浙江青田石平川钾长花岗岩特征及其成因探讨

青田县石平川钼矿床是浙江省现已发现的规模最大的钼矿床,多数人认为石平川钼矿床的形成与钾长花岗岩有密切关系。本文主要从岩相学、岩石地球化学、LA—ICPMS锆石U—Pb年代学等方面研究石平川钾长花岗岩,并探讨其成岩环境及成因。研究表明,石平川岩体属于高钾钙碱性、弱过铝质S型花岗岩,其形成于早自垩世晚期挤压环境,源岩物质主要是壳源,并有少部分幔源物质成分参与。     

腾冲火山活动的时代和岩浆来源问题

47个腾冲火山岩样品的K-Ar年龄值域在0.09和17.84Ma之间。4条火山岩的⁴⁰Ar/³⁶Ar-⁴⁰K/³⁶Ar等时线年龄分别为2.93、0.81、0.31和0.13Ma。火山喷发的时代从中新世到更新世,喷发的高潮在晚更新世。腾冲火山目前还不是死火山,而腾冲及其邻区的热事件（侵入-热变质-喷发）又是连续发生的。20个样品的Rb和Sr含量、稳定Sr同位素初始比（0.70578-0.71437）以及其它地球化学资料还表明,这些火山岩是属于板块碰撞带生成的高钾钙碱性岩浆系列。火山岩的母岩浆来源于地幔的玄武岩浆,但在上升过程中受到过富含放射性成因Sr的地壳物质的强烈渐进混染。     

New unspiked K–Ar ages of volcanic rocks of the central and western sector of the Aeolian Islands: reconstruction of the volcanic stages

A geochronological study of the Filicudi, Salina, Lipari and Vulcano Islands (Aeolian Archipelago) using the unspiked potassium–argon technique provides new age data which, combined with stratigraphic correlation, better constrain the temporal evolution of volcanism. The unspiked K–Ar age of the oldest exposed lavas on Filicudi, 219±5 ka, is significantly younger than the previous estimation of 1.02 Ma. In the general context of Aeolian volcanism, this new date suggests that the volcanism of the western sector of the Aeolian Archipelago is younger than previously thought. Geochronological data point out on the rapid transition from calc–alkaline to potassic volcanism. The distribution of the K–Ar ages within the Salina–Lipari–Vulcano group shows that the volcanism started on Lipari and propagated over time northward on Salina and southward on Vulcano. Geochronological and geophysical data suggest that the onset of volcanism in the central sector of the Aeolian Arc may be due to a mantle upwelling structure located below Lipari. A change in the style of the eruptions occurred in the Salina–Lipari–Vulcano system at about 100 ka from the present. Low-energy magmatic eruptions occurred between 188 and about 100 ka. From about 100 ka to the present, higher-energy eruptions and low-energy events due to magma–water interaction also occurred. This change in the style of activity, together with the appearance of evolved products (i.e. rhyolites) during the last 50 ka, is consistent with the formation of magmatic reservoirs located at shallower depth with respect to those of the 188–100-ka period. The new geochronological data and available petrological models reveal that a change in the deep source of the primary magmas occurred in a relatively short time interval.     

The <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar geochronology constraint and geological significance of mylonites in Shangyi-Chicheng fault belt on the north of North China Craton

A dating of two biotite samples taken from the meso- and low-temperature mylonites within the Shangyi-Chicheng fault belt on the north of the North China Craton yields ⁴⁰Ar/³⁹Ar isotopic ages of (399 ± 1) Ma and (263 ± 2) Ma, respectively. These data reflect an Early Devonian deformation and a Late Carboniferous retrograde metamorphism event along the fault, suggesting that the tectonic activities of the North China Craton in Paleozoic should be reconsidered.     

K–Ar ages of the Akan-Shiretoko volcanic chain lying oblique to the Kurile trench: Implications for tectonic control of volcanism

The Akan‐Shiretoko volcanic chain, situated in the Southwestern Kurile arc, consists mainly of nine subaerial andesitic stratovolcanoes and three calderas. The chain extends in a SW–NE direction for 200 km, situated oblique to the Kurile trench at an angle of 25 degrees. Thirty‐seven new K–Ar ages, plus previous data, suggest that volcanic activity along the Akan‐Shiretoko volcanic chain began at ca 4 Ma at Akan, at the southwestern end of the chain, and systematically progressed northeastward, resulting in the southwest‐northeast‐trending volcanic chain. This spatial and temporal distribution of volcanoes can be explained by anticline development advancing northeastward from the Akan area, accompanied by magma rising through northeast‐trending fractures that developed along the anticlinal axis. The northeastward development of the anticline caused uplifting of the Akan‐Shiretoko area and changed the area from submarine to subaerial conditions. Anticline formation was likely due to deformation of the southwestern Kurile arc, with southwestward migration of the Kurile forearc sliver caused by oblique subduction of the Pacific plate. The echelon topographic arrangement of the Shiretoko, Kunashiri, Etorofu and Urup was formed at ca 1 Ma.     

Postshield stage transitional volcanism on Mahukona Volcano, Hawaii

Age spectra from ⁴⁰Ar/³⁹Ar incremental heating experiments yield ages of 298 ± 25 ka and 310 ± 31 ka for transitional composition lavas from two cones on submarine Mahukona Volcano, Hawaii. These ages are younger than the inferred end of the tholeiitic shield stage and indicate that the volcano had entered the postshield alkalic stage before going extinct. Previously reported elevated helium isotopic ratios of lavas from one of these cones were incorrectly interpreted to indicate eruption during a preshield alkalic stage. Consequently, high helium isotopic ratios are a poor indicator of eruptive stage, as they occur in preshield, shield, and postshield stage lavas. Loihi Seamount and Kilauea are the only known Hawaiian volcanoes where the volume of preshield alkalic stage lavas can be estimated. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

祁连山西段新元古代晚期花岗质片麻岩成因及LA-ICP-MS锆石U-Pb定年

祁连山西段吊大坂新元古代花岗质片麻岩出露于北大河岩群二云母片麻岩中。地球化学特征显示,吊大坂新元古代花岗质片麻岩主要为碱性、弱过铝质花岗岩(A/CNK=1.04~1.12)。岩石主体Rb含量较低,Sr和Ba含量高,K/Rb值介于179~225之间,说明吊大坂新元古代花岗质片麻岩不是高分异花岗岩,但明显的负Eu异常（Eu/Eu?=0.25~0.35）,说明该岩浆经历了弱的分离结晶作用。在(Al2O3+TFeO+MgO+TiO2)-Al2O3/(TFeO+MgO+TiO2)图解中,未经历强烈分异的花岗质岩石样品点落入地壳杂砂岩或中性岩浆岩源区。未经历强烈分异的样品富集强不相容元素,并且在Y-Nb和(Y+Nb)-Rb图解中,主体落入板内花岗岩区域。吊大坂花岗质片麻岩LA-ICP-MS锆石206Pb/238U年龄为736±5Ma,该年龄被解释为花岗质片麻岩的形成时代,说明祁连山存在750~730Ma的岩浆作用记录,可能为新元古代晚期伸展背景下的产物。祁连山新元古代岩浆活动记录了新元古代早期汇聚、新元古代晚期伸展到裂解的长期演化过程。     

青海格尔木哈希牙地区中基性岩墙群地球化学特征与LA-ICP-MS锆石U-Pb年龄

位于东昆仑造山带上的东昆北哈希牙地区发育中基性岩墙群。其岩性主要为辉绿岩、闪斜煌斑岩和闪长玢岩,地球化学数据显示其具有高钾钙碱性玄武岩系列特征。轻、重稀土元素存在较高程度分馏,LREE/HREE值为4.72~8.66,平均值为6.57。δEu值介于0.81~0.98之间,平均值为0.91,显示出微弱的负Eu异常,表明斜长石的分离结晶作用不明显,富集Rb、Ba、Pb、K等大离子亲石元素,贫高场强元素Ta、Nb、Zr、Hf等地球化学特征,主体显示板内玄武岩特征,但有来自俯冲带的部分信息。采用LA-ICP-MS技术对锆石进行了U-Th-Pb同位素测定,结果显示锆石年龄较为分散,其中8颗岩浆锆石给出的206Pb/238U年龄加权平均值为411.5±7.5Ma,代表了格尔木哈希牙地区辉绿岩墙的结晶年龄,反映东昆北地块于晚志留世—早泥盆世已由地体碰撞的挤压状态转为碰撞后伸展状态,标志着该地区加里东期构造旋回的结束。     

南极南设得兰群岛中-新生代火山作用与地质环境

本文对采自南设得兰群岛的乔治王岛、纳尔逊岛、利文斯顿岛、欺骗岛和南极半岛的火山岩和火山灰进行了岩石化学和Sr、Nd同位素分析，Ar-Ar和K－Ar年龄测定。研究表明，南设得兰群岛火山岩属于玄武岩－安山岩－英安岩岩石组合，安们的Sr、Nd同位素比值非常接近，^87Sr/^86Sr比值普遍比较低，为0．703297－0．703507；^143Nd/^144Nd比值普遍比较高，为0．512835－0．513779，二者呈负相关，εNd-^87Sr/^86Sr相关图显示岩浆来源于亏损地幔。火山岩形成时代集中于96Ma、91Ma、78Ma、60Ma和35Ma等时段。35Ma之后，火山活动长时间消沉，直到晚中新世和第四纪才时有发生；这一漫长的历史时期，正是南极大陆冰盖逐渐形成之时。是气候变冷抑制了火山活动？还是火山活动的减弱和停止导致气候变冷？尚待进一步研究；但冷期火山活动减弱或停止，暧期火山活动活跃和增强，这一对应关系是存在的。火山作用的时空分布及岩石地球化学特征暗示，南设得兰群岛处于一个岛弧的地质环境，早期群岛基本上与南极半岛连在一起，在德雷克板块的俯冲下，群岛逐渐与半岛分离，形成布兰斯菲尔德海峡（裂谷），在弧后扩张和裂谷作用下产生新的火山活动。     

Groundwater dating with 3H and SF6 in relation to mixing patterns,transport modelling and hydrochemistry

A comprehensive study of a sandy aquifer of deltaic origin in southern Poland included water chemistry, isotopes, dissolved trace gases and transport modelling. Tritium, sulphur hexafluoride (SF₆) and freons (F‐11, F‐12 and F‐113) showed the presence of modern waters in the recharge areas and shallow confined parts of the aquifer. The presence of older Holocene waters farther from the recharge areas was indicated by lack of ³H, SF₆ contents ≤0·02 fmol l⁻¹ and relatively low ¹⁴C values. The discharge from the system is by upward seepage in the valley of a major river. Pre‐Holocene waters of a cooler climate, identified on the basis of δ¹⁸O, δ²H, ¹⁴C, Ne and Ar data, were found in some distant wells. Concentrations of N₂, Ne and Ar determined by gas chromatography were used for calculating the noble gas temperatures, air excess needed for correction of SF₆, and nitrogen content released by denitrification process. The time series of ³H content available for some wells supplied quantitative information on age distributions and the total mean ages of flow through the unsaturated and saturated zones. The derived ³H age distributions turned out to be very wide, with mean values in the range of about 30 to 160 years. For each well with determined ³H age, the SF₆ data showed either a lower age range or the possibility of a lower age as expected due to shorter travel times of SF₆ through the unsaturated zone, which most probably also resulted in different types of age distributions of these tracers. Freons appeared to be of little use for individual age determinations. A quantitative estimation of two‐component mixing from SF₆ ³H relations is not possible unless the travel time of ³H through the unsaturated zone is comparable to that of SF₆. The ratio of integrals of the response function over the age range with tracer and the whole response function yields the ratio of water with tracer to total flow of water. That ratio is a tracer‐dependent function of time. Transport modelling of SF₆ tracer done with MT3D code yielded initially large discrepancies between calculated and measured tracer concentrations. Some discrepancies remained even after calibration of the transport model with SF₆. Simulation of tritium contents with a calibrated transport model yielded reasonable agreement with measured contents in some wells and indicated a need for further investigations, particularly in the eastern part of the aquifer. The existence of distinct hydrochemical zones is consistent with the tracer data; young waters with measurable ³H and SF₆ contents are aerobic and of HCO₃ Ca or HCO₃ SO₄ Ca types. Slightly elevated Na and Cl contents, as well as the highest concentrations of SO₄ and NO₃ within this zone are due to anthropogenic influences. Anaerobic conditions prevail in the far field, under the confining cover, where pre‐bomb era Holocene waters dominate. In that zone, dissolved oxygen, NO₃ and U contents are reduced, and Fe, Mn and NH₄ contents increase. In the third zone, early Holocene and glacial waters occur. They are of HCO₃ Ca Na or HCO₃ Na types, with TDS values higher than 1 g l⁻¹ and Na content higher than 200 mg l⁻¹, due to either small admixtures of ascending or diffusing older water or freshening of marine sediments, a process that is probably occurring till the present time. Copyright © 2005 John Wiley & Sons, Ltd.