Evidence of melt/rock interaction in the Cr-spinel bearing wehrlite rocks of Bangriposi,India: Implications for nature of the metasomatic agent

Cr-spinel bearing wehrlite rocks of Bangriposi are found within the multiply deformed metasedimentary rocks of Singhbhum Group belonging to North Singhbhum Mobile Belt of eastern India. Detailed mineralogical and geochemical studies reveal that these rocks have suffered a two-stage alteration involving a deeper level modal and cryptic metasomatism and a subsequent shallower depth pervasive hydrothermal alteration. Cryptic metasomatism is defined by elevated LREE contents of the wehrlite and its clinopyroxne grains. Metasomatism induced changes in the modal mineralogy of the rocks include the absence of primary orthopyroxene grains, presence of secondary diopside-phlogopite(now present as vermiculite) defining disequilibrium reaction textures and secondary orthopyroxene rims around serpentinized olivine. The mineralogical and geochemical changes due to the metasomatic event present a contrasting picture in regard to the metasomatic history of the rocks. Possible scenarios involving a single stage or multiple stage metasomatism events have been discussed while explaining the metasomatic reactions that took place. An attempt has been made to estimate the REE concentrations of the final equilibrating melt from REE contents of clinopyroxene grains of the wehrlite. The possibility of the LREE-enriched equilibrating melt of the wehrlite rocks(the deeper level metasomatic agent) being similar to residual melts from the E-MORB type parental melts of nearby gabbro suite has been ruled out by geochemical modeling. REE abundance patterns of several natural enriched melts have been compared with REE pattern of calculated LREE-enriched equilibrating melt of the wehrlite and most resemblance has been observed with calcic and potassic melts. It is therefore suggested that the Cr-spinel bearing wehrlite rocks of Bangriposi has been affected by a calcio-potassic melt in deeper level, prior to the shallow level serpentinization event.     

Ordovician Granitoids and Silurian Mafic Dikes in the Western Kunlun Orogen, Northwest China: Implications for Evolution of the Proto-Tethys

The western Kunlun orogen in the northwest Tibet Plateau is related to subduction and collision of Proto-and Paleo-Tethys from early Paleozoic to early Mesozoic. This paper presents new LA-ICPMS zircon U-Pb ages and Lu-Hf isotopes, whole-rock major and trace elements, and Sr–Nd isotopes of two Ordovician granitoid plutons(466–455 Ma) and their Silurian mafic dikes(～436 Ma) in the western Kunlun orogen. These granitoids show peraluminous high-K calcalkaline characteristics, with(⁸⁷Sr/⁸⁶Sr)_i value of 0.7129–0.7224, ε_Nd(t) values of -9.3 to -7.0 and zircon ε_Hf(t) values of -17.3 to -0.2, indicating that they were formed by partial melting of ancient lower-crust(metaigneous rocks mixed with metasedimentary rocks) with some mantle materials in response to subduction of the Proto-Tethyan Ocean and following collision. The Silurian mafic dikes were considered to have been derived from a low degree of partial melting of primary mafic magma. These mafic dikes show initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7101–0.7152 and ε_Nd(t) values of -3.8 to -3.4 and zircon ε_Hf(t) values of -8.8 to -4.9, indicating that they were derived from enriched mantle in response to post-collisional slab break-off. Combined with regional geology, our new data provide valuable insight into late evolution of the Proto-Tethys.     

碱性玄武岩形成的时限及其地质意义

中国华北克拉通及邻区的早前寒武纪不存在碱性玄武岩。全球范围内碱性玄武岩的形成也存在时限性，它们在中新生代以来相对大量的出现。碱性玄武岩可划分为钾质碱性玄武岩和钠质碱性玄武岩两大类，后者还可作进一步划分。它们在同位素组成和元素组成上存在相互过渡的变化，这与地幔源区外来加入物质的种类和比例不同有关。高压和低程度熔融是所有碱性玄武岩形成的必要条件。研究表明，碱性玄武岩形成具时限性主要与地球热状态从热向冷的历史演化有关。碱性玄武岩的形成需要地幔俯冲作用，可达到相当深度的地幔俯冲作用只是到了太古宙以后才发生，并在中新生代以来达到高潮。     

动物蛋白酶1058水解ti鱼可溶性蛋白质

研究了动物蛋白酶 1 0 58水解鱼是鱼蛋白时 ,酶量、温度、作用时间对鱼是鱼蛋白质水解率和苦味的影响。结果表明 :酶浓度的提高 ,水解时间的延长 ,均使鱼是鱼蛋白水解率明显提高。最适水解温度为 50℃ ,当温度高于 50℃时 ,水解率逐渐下降 ,蛋白酶开始失活。苦味值随水解率提高而增加。用正交试验的方法 ,经综合分析和试验得出 ,该蛋白酶水解鱼是鱼的最佳条件是酶量与底物之比为 1 .5∶ 1 0 0 0 ;温度为 50℃ ;水解时间为 4h。     

华北陆块南缘富碱侵入岩岩石组合及时空分布

华北陆块南缘（河南段）出露的富碱侵入岩类集中分布于卢氏－确山一线。岩石类型主要分为三大类：①碱性岩类，即含有似长石或碱性暗色矿物的正长岩类；②碱性花岗岩类，包括钠铁闪石花岗岩以及孪生的钾长花岗岩类；③石英正长岩类，包括碱性长石为主的石英正长岩、英碱正长岩和花岗正长（斑）岩类。在空间上构成一条富碱岩浆岩带，据岩石组合自北而南划为三个亚带：北部碱性岩亚带、中部碱性花岗岩类亚带和南部石英正长（斑）岩亚带。在形成时间上富碱岩浆活动集中于晚元古代末期（７００Ｍａ±）和海西晚期（３００Ｍａ±）。     

北山—阿拉善地区二叠—三叠纪富碱侵入岩的岩石学特征

甘肃北山－内蒙古阿拉善地区发育有一套以正长岩、石英正长岩、霓辉正长岩、霓霞正长岩类为代表，包括碱性辉长岩、二长岩、石英二长岩、碱长花岗岩和碱性花岗岩等类岩石在内的富碱侵入体。本文总结了它们的空间分布、形成时代、产状、岩石组合和岩石化学特征；指出它们具有近东西向的分布特征，主体形成于二叠－三叠纪时期，具有富碱、碱性岩类的岩石化学特征，构成一条富碱侵入岩带；认为其时空分布特点与华北地台、塔里木地台北缘及邻区碱性岩带一致，是华北－塔里木北缘及邻区巨型碱性岩带的重要组成部分。     

新疆北部花岗岩类的稀土特征

新疆北部的改造系列花岗岩演化由斜长花岗岩阶段、钾长花岗岩阶段至碱长花岗岩阶段,其稀土配分组成递降曲线簇.新疆北部的同熔型花岗岩类稀土配分基本为轻稀土富集型,具Eu负异常,有递增曲线簇和递降曲线簇两种情况.深源碱性系列轻重稀土比值大、Eu负异常一般不显著.文中还叙述了新疆北部的幔分异系列花岗岩类及一些古老花岗岩的稀土特征.     

燕辽三叠纪碱性偏碱性杂岩体地球化学特征及意义

华北地台北部燕辽地区发现一批三叠纪(245—195Ma)碱性或偏碱性杂岩体。这些杂岩体均贫硅,绝大多数富含铁、镁、钾、磷和稀土等不相容微量元素。~(87)Sr/~(86)Sr初始值为0.7055—0.7057,它们可能源自被交代蚀变的上地幔。结合燕辽地区三叠系的分布及构造形变的研究,表明该地区三叠纪存在构造岩浆活动带,它是本地区印支运动的重要表现。     

不同磷源对米氏凯伦藻生长和碱性磷酸酶活性的影响

为了解米氏凯伦藻(Karenia mikimotoi)赤潮形成的磷营养机理,作者研究了不同磷源[三磷酸腺苷二钠盐(Adenosine disodium triphosphate,ATP)、甘油磷酸钠(sodium glycerophosphate,G-P)、卵磷脂(lecthin,LEC)和Na H2PO4·2H2O]对其生长和藻细胞碱性磷酸酶活性(alkaline phosphatase activity,APA)的影响。结果表明:(1)米氏凯伦藻可以有效利用无机磷(Na H2PO4·2H2O),对有机磷源如三磷酸腺苷二钠盐(ATP)、甘油磷酸钠(G-P)也能有效利用,但不能有效利用卵磷脂(LEC);(2)米氏凯伦藻碱性磷酸酶的检测中,在起始阶段,不同磷源(ATP,G-P,LEC和Na H2PO4·2H2O)的米氏凯伦藻APA达到最大值,米氏凯伦藻的APA分别为6.0,10.5,8.0和0.4 pmol/(个·h)。随培养时间的持续,各有机磷培养基中米氏凯伦藻的APA均表现出先逐渐减小,而后增强,最后在最大值维持的趋势,而以Na H2PO4·2H2O为磷源的米氏凯伦藻的APA没有明显的增加;(3)单个细胞的米氏凯伦藻的APA位点分布明显,大致位于细胞表面。通过研究发现,米氏凯伦藻在外界环境无机磷限制的条件下,能够较好地吸收利用有机磷维持生长,印证了近年来米氏凯伦藻赤潮频繁地发生在磷限制海域的事实。     

三疣梭子蟹(Portunus trituberculatus)肝胰腺内源酶性质的初步研究

内源酶是三疣梭子蟹(Portunus trituberculatus)体内重要的酶,往往会导致梭子蟹死后肌肉组织迅速软化,严重影响了蟹肉的贮藏品质。为了探明该酶的基本特性,本试验从三疣梭子蟹肝胰腺中提取了粗酶,优化了提取方法,并对其部分酶学性质进行初步研究。结果表明:三疣梭子蟹肝胰腺内源酶最佳浸提时间段为4～12 h,酶比活显著高于0～4 h和12～14 h;以酪蛋白为水解底物,内源酶作用最适温度为65℃、最适p H范围为7.0～8.0;丝氨酸蛋白酶特异性抑制剂,包括大豆胰蛋白酶抑制剂(SBTI)和苯甲基磺酰氟(PMSF),对内源酶活力的相对抑制率分别为100%、70.46%±6.27%,显著高于其他抑制剂的相对抑制率,推测丝氨酸蛋白酶为主要内源酶;在硫酸铵分级沉淀中,分别以酪蛋白和Boc-Phe-Ser-Arg-MCA为底物,前者最适盐析浓度为0～70%,后者为30%～70%,酶比活显著高于其他盐浓度;当硫酸铵浓度为40%～60%时,盐析蛋白质含量、粗酶酶活和丝氨酸蛋白酶活均显著高于其他盐浓度。