电感耦合等离子体发射光谱法测定键合用硅铝丝中硅铁铜

采用电感耦合等离子体发射光谱法测定硅铝丝（Al—1％Si）中Si及杂质元素Fe和Cu。确定了最少取样量和样品溶解方法，优化了元素分析谱线和仪器的测量条件。实验表明，方法的加标回收率为99％～1叭％，相对标准偏差（n=6）低于1．4％，Si、Fe、Cu的检出限分别为8．5、1．0和0．4μg／L。该方法应用于快速测定键合硅铝丝中的各种元素，结果满意。     

微波消解-等离子体发射光谱法同时测定水中硅铁钠

讨论使用电感耦合等离子体发射光谱法测定水样中si、Fe、Na时，四种水样前处理方法对测试结果的影响。提出采用HNO3^-HF体系微波消解、H3BO3掩蔽HF的方法前处理水样，用等离子体发射光谱法可同时准确快速地测定水中Si、Fe、Na三种元素的含量。5次测定的相对标准偏差小于4％，加标回收率为89．2％-106％。     

GIS辅助的吴淞工业区铺设道路扬尘估算

本文以上海市的吴淞工业区为研究对象,借鉴美国EPA提出的AP-42方法,利用动力学粒径谱仪的粒径分析结果对公式系数进行修正,在GIS手段的辅助下对吴淞工业区铺设道路不同粒径的扬尘量进行估算,最终由V isualBasic语言和MapObjects2.0组件建立的铺设道路扬尘管理信息系统表明GIS的使用有利于加强扬尘污染的研究和控制。     

基于岩石变形声发射实验结果讨论岩石失稳的可预测性

根据室内岩石变形声发射实验结果,计算了声发射序列的地震非均匀度GL值,并以此探讨了岩石破裂失稳的可预测性。在双轴压缩、等速率加载条件下,含障碍体断层、挤压雁列断层和Ⅲ型剪切断层等非连续岩石标本在临近滑动失稳前,声发射活动均出现了显著的均匀—非均匀的状态变化,表现为GL值出现持续大于1的异常变化,GL值异常的位置与破裂成核部位相重合,并与断层走向一致;改变统计窗长、窗内分割数及能级统计下限计算声发射序列的GL值,结果表明,GL值计算结果具有一定的稳定性。综合分析认为,地震非均匀度(GL值)可以较好地刻画岩石失稳前夕因破裂成核导致的声发射活动在时间分布上的状态变化,GL值持续异常是岩石失稳的显著性标志,对预测岩石失稳具有较好的指示意义。     

Seismic diagnosis of railway substructures by using secondary acoustic emission

One difficult task for the seismic diagnosis of existing structures is how to nondestructively evaluate the damage degree of invisible substructures, such as embedded foundations. To diagnose substructures efficiently, a method for nondestructive inspection is developed by applying acoustic emission (AE) technique. As a newly proposed method, characteristics of secondary AE induced by train operations were investigated, and experiments using model piles and in-situ AE monitoring of in-service railway bridges conducted under railroad traffic, from which it was demonstrated that the proposed method is practicable enough to detect invisible defects in structures. A new index, known as RTRI (ratio of Repeated Train load at the onset of AE activity to Relative maximum load for Inspection period) is proposed for structural damage qualification based on the results of in-situ AE monitoring.     

Fracture in Westerly Granite under AE Feedback and Constant Strain Rate Loading: Nucleation, Quasi-static Propagation, and the Transition to Unstable Fracture Propagation

New observations of fracture nucleation are presented from three triaxial compression experiments on intact samples of Westerly granite, using Acoustic Emission (AE) monitoring. By conducting the tests under different loading conditions, the fracture process is demonstrated for quasi-static fracture (under AE Feedback load), a slowly developing unstable fracture (loaded at a `slow' constant strain rate of 2.5 × 10<sup>−6</sup> /s) and an unstable fracture that develops near instantaneously (loaded at a `fast' constant strain rate of 5 × 10⁻⁵ /s). By recording a continuous ultrasonic waveform during the critical period of fracture, the entire AE catalogue can be captured and the exact time of fracture defined. Under constant strain loading, three stages are observed: (1) An initial nucleation or stable growth phase at a rate of ~ 1.3 mm/s, (2) a sudden increase to a constant or slowly accelerating propagation speed of ~ 18 mm/s, and (3) unstable, accelerating propagation. In the ~ 100 ms before rupture, the high level of AE activity (as seen on the continuous record) prevented the location of discrete AE events. A lower bound estimate of the average propagation velocity (using the time-to-rupture and the existing fracture length) suggests values of a few m/s. However from a low gain acoustic record, we infer that in the final few ms, the fracture propagation speed increased to 175 m/s. These results demonstrate similarities between fracture nucleation in intact rock and the nucleation of dynamic instabilities in stick slip experiments. It is suggested that the ability to constrain the size of an evolving fracture provides a crucial tool in further understanding the controls on fracture nucleation.     

水对不同岩石声波速度影响的研究

通过分析不同成因类型岩石的声波速度,提出了水对不同岩石声波速度的影响,从岩石孔隙及隐微裂隙的发育程度及岩石的水理性质解释了在水的作用下岩石声波变化规律,利用这些规律可以初步判断岩石的隐微裂隙发育程度及水理性质。     

声波测井岩石波速统计分析

通常不同岩性的声波速度不同,同一岩性因裂隙发育和风化程度不同,声波速度也不相同。声波测井技术就是依据岩层的这一特性,划分不同岩层及岩层的风化破碎程度。这里对某铁路线的勘测的声波测井结果进行统计分析,给出了测区钻孔揭露的主要岩石较完整状态的声波波速统计值和异常发育概率统计。     

起伏地表条件下的声波散射数值模拟的积分方程法

从散射理论的角度来看,起伏地表可以看作是一种特殊的扰动介质,因此应用散射积分方程求解起伏地表条件下的散射场在理论上是可行的。从三维频率域声波方程出发,由格林函数定理,得出起伏地表条件下的散射积分方程。散射积分方程为关于起伏地表的面积分和与速度扰动体有关的体积分之和,同时给出了格林函数在奇异点的积分方法。由于数值离散求解积分方程存在着计算时间太长和存储内存不足的问题,采用电磁散射积分方程的拟解析近似的方法。在假设反射函数为缓变函数的基础上,最终得到其近似表达式,因此散射场的数值求解不必再借助于代数方程组,只要进行数值积分即可。这种方法避开了传统数值计算方法存在的问题,为地震散射波场快速正演模拟打下了基础。理论分析表明,这种方法适用于小扰动的问题。当扰动较大时,拟解析近似会产生较大的误差。     

中国城市固体废弃物甲烷排放研究

The greenhouse effect of methane (CH4) is only inferior to that of carbon dioxide (CO2). As an important anthropogenic emission source, the calculation of the emission amount of CH4 from waste treatment in landfills plays an important role in compiling greenhouse gases inventory and in estimating the climate change effects caused by increasing of greenhouse gases. Based on the previous work, and according to the sampling and analysis on municipal solid waste (MSW) in typical cities, the degradable organic carbon (DOC) percentile was identified in typical cities in recent years. According to the IPCC greenhouse gases inventory guideline and default method of CH4 emission from MSW landfills, and in light of MSW managing situation in different regions, the amount of CH4 emission was calculated. The results show that the amount of CH4 emission decreases geographically from east to west and it increases temporally from 1994 to 2004 in China.