坝-坝基代表性的位移、变形量变化曲线的拐点作为评价极限抗震能力的标准,可知拱坝-坝基体系的抗震超载安全系数为2.7,相应的基岩水平向峰值加速度0.729g,拱坝-坝基体系抗剪参数强度储备安全系数为2.0,乌东德高拱坝具备较强的极限抗震能力。     

Monitoring litter interception of rainfall using leaf wetness sensor under controlled and field conditions

Leaf litter interception of water is an integral component of the water budget for some vegetated ecosystems. However, loss of rainfall to litter receives considerably less attention than canopy interception due to lack of suitable sensors to measure changes in litter water content. In this study, a commercially available leaf wetness sensor was calibrated to the gravimetric water content of eastern redcedar (Juniperus virginiana ) litter and used to estimate litter interception in a subhumid eastern redcedar woodland in north‐central Oklahoma. Under controlled laboratory conditions, a strong positive correlation between the leaf wetness sensor output voltage (mV) and measured gravimetric litter water content (? _g) was determined: ? _g = (.0009 × mV²) ? (0.14 × mV) ? 11.41 (R ² = .94, p  < .0001). This relationship was validated with field sampling and the output voltage (mV) accounted for 48% of the observed variance in the measured water content. The maximum and minimum interception storage capacity ranged between 1.16 and 12.04 and 1.12 and 9.62 mm, respectively. The maximum and minimum amount of intercepted rain was positively correlated to rainfall amount and intensity. The continuous field measurements demonstrated that eastern redcedar litter intercepted approximately 8% of the gross rainfall that fell between December 16, 2014 and May 31, 2015. Therefore, rainfall loss to litter can constitute a substantial component of the annual water budget. Long‐term in situ measurement of litter interception loss is necessary to gain a better estimate of water availability for streamflow and recharge. This is critical to manage water resources in the south‐central Great Plains, USA where grasslands are rapidly being transformed to woodland or woody dominated savanna.     

桩土相互作用时桩参数对大直径空心桩承载影响的有限元研究

运用Ansys有限元技术,分析了在竖向荷载作用下大直径空心桩桩顶沉降、桩端沉降与桩身压缩三者的关系,桩长L对桩身轴力的影响,桩长L、桩径D、桩体弹性模量E对桩P-s曲线的影响,桩长L、桩径D对桩P-Se（桩端沉降与桩顶沉降的比值）曲线的影响,具有工程上的实际意义。     

板钉连接CFST柱-RC梁节点梁端塑性铰区受力性能数值模拟

建立竖板-栓钉连接钢管混凝土（CFST）柱-钢筋混凝土（RC）梁节点试件（SSJD）拟静力加载试验有限元模型,并在节点损伤情况、梁端荷载-位移曲线等数值模拟结果与试验结果吻合较好的基础上,进一步开展了RC梁混凝土强度、配筋率ρs和连接竖板长度Lb及界面连接情况等对CFST柱-RC梁节点梁端塑性铰区域力学性能的影响。研究结果表明,RC梁混凝土强度对试件SSJD塑性铰区域受力性能的影响较小;适筋范围内RC梁配筋率增加可适当提高试件SSJD承载力和延性;随着连接竖板长度的增加,梁端塑性铰区域外移,梁破坏荷载增大;本研究给出的RC梁与CFST柱之间的界面抗剪承载力模拟值与计算值吻合较好,可用于界面抗剪设计。     

宁波地区空气质量及大气自净能力海陆差异对比

以镇海、奉化分别作为宁波沿海和内陆空气质量代表站。基于代表站2013-2017年污染物资料和2015年12月至2017年2月冬季激光雷达资料,对比分析宁波地区沿海和内陆站点的空气质量差异;利用NCEP的GDAS(Global Data Assimilation System)资料和ERA-Interim高分辨率再分析资料评估两地气溶胶来源及大气自净能力差异。结果表明:宁波沿海和内陆地区中度及以上污染主要集中于冬季,冬季首要污染物以PM2.5为主;镇海NO2浓度较奉化显著偏高,而两地PM2.5 和PM10 浓度差异较小。冬季镇海和奉化3km以下都存在消光系数大的气溶胶集中层,镇海3km内消光系数平均值较奉化偏高约40%。两地中度及以上污染时,镇海和奉化的气溶胶粒子主要来自宁波西北方向的内陆地区,比例分别为90%和63%,镇海地区其余10%左右来自近距离低空偏东气流的输送,而奉化地区有37%来自浙江西南部的短距离输送。冬季当宁波地区出现区域性优和中度以上污染时,浙江北部沿海分别盛行东北风和西北风,空气质量优时混合层内平均风速大于中度以上污染时。浙江省大气自净能力比值呈自西北向东南减小,宁波地区优等空气质量大气自净能力约为中度以上污染的 1.5倍。大气自净能力在不同空气质量等级下差异显著,可作为大气污染发生、发展和消退判定的参考依据。     

内蒙古生态承载力评价及生态安全格局优化

生态安全水平对区域发展的约束作用不断增强,构建科学合理的生态安全格局可以有效缓解经济发展与环境保护之间的矛盾.以内蒙古自治区为研究区,2000年、2005年、2010年、2015年为间断点,建立区域生态承载力评价指标体系,探讨生态承载力时空演变特征;甄别生态优势斑块,结合自然保护区等重要生态斑块组建生态源地,建立生态源...