Approaches to equilibrium in the distribution of trace elements among the principal minerals in a high-grade metamorphic terrane

X-ray fluorescence, instrumental neutron activation, and particle-induced X-ray emission methods were used to determine the distribution of numerous trace elements among garnet (Grt), Ca-pyroxene (Cpx), hornblende (Hbl), biotite (Bt), plagioclase (Pl) and K-feldspar (Kf) in a high-grade metamorphic terrane within the Grenville Province of the Canadian Shield. Results are presented as distribution formulae, e.g. Sr: Kf 1.1 Pl 16 Hbl 2.2 Cpx 1.0 Bt 1.2 Grt Sc: Hbl 1.1 Cpx 1.0 Grt 7.8 Bt 22 Pl 2.6 Kf V: Hbl 1.15 Bt 2.07 Cpx 6.0 Grt (1.4% CaO)>1 (Pl, Kf) Zn: Bt 1.6 Hbl 1.62 Cpx 2.9 Grt 10 Pl Ga: Bt 1.2 Hbl 1.2 Pl 2.5 Cpx 1.3 Grt where numbers are distribution ratios, e.g. ppm Sr in Hbl/ppm Sr in Cpx=2.2. Examples of inter-element similarities and differences are (a) both Rb and Cs are concentrated in biotite relative to K-feldspar, but for Rb the ratio is 2.3 and for Cs it is 16, (b) the distribution formulae for seven lanthanides are similar except for the position of garnet, e.g. Ce: Hbl 2.7 Cpx 2.8 Pl 1.1 Bt 11 Kf 16 Grt Yb: Grt 2.8 Hbl 2.7 Cpx 9 Pl 1.0 Bt 7 Kf and (c) all of Sr, eight lanthanides, Zr, V and Cr are concentrated in hornblende relative to Ca-pyroxene by a factor that lies in the narrow range of 2.2–3.1. There is a larger variation (departure from the mean) in some distribution ratios than in others. Thus the mean ratios (Hbl/Cpx) for each of six elements and in parentheses the percentage relative standard deviation are Zn 1.62 (8.6), V 2.38 (12), Cr 2.42 (18), Sr 2.7 (28), Ba 2.9 (36) and Ni 1.66 (38). We suggest that variation of this kind is the result of differences from place to place in the magnitude of deformation and recrystallization (which facilitated the rearrangement of atoms), combined with rates of lattice and crystal-boundary diffusion that are unique for the various elements, thus permitting some trace elements to approach equilibrium more closely than others.     

民用P(Y)码伪距的精度分析及其在单点定位中的应用

民用GPS双频接收机主要采用互相关技术和Z跟踪技术消除或减弱A-S(Anti-Spoofing)的影响,获取P(Y)码伪距观测值。文中对两种技术获取的P(Y)码伪距的精度进行了理论分析和实测数据的验证。民用GPS双频接收机获取P(Y)码伪距的意义在于消除或减弱电离层延迟误差的影响,进而提高定位的精度,文中结合单点定位给出了例证。     

桂西巴马地区极高Ti/Y 值基性岩地球化学特征——来自峨眉山地幔柱高Ti母岩浆？

桂西地区位于扬子地块西南缘,越北地块以北。桂西巴马等地出露层状—似层状基性岩（辉绿岩和玄武岩）,该地区的基性岩成因对于理解该区构造—岩浆作用具有十分重要的意义。对桂西巴马基性岩进行了岩石学和地球化学研究,对其岩石成因和岩浆源区特征进行了讨论。研究表明,桂西巴马基性岩属于碱性玄武质岩,相对富集轻稀土元素和Nb、Ti等微量元素,与峨眉山大火成岩省高Ti玄武岩相似,说明其与峨眉山地幔柱具有相关性。然而,对比峨眉山高Ti玄武岩,巴马基性岩表现出更高的Ti/Y值。不相容元素比值特征表明,桂西巴马基性岩岩浆演化呈现更高的Nb/Y值等演化趋势。结合Dy/Dy?与Dy/Yb、Ti/Y的协变关系,对桂西基性岩与峨眉山玄武岩岩浆源区中稀土元素的分异特征进行判别,揭示出桂西巴马基性岩和峨眉山高Ti玄武岩具有同源性。然而,巴马基性岩地幔熔融程度更低,可能是峨眉山大火成岩省外带的地幔柱岩浆作用延伸的结果,代表了峨眉山地幔柱高Ti玄武岩母岩浆的特征。     

GPS双频接收机C/A码与P码伪距精度的分析和比较

本文主要研究GPS双频接收机C/A码和P码伪距的精度问题,首先阐述了保密P(Y)码伪距的测量原理,然后采用自行编制的精密单点定位程序,利用大量IGS跟踪站观测数据进行了试算,对该问题进行了探讨和分析,结论认为C/A码和P1码伪距的精度基本相同,而P2码伪距观测值的精度较低。     

Aperture synthesis observations of HCN J=1-0 emission from Y canum venaticorum

We have made high resolution observations of HCN (1-0) emission from the carbon star Y Canum Venaticorum using the Nobeyama Millimeter Array. We find that the emission region is not well resolved by the synthesized beam of 3.7 × 4.6 over the entire velocity range (V_LSR =10 to 35 km s^–1). We find that the true brightness temperature probably exceeds 200 K at many velocity channels as well as at the 26 km s^–1 maser spike. The broad emission component may be the result of superimposed maser spikes. The high brightness requires an unreasonably high HCN fractional abundance if LTE is assumed. It is likely that the HCN abundance previously reported for the star is considerably affected by the maser action. A new maser spike has been found at V_LSR = 29 km s^–1     

Composition and origin of intermediate solid solutions in the system thorite–xenotime–zircon–coffinite

A comprehensive survey of the accessory-mineral assemblages in Variscan granites of the German Erzgebirge and Pan-African granites from Jordan revealed the occurrence of intermediate solid solutions of the tetragonal thorite–xenotime–zircon–coffinite mineral group with partially novel compositions. These solid solutions preferentially formed in evolved and metasomatically altered, P-poor leucogranites of either I- or A-type affinity. Thorite from the Erzgebirge contained up to 18.8 wt.% Y₂O₃, 16.1 wt.% ZrO₂, and 23.3 wt.% UO₂. Xenotime and zircon have incorporated Th in abundances up to 36.3 wt.% and 41.8 wt.% ThO₂, respectively. Extended compositional gradation with only minor gaps is confined to hydrated members of this mineral group, and is observed to exist between thorite and xenotime, thorite and coffinite, and Y–HREE-bearing thorite and zircon. Complex, hydrous solid solutions containing elevated abundances of three or more of the endmembers are subordinate. Previously reported intermediate solid solutions between anhydrous zircon and xenotime, and anhydrous zircon and thorite, are not observed and are in conflict with experimental work demonstrating very limited miscibility between anhydrous species of endmember composition. The majority of hydrous intermediate solid solutions in the Th–Y–Zr–U system are likely thermodynamically unstable. Instead, they are probably metastable responses to unusual physico-chemical conditions involving various parameters and conditions, the relative importance of which is incompletely known. Leaching and dissolution of preexisting accessory phases during interaction with F-bearing hydrous fluids enriched in Th, Y(HREE), Zr, and/or U, and common deposition of the various elements at disequilibrium (supersaturation) seems to play a key role, but other processes may be of similar importance. Experimental work involving hydrous conditions and complex systems composed of more than two endmembers are needed to shed light into the stability relations of the chemically uncommon compositions treated in this study.     

超稳定Y型沸石为载体的新型Ni-Mo环境催化剂

在经济高速发展的今天,必须注意保护和改善我们赖以生存的地球环境：既要尽量减少污染,又需加强对已有污染物的处理。能源（煤、石油、天然气）的利用是工业革命的强大推动力,但也是污染地球环境的主要来源。因此,我们必须提高能源的利用效率,减少其中污染物的含量,从而减少能源的利用对环境的污染,同时加强治理能源工业和利用所产生的污染物,例如石油残渣。在石油和液化煤的提炼过程,所利用的主要是催化的氢化和氢气裂解反应。工业上最常用的催化剂是以γＡｌ２Ｏ３为载体,Ｃｏ或Ｎｉ为促进剂的Ｍｏ或Ｗ的硫化物。但是,由于北…     

厚藤共生真菌(Fusarium oxysporum Y24-2)胞外多糖的化学组成和结构研究

从厚藤共生真菌(Fusarium oxysporum Y24-2)发酵液中提取得到胞外多糖,以Q-Sepharose Fast Flow阴离子交换柱和Superdex S-75凝胶色谱柱对其进行分离纯化,得到纯度高的多糖组分F1S。采用HPGPC和HPLC对F1S的分子量及单糖组成进行分析,结果表明F1S主要由Man、Glc和Gal组成,其摩尔比为1.0∶1.9∶2.1,分子量为37.3kD。F1S的GC-MS和1D,2D-NMR分析表明,该多糖是以→6)-β-Galf(1→为主链,以→2)-α-Glcp(1→,α-Glcp(1→和β-Manp(1→为支链的杂多糖,支链取代于→6)-β-Galf(1→的O-2位。该厚藤共生真菌的胞外多糖为富含呋喃型半乳糖的结构新颖的具有多分支结构的中性杂聚多糖。     

Characterisation of early Archaean chemical sediments by trace element signatures

Rare earth element (REE) plus yttrium (Y) patterns of modern seawater have characteristic features that can be used as chemical fingerprints. Reliable proxies for marine REE+Y chemistry have been demonstrated from a large geological time span, including Archaean banded iron formation (BIF), stromatolitic limestone, Phanerozoic reef carbonate and Holocene microbialite.Here we present new REE+Y data for two distinct suites of early Archaean (ca. 3.7-3.8 Ga) metamorphosed rocks from southern West Greenland, whose interrelationships, if any, have been much debated in recent literature. The first suite comprises magnetite-quartz BIF, magnetite-carbonate BIF and banded magnetite-rich quartz rock, mostly from the Isua Greenstone Belt (IGB). The REE+Y patterns, particularly diagnostic anomalies (Ce/Ce*, Pr/Pr*), are closely related to those of published seawater proxies. The second suite includes banded quartz-pyroxene-amphibole±garnet rocks with minor magnetite from the so-called Akilia Association enclaves (in early Archaean granitoid gneisses) of the coastal region, some 150 km southwest of the IGB. Rocks of this type from one much publicised and highly debated locality (the island of Akilia) have been identified by some workers [Nature 384 (1996) 55; Geochim. Cosmochim. Acta 61 (1997) 2475] as BIF-facies, and their ¹³C-depleted signature in trace graphite interpreted as a proxy for earliest life on Earth. However, REE+Y patterns of the Akilia Association suite (except for one probably genuine magnetite-rich BIF from Ugpik) are inconsistent with a seawater origin. We agree with published geological and geochemical (including REE) work [Science 296 (2002) 1448] that most of the analysed Akilia rocks are not chemical sediments, and that C-isotopes in such rocks therefore cannot be used as biological proxies.Application of the REE+Y discriminant for the above two rock suites has been facilitated in this study by the use of MC-ICP technique which yields a more complete and precise REE+Y spectrum than was available in many previous studies.     

浅析计算机2000年问题及其在微机上的检测

对计算机２０００ 年问题的成因及其在计算机应用领域造成的影响进行了分析, 并提出了解决２０００ 年问题的测试方法和解决方案