Chemical and physical properties affecting strontium distribution coefficients of surficial-sediment samples at the Idaho National Engineering and Environmental Laboratory, Idaho

 The U.S. Geological Survey and Idaho State University, in cooperation with the U.S. Department of Energy, conducted a study to determine strontium distribution coefficients (K_ds) of surficial sediments at the Idaho National Engineering and Environmental Laboratory (INEEL). Batch experiments using synthesized aqueous solutions were used to determine K_ds, which describe the distribution of a solute between the solution and solid phase, of 20 surficial-sediment samples from the INEEL. The K_ds for the 20 surficial-sediment samples ranged from 36 to 275 ml/g. Many properties of both the synthesized aqueous solutions and sediments used in the experiments also were determined. Solution properties determined were initial and equilibrium concentrations of calcium, magnesium, and strontium, pH and specific conductance, and initial concentrations of potassium and sodium. Sediment properties determined were grain-size distribution, bulk mineralogy, whole-rock major-oxide and strontium and barium concentrations, and Brunauer-Emmett-Teller (BET) surface area. Solution and sediment properties were correlated with strontium K_ds of the 20 surficial sediments using Pearson correlation coefficients. Solution properties with the strongest correlations with strontium K_ds were equilibrium pH and equilibrium calcium concentration correlation coefficients, 0.6598 and –0.6518, respectively. Sediment properties with the strongest correlations with strontium K_ds were manganese oxide (MnO), BET surface area, and the >4.75-mm-grain-size fraction correlation coefficients, 0.7054, 0.7022, and –0.6660, respectively. Effects of solution properties on strontium K_ds were interpreted as being due to competition among similarly charged and sized cations in solution for strontium-sorption sites; effects of sediment properties on strontium K_ds were interpreted as being surface-area related. Multivariate analyses of these solution and sediment properties resulted in r² values of 0.8071 when all five properties were used and 0.8043 when three properties, equilibrium pH, MnO, and BET surface area, were used. Received: 30 November 1998 · Accepted: 16 February 1999     

双基地激光测风雷达回波信号仿真研究

本文针对传统的体散射模型并未考虑大气不均匀性对信号传输的影响等问题,通过引入垂直非均匀的大气参数改进了模型,并利用其建立了体目标的双基地激光测风雷达方程,仿真了侧向散射回波信号,并与单基地雷达进行了对比分析。研究表明:水平方向上,双基地激光测风雷达的回波信号分布特征与单基地雷达差异较大,其回波信号等值线在近地面为卵形线,随着探测高度的增加,回波信号等值线逐渐变为以主、被动雷达为焦点的椭圆形,并最终趋近于圆形;垂直方向上,双基地激光测风雷达的回波信号随高度衰减剧烈,近地面的回波能量约为10^-10 J,4 km高度的回波能量约为10^-15J,在中低层大气(0~10 km),回波信号中气溶胶散射占比大,在高层大气(10 km以上),分子散射占比大。     

川北山丘区地下水补给特征与定量研究

针对川北山丘区地下水资源和污染防护研究中地下水补给难以定量等问题,以川北典型山丘区平溪河北岸的山丘区子流域为研究对象,布设监测孔并对其地下水的水位和水温开展动态监测,并基于大气压监测数据校正地下水监测水位,分析了山丘区地下水水位及水温的年内动态变化特征;采用渗水试验和分段双栓塞水文地质试验获取含水层空间渗透系数;基于达西断面法定量计算了研究区内观测断面的地下水径流补给量,并建立了月降雨量与降水入渗系数的函数关系,结果显示:研究区多年平均大气降水入渗补给量为16.61mm,多年平均降水入渗系数为0.0182;月降雨量与降水入渗系数呈幂函数关系;此成果可为研究区地下水资源、地下水防污性能评价及地下水数值模拟等研究提供重要依据。     

The use of remotely sensed land cover to derive floodplain friction coefficients for flood inundation modelling

Remotely sensed land cover was used to generate spatially‐distributed friction coefficients for use in a two‐dimensional model of flood inundation. Such models are at the forefront of research into the prediction of river flooding. Standard practice, however, is to use single (static) friction coefficients on both the channel and floodplain, which are varied in a calibration procedure to provide a “best fit” to a known inundation extent. Spatially‐distributed friction provides a physically grounded estimate of friction that does not require fitting to a known inundation extent, but which can be fitted if desired. Remote sensing offers the opportunity to map these friction coefficients relatively straightforwardly and for low cost. Inundation was predicted using the LISFLOOD‐FP model for a reach on the River Nene, UK. Friction coefficients were produced from land cover predicted from Landsat TM imagery using both ML and fuzzy c‐means classifiction. The elevetion data used were from combined contour and differential global positioning system (GPS) elevation data. Predicted inundation using spatially‐distributed and static friction were compared. Spatially‐distributed friction had the greatest effect on the timing of flood inundation, but a small effect on predicted inundation extent. The results indicate that spatially‐distributed friction should be considered where the timing of initial flooding (e.g. for early warning) is important. Copyright © 2007 John Wiley & Sons, Ltd.     

Evaluation of the accuracy of the EIGEN-1S and -2 CHAMP-derived gravity field models by satellite crossover altimetry

Since the advent of CHAMP, the first in a series of low-altitude satellites being almost continuously and precisely tracked by GPS, a new generation of long-wavelength gravitational geopotential models can be derived. The accuracy evaluation of these models depends to a large extent on the comparison with external data of comparable quality. Here, two CHAMP-derived models, EIGEN-1S and EIGEN-2, are tested with independent long-term-averaged single satellite crossover (SSC) sea heights from three altimetric satellites (ERS-1, ERS-2 and Geosat). The analyses show that long-term averages of crossover residuals still are powerful data to test CHAMP gravity field models. The new models are tested in the spatial domain with the aid of ERS-1/-2 and Geosat SSCs, and in the spectral domain with latitude-lumped coefficient (LLC) corrections derived from the SSCs. The LLC corrections allow a representation of the satellite-orbit-specific error spectra per order of the models spherical harmonic coefficients. These observed LLC corrections are compared to the LLC projections from the models variance–covariance matrix. The excessively large LLC errors at order 2 found in the case of EIGEN-2 with the ERS data are discussed. The degree-dependent scaling factors for the variance-covariance matrices of EIGEN-1S and –2, applied to obtain more realistic error estimates of the solved-for coefficients, are compatible with the results found here.     

‘Surface Drag in the Arctic Marginal Sea-ice Zone: A Comparison of Different Parameterisation Concepts’

Two parameterisation schemes for the turbulent surface fluxes and drag coefficients over the Arctic marginal sea-ice zone (MIZ) are (further) developed, and their results are compared with each other. Although the schemes are based on different principles (flux averaging and parameter averaging), the resulting drag coefficients differ only slightly in the case of neutral and stable stratification. For unstable stratification and sea-ice conditions being typical for the north-eastern Fram Strait, the drag coefficients resulting from the parameter-averaging concept are 5–10% larger than those of the flux-averaging concept. At a sea-ice concentration of 45%, the parameter-averaging method overestimates the heat fluxes by a factor of 1.2. An inclusion in the schemes of form drag caused by floe edges and ridges has a much larger effect on the drag coefficient, and on the momentum fluxes, than the choice between the parameter-averaging or flux-averaging methods. Based on sensitivity studies with the flux-averaging scheme, a simple formula for the effective drag coefficient above the Arctic MIZ is derived. It reduces the computational costs of the more complex parameterisations and could also be used in larger scale models. With this simple formula, the effective drag coefficient can be calculated as a function of the sea-ice concentration and skin drag coefficients for water and ice floes. The results obtained with this parameterisation differ only slightly from those using the more complex schemes. Finally, it is shown that in the MIZ, drag coefficients for sea-ice models may differ significantly from the effective drag coefficients used in atmospheric models.     

Studies on turbulent diffusion processes and evaluation of diffusivity values from hydrodynamic observations in Corpus Christi Bay

The physical process of dispersion which can be attributed to turbulence (turbulent diffusion) or shear (shear-augmented diffusion) within the flow field is very important as it ultimately governs the distribution of constituents of interest within the environment. A series of diffusion experiments were conducted in Corpus Christi Bay, TX with the purpose of characterizing turbulent diffusion through dispersion coefficients or turbulent diffusivity, K_i (i=x, y, z) dependent on the degree of randomness or turbulence intensity, I.Measured with a boat-mounted acoustic doppler current profiler (ADCP), the Eulerian velocity time-series of fluid particles in random motion, u_i was used in the evaluation of the Eulerian time-scale of turbulence, T^E based on the velocity correlation function, R^E with T^E being related to the Lagrangian time-scale T^L through a scaling parameter, β(=T^L/T^E). Surface currents were obtained with high frequency (HF) Radar equipment deployed over the study area from which the horizontal velocity gradients were determined.Within the spatial scale of the experiment (1000 m), the observed low horizontal gradients (10⁻⁴ s⁻¹) allowed for the generation of velocity time-series from an ADCP mounted on a moving platform. A numerical scheme for evaluating turbulent diffusivity values was developed on the basis of Eulerian current measurements and calibrated through the statistics of an evolving dye patch for the scaling parameter β which in this scheme was found to be in the range 1–3.     

Analytical evaluation of the relativistic thermodynamic functions using binomial expansion theorem and incomplete Gamma functions

A simple evaluation algorithm for calculation of the fermions and bosons relativistic thermodynamic functions with high accuracy is presented. This method is based on the use of the binomial expansion theorems and incomplete Gamma functions. The importance of this result is that it enables a series analytical formula to determine the thermodynamic functions of fermions and bosons in cases of degeneracy and relativity. The formulas obtained are numerically stable for ψ < 0. Examples of comparative calculations are given. Numerical results verify the effectiveness of the present approach and they are in good agreement with literature.     

基于L1范数的波阻抗反演

提出了一种新的波阻抗反演方法,首先根据地下反射系数序列是一个稀疏脉冲序列这一假设,将地震波阻抗反演中的目标函数表示为L1范数约束下的L1范数优化问题,并将L1范数用一个平滑函数来近似,从而使得目标函数函数可微。然后将L1范数约束下的基追踪问题转化为无约束最优化问题,并利用基于导数的局部优化方法求解无约束优化问题,求得反射系数,进而计算得到波阻抗。模型和实际资料计算结果均表明该方法可行。