李坝金矿床金的赋存状态与选矿工艺学

李坝大型金矿床是产于西秦岭上古生代沉积岩系中类卡林型金矿床典型代表。通过显微镜及选矿实验查定了李坝金矿床金的赋存状态，矿床金矿物呈微细粒多种独立矿物出现，金的赋存形式多样，显示多期多阶段成矿特点，成为划分类卡林型金矿的重要参考。矿石工艺学的研究对工业选矿有指导意义。     

东秦岭上宫金矿流体成矿作用:矿物学研究

通过对上宫金矿矿物学资料的研究，确定其成矿过程具有3阶段演化特征。早阶段以粗粒乳白色石英脉为标志，矿物破碎、变形明显，金和杂质成分含量低，形成于挤压构造背景下静岩压力的变质流体。中阶段发育细粒多金属硫化物-碲化物-自然元素组合，呈微细网脉浸染于共轭节理或裂隙，没有遭受变形，金和杂质成分含量高，自然金与其他矿物属共沉淀关系，由变质流体沸腾导致，而流体沸腾则由造山过程的地壳快速隆升剥蚀引起。晚阶段发育具梳状构造的石英-碳酸盐网脉，含金性较低，由静水压力的大气降水热液在伸展构造背景下贯入张性裂隙形成。矿床地质地球化学特征与造山型金矿一致，成矿过程同步于陆陆碰撞造山作用，属于典型的断控脉状造山型金矿，成因适合于CMF模式。     

西秦岭三个典型金矿床稳定同位素地球化学特征

据八卦庙金矿、李坝金矿、小沟里金矿稳定同位素研究,金矿床δ34S比正常沉积岩变化范围窄,比岩浆-火山岩型矿床宽,硫源是海水硫酸盐还原硫与深部热液来源硫所组成的混合硫。石英包裹体流体氢、氧同位素分布于岩浆水、大气降水的重叠过渡区,更靠近岩浆水区,岩浆水的同位素特征更明显。八卦庙金矿石英脉3He/4He高于地壳3He/4He值(n×10-8),低于地幔3He/4He值(n×10-5),为壳-幔混合源。上述同位素地球化学证据表明,金成矿与岩浆岩有一定的成因关系。岩浆岩与金矿床空间关系密切,矿区内脉岩发育,脉岩为矿体的上下盘。含矿岩石中发育斑点构造,斑点为黄铁矿、磁黄铁矿、毒砂、绿泥石、石英、绢云母、黑云母、堇青石、红柱石、电气石、碳酸盐等热变质矿物和热液交代矿物,表明花岗岩为成矿提供热动力。据八卦庙金矿、李坝金矿、小沟里金矿稳定同位素地球化学研究,结合成矿地质背景分析和区域成矿地质特征对比,认为凤太、西成、礼岷地区金矿与微细浸染型(卡林型)金矿有明显的差别,该区金矿类似于岩浆热液矿床。     

Late Quaternary downcutting rates of the Qianyou River from U/Th speleothem dates, Qinling mountains, China

Dating deposits in caves formed by rivers may yield insight into rates and processes of bedrock incision. Three cave passages at different levels have developed in the walls of the Qianyou River valley in the Qinling mountains, south of the city of Xian, China. Twelve speleothem samples near the position of palaeowater tables in three cave passages are dated by the ²³⁰Th dating method. The results show that the river cut down at the rate of 0.23 ± 0.02 mm/yr from 358,000 ± 38,000 to 247,000 ± 28,000 yr ago, 0.19 ± 0.03 mm/yr from 247,000 ± 28,000 to 118,000 ± 19,000 yr ago, and 0.51 ± 0.08 mm/yr from 118,000 ± 19,000 yr ago until today. These fall very close to the glacial-interglacial transition following marine oxygen isotope stages 10, 8, and 6, respectively. The increase in downcutting rates during the interglacial period is consistent with warm, wet weather, increasing rates of erosion. This may lead us toward an underlying mechanism for modulating incision that is not in a direct response to the presence of headwater glaciers.     

Zircon U–Pb ages and Hf isotope compositions of migmatites from the North Qinling terrane and their geological implications

Migmatites are predominant in the North Qinling (NQ) orogen, but their formation ages are poorly constrained. This paper presents a combined study of cathodoluminescence imaging, U–Pb age, trace element and Hf isotopes of zircon in migmatites from the NQ unit. In the migmatites, most zircon grains occur as new, homogeneous crystals, while some are present as overgrowth rims around inherited cores. Morphological and trace element features suggest that the zircon crystals are metamorphic and formed during partial melting. The inherited cores have oscillatory zoning and yield U–Pb ages of c. 900 Ma, representing their protolith ages. The early Neoproterozoic protoliths probably formed in an active continental margin, being a response to the assembly of the supercontinent Rodinia. The migmatite zircon yields Hf model ages of 1911 ± 20 to 990 ± 22 Ma, indicating that the protoliths were derived from reworking of Palaeoproterozoic to Neoproterozoic crustal materials. The anatexis zircon yields formation ages ranging from 455 ± 5 to 420 ± 4 Ma, with a peak at c. 435 Ma. Combined with previous results, we suggest that the migmatization of the NQ terrane occurred at c. 455–400 Ma. The migmatization was c. 50 Ma later than the c. 490 Ma ultra‐high‐P (UHP) metamorphism, indicating that they occurred in two independent tectonic events. By contrast, the migmatization was coeval with the granulite facies metamorphism and the granitic magmatism in the NQ unit, which collectively argue for their formation due to the northward subduction of the Shangdan Ocean. UHP rocks were distributed mainly along the northern margin and occasionally in the inner part of the NQ unit, indicating that they were exhumed along the northern edge and detached from the basement by the subsequent migmatization process.     

南秦岭石泉-汉阴北部煌斑岩脉特征及与金矿化的关系

羊坪湾矿区位于南秦岭南部逆冲推覆系迎丰-搁河口推覆体。北邻留凤关-金鸡岭褶皱束,西邻扬子准地台汉南凸起,南接北大巴山弧形褶皱带。矿区出露地层由南西向北东依次为洞河群（Z2-O）和下志留统梅子垭组（S1m）。其中洞河群分布于矿区的西南部,呈北西向展布,总体北东倾,倾角15°～45°,主要为硅质板岩,板岩中局部夹薄层炭质绢云石英片岩。下志留统梅子垭组倾向北东,倾角一般15°～50°,局部倾角最高可达75o,地层沿倾向及走向具波状起伏特征。梅子垭组以绢云石英片岩、二云石英片岩、含炭绢云石英片岩为主,以及夹有少量灰岩、大理岩条带等。金矿均赋存于志留系梅子垭组二云母石英片岩和含炭二云石英片岩中,以前者为主,约占90%以上。黄龙金矿区出露地层为下志留统梅子垭组,岩性为一套巨厚的浅变质细碎屑岩系,主要为绢云石英片岩、变砂岩、含黑云母变斑晶绢云石英片岩、含炭绢云石英片岩、含石榴子石黑云母变斑晶绢云石英片岩等。其中与矿（化）体关系最为密切的岩性为含炭绢云石英片岩、含黑云母变斑晶绢云石英片岩、含石榴子石黑云母变斑晶绢云石英片岩。     

陕南羊坪湾金矿床黄铁矿标型特征研究

羊坪湾金矿位于陕西石泉-汉阴北部金矿带东部,前人曾在该地区开展过大量勘探和综合研究,并取得一定的认识成果（李会民等,1997;李福让等,2009;任小华等,2015）。羊坪湾金矿床中载金矿物主要为黄铁矿,其次为磁黄铁矿,此外还有少量褐铁矿、石英等。本次重点针对矿区内载金黄铁矿进行电子探针测试分析,探讨其同金成之间关系。     

西秦岭与赛什塘铜矿床有关的花岗质岩石岩浆源区特征及大地构造背景探讨

西秦岭赛什塘铜矿区内出露的三叠纪花岗质岩石有闪长玢岩、石英闪长岩、石英闪长玢岩、花岗斑岩和石英斑岩,其岩浆源区与形成构造环境可为古特提斯洋演化和区域成矿作用研究提供证据。岩石地球化学特征共同表明,这些花岗质岩石属于准铝质钙碱性-高钾钙碱性系列,为I型花岗岩;Mg#值变化较大(39~68),LREE富集,HREE亏损,(La/Yb)N比值介于8.50~22.9,具有Eu负异常,δEu介于0.28~0.78,同时富集大离子亲石元素Cs、Rb、K、Pb,亏损高场强元素Nb、Ta、Ti,呈现出与典型俯冲作用密切相关岛弧花岗岩相一致地球化学特征。石英闪长玢岩和石英斑岩SHRIMP锆石U-Pb年龄分别为219.0±2.3Ma和220.0±2.0Ma,锆石εHf(t)分别为-4.5~-2.1和-2.5~+1.0,对应二阶段模式年龄分别为1392~1544Ma和1190~1415Ma。结合前人对西秦岭三叠纪花岗岩以及其南侧阿尼玛卿蛇绿混杂带研究成果,本文认为赛什塘铜矿区花岗质岩石与西秦岭同时期花岗岩形成于与古特提斯洋向北俯冲密切相关的大陆边缘弧环境,其岩浆源区为中元古代下地壳变基性岩,且岩浆可能受到地幔物质混染。     

西秦岭上白垩统红层空间分布及其对青藏高原东北缘隆升的地质约束

通过对西秦岭上白垩统红层地层基本沉积特征的研究和空间高程分布的定量化分析,讨论了西秦岭晚白垩世时期可能的构造地貌状态及西秦岭新生代以来地壳隆升的空间变化规律。取得如下认识:1根据西秦岭上白垩统底部洪积-冲积砾岩层之上普遍存在一套厚度不等的具有风成砂岩特征的红色中细粒砂岩和上部出现以泥岩、泥质粉砂岩为主的湖相沉积,结合现今多分布在不同水系分水岭之上,以及西秦岭中部宕昌-岷县-临潭断裂带两侧上白垩统红层地层顶面高程和底部角度不整合面高程没有显著差异分析,认为西秦岭无论在晚白垩之前经历了何种构造过程,晚白垩世具有整体稳定的泛沙漠-湖盆的古构造地貌状态,且断裂带不具备控制上白垩统沉积的构造边界性质;2现今离散型分布在西秦岭的上白垩统沉积地层反映的原型盆地不是孤立的、受区域断裂控制的山间盆地,而是统一的泛沙漠-内陆湖盆,现今的离散型分布是新生代以来地壳不均匀隆升和侵蚀的结果;3西秦岭上白垩统底部的角度不整合面产状,虽然由于后期构造变动呈非完全水平状态,但总体产状平缓。从大区域尺度分析,可以近似看做原始近水平的古地貌面。通过对该角度不整合面高程信息提取和模拟分析,结果表明,其高程分布具有从南西到北东、从北西到南东逐渐降低,穿越区域断裂带没有显著梯度变化,指示了西秦岭新生代以来的隆升具有整体性和隆升幅度呈连续梯度变化的特征。这可能指示了西秦岭新生代以来的地壳隆升机制主要不是上地壳挤压逆冲缩短,而是在印度板块-欧亚板块碰撞汇聚的动力学背景下,下地壳或上地幔自西南向北东连续流变逐渐增厚,造成了青藏高原东北缘呈向北东突出的弧形扩展隆升。     

青海南山地区角孔变质岩地质特征、年代学及其地质意义

青海南山达不祖乎山北部一带的角孔变质岩系原划为早中三叠世隆务河组。通过野外实测地质剖面和路线地质调查,查明该套地层单元野外产出状态及岩石组合特征,并对其物质来源和形成时代进行分析,对进一步研究该区晚古生代-早中生代的构造演化具有重要意义。该套变质岩系为一套长石石英岩、石英岩、大理岩和黑云石英片岩组合,由下向上划分为3个岩段,叠置厚度大于3186.3m。根据碎屑锆石年龄分布特征,可大致划分为5个年龄组段,分别为250～304Ma、405～546Ma、649～1077Ma、1402～1620Ma和1861～2990Ma,其中250～304Ma可进一步划分为250～269Ma和289～304Ma两个亚组。综合前人研究资料与区域构造岩浆活动,将青海南山地区角孔变质岩的沉积时代限定为二叠纪,物源主要来自祁连造山带加里东期和晋宁期岩浆弧,柴北缘构造带海西期岩浆弧也提供了部分物质,晚古生代—早中生代经历了陆内裂陷、洋盆拉张及俯冲碰撞的构造演化过程。