南秦岭十里坪锑矿床成矿时代及成因的初步研究

十里坪锑矿床受赵川陆缘隆_滑构造的主滑脱拆离带的控制。矿体呈脉状赋存于韧_脆性主滑脱带上部的脆性次级断层_节理中,矿石类型主要为萤石石英辉锑矿型。围岩为太古宙_元古宙变质岩系,围岩蚀变弱。成矿流体属H2O_CO2_NaCl体系,流体包裹体盐度w(NaCleq)为3.6%～11.3%,均一温度为109～232℃,形成压力大致为800×105Pa。硫、铅同位素研究表明,矿质主要来源于变火山岩围岩;氢、氧同位素显示,成矿流体以大气降水为主,初步将该矿床定为变质岩源就地式大气降水热液矿床。矿石中萤石Sm_Nd等时线年龄为(392±24)Ma,与南秦岭北部晚古生代拗陷区热水喷流_沉积成矿时代相一致,它们都形成于秦岭微板块泥盆纪非造山裂解阶段。     

李坝金矿床金的赋存状态与选矿工艺学

李坝大型金矿床是产于西秦岭上古生代沉积岩系中类卡林型金矿床典型代表。通过显微镜及选矿实验查定了李坝金矿床金的赋存状态，矿床金矿物呈微细粒多种独立矿物出现，金的赋存形式多样，显示多期多阶段成矿特点，成为划分类卡林型金矿的重要参考。矿石工艺学的研究对工业选矿有指导意义。     

西秦岭三个典型金矿床稳定同位素地球化学特征

据八卦庙金矿、李坝金矿、小沟里金矿稳定同位素研究,金矿床δ34S比正常沉积岩变化范围窄,比岩浆-火山岩型矿床宽,硫源是海水硫酸盐还原硫与深部热液来源硫所组成的混合硫。石英包裹体流体氢、氧同位素分布于岩浆水、大气降水的重叠过渡区,更靠近岩浆水区,岩浆水的同位素特征更明显。八卦庙金矿石英脉3He/4He高于地壳3He/4He值(n×10-8),低于地幔3He/4He值(n×10-5),为壳-幔混合源。上述同位素地球化学证据表明,金成矿与岩浆岩有一定的成因关系。岩浆岩与金矿床空间关系密切,矿区内脉岩发育,脉岩为矿体的上下盘。含矿岩石中发育斑点构造,斑点为黄铁矿、磁黄铁矿、毒砂、绿泥石、石英、绢云母、黑云母、堇青石、红柱石、电气石、碳酸盐等热变质矿物和热液交代矿物,表明花岗岩为成矿提供热动力。据八卦庙金矿、李坝金矿、小沟里金矿稳定同位素地球化学研究,结合成矿地质背景分析和区域成矿地质特征对比,认为凤太、西成、礼岷地区金矿与微细浸染型(卡林型)金矿有明显的差别,该区金矿类似于岩浆热液矿床。     

Late Quaternary downcutting rates of the Qianyou River from U/Th speleothem dates, Qinling mountains, China

Dating deposits in caves formed by rivers may yield insight into rates and processes of bedrock incision. Three cave passages at different levels have developed in the walls of the Qianyou River valley in the Qinling mountains, south of the city of Xian, China. Twelve speleothem samples near the position of palaeowater tables in three cave passages are dated by the ²³⁰Th dating method. The results show that the river cut down at the rate of 0.23 ± 0.02 mm/yr from 358,000 ± 38,000 to 247,000 ± 28,000 yr ago, 0.19 ± 0.03 mm/yr from 247,000 ± 28,000 to 118,000 ± 19,000 yr ago, and 0.51 ± 0.08 mm/yr from 118,000 ± 19,000 yr ago until today. These fall very close to the glacial-interglacial transition following marine oxygen isotope stages 10, 8, and 6, respectively. The increase in downcutting rates during the interglacial period is consistent with warm, wet weather, increasing rates of erosion. This may lead us toward an underlying mechanism for modulating incision that is not in a direct response to the presence of headwater glaciers.     

Zircon U–Pb ages and Hf isotope compositions of migmatites from the North Qinling terrane and their geological implications

Migmatites are predominant in the North Qinling (NQ) orogen, but their formation ages are poorly constrained. This paper presents a combined study of cathodoluminescence imaging, U–Pb age, trace element and Hf isotopes of zircon in migmatites from the NQ unit. In the migmatites, most zircon grains occur as new, homogeneous crystals, while some are present as overgrowth rims around inherited cores. Morphological and trace element features suggest that the zircon crystals are metamorphic and formed during partial melting. The inherited cores have oscillatory zoning and yield U–Pb ages of c. 900 Ma, representing their protolith ages. The early Neoproterozoic protoliths probably formed in an active continental margin, being a response to the assembly of the supercontinent Rodinia. The migmatite zircon yields Hf model ages of 1911 ± 20 to 990 ± 22 Ma, indicating that the protoliths were derived from reworking of Palaeoproterozoic to Neoproterozoic crustal materials. The anatexis zircon yields formation ages ranging from 455 ± 5 to 420 ± 4 Ma, with a peak at c. 435 Ma. Combined with previous results, we suggest that the migmatization of the NQ terrane occurred at c. 455–400 Ma. The migmatization was c. 50 Ma later than the c. 490 Ma ultra‐high‐P (UHP) metamorphism, indicating that they occurred in two independent tectonic events. By contrast, the migmatization was coeval with the granulite facies metamorphism and the granitic magmatism in the NQ unit, which collectively argue for their formation due to the northward subduction of the Shangdan Ocean. UHP rocks were distributed mainly along the northern margin and occasionally in the inner part of the NQ unit, indicating that they were exhumed along the northern edge and detached from the basement by the subsequent migmatization process.     

陕南羊坪湾金矿床黄铁矿标型特征研究

羊坪湾金矿位于陕西石泉-汉阴北部金矿带东部,前人曾在该地区开展过大量勘探和综合研究,并取得一定的认识成果（李会民等,1997;李福让等,2009;任小华等,2015）。羊坪湾金矿床中载金矿物主要为黄铁矿,其次为磁黄铁矿,此外还有少量褐铁矿、石英等。本次重点针对矿区内载金黄铁矿进行电子探针测试分析,探讨其同金成之间关系。     

西秦岭上白垩统红层空间分布及其对青藏高原东北缘隆升的地质约束

通过对西秦岭上白垩统红层地层基本沉积特征的研究和空间高程分布的定量化分析,讨论了西秦岭晚白垩世时期可能的构造地貌状态及西秦岭新生代以来地壳隆升的空间变化规律。取得如下认识:1根据西秦岭上白垩统底部洪积-冲积砾岩层之上普遍存在一套厚度不等的具有风成砂岩特征的红色中细粒砂岩和上部出现以泥岩、泥质粉砂岩为主的湖相沉积,结合现今多分布在不同水系分水岭之上,以及西秦岭中部宕昌-岷县-临潭断裂带两侧上白垩统红层地层顶面高程和底部角度不整合面高程没有显著差异分析,认为西秦岭无论在晚白垩之前经历了何种构造过程,晚白垩世具有整体稳定的泛沙漠-湖盆的古构造地貌状态,且断裂带不具备控制上白垩统沉积的构造边界性质;2现今离散型分布在西秦岭的上白垩统沉积地层反映的原型盆地不是孤立的、受区域断裂控制的山间盆地,而是统一的泛沙漠-内陆湖盆,现今的离散型分布是新生代以来地壳不均匀隆升和侵蚀的结果;3西秦岭上白垩统底部的角度不整合面产状,虽然由于后期构造变动呈非完全水平状态,但总体产状平缓。从大区域尺度分析,可以近似看做原始近水平的古地貌面。通过对该角度不整合面高程信息提取和模拟分析,结果表明,其高程分布具有从南西到北东、从北西到南东逐渐降低,穿越区域断裂带没有显著梯度变化,指示了西秦岭新生代以来的隆升具有整体性和隆升幅度呈连续梯度变化的特征。这可能指示了西秦岭新生代以来的地壳隆升机制主要不是上地壳挤压逆冲缩短,而是在印度板块-欧亚板块碰撞汇聚的动力学背景下,下地壳或上地幔自西南向北东连续流变逐渐增厚,造成了青藏高原东北缘呈向北东突出的弧形扩展隆升。     

秦岭某钼矿区开发对东川河流域Cd的影响

为了探索矿业活动对河流水质产生的影响,以秦岭某大型钼矿区下游的东川河流域为研究对象,通过现场采样与室内测试的方法,分析了地表水、沉积物、岩矿样品中重金属Cd的含量特征。采用污染超标倍数法、地累积指数法及Hakanson潜在生态风险评价法分别对东川河流域的河水和底泥样品进行了污染现状评价和生态风险程度评价,最后讨论了Cd的来源。结果表明:东川河主沟16个河水采样点位中,有11个点位的Cd含量明显高于未受矿业活动影响的对照区各点位Cd含量值,Cd含量变异系数达到95.65%,并且从上游到下游各点位Cd含量呈偏态分布,说明东川河流域Cd受矿业活动影响显著。东川河主沟16个河水采样点中有15个Cd含量满足地表水Ⅱ类水标准,比重为93.75%,可以判断东川河整体水质较好。仅5号点位超Ⅱ类水质标准,污染超标倍数为1,为轻度污染。地累积指数分析结果表明,东川河主沟11个底泥样品均存在不同程度的污染:污染最严重的10号点位达到中度-强污染级别;污染最轻的8、9、13号点位为无污染-中度污染;大多数点位为中度污染。东川河主沟11件底泥样品重金属Cd的潜在生态危害指数平均值为120.27,表明东川河主沟底泥总体达到强生态风险程度。酸性矿山废水、原生地质背景、底泥释放、大气干湿降尘等是造成东川河流域Cd重金属污染的主要污染源。     

西秦岭温泉—中川一带金属矿床的成矿规律及找矿预测

西秦岭温泉—中川一带实施的1:5万矿产地质调查项目,共圈定1:5万局部高磁异常33处,1:5万地球化学综合异常11处,发现矿点2处,矿化点5处,矿种有金、钼、铁、铜、铷等。通过分析研究区成矿地质条件、1:5万地球物理和地球化学综合异常特征、矿(化)点特征及分布规律等,阐明了该区成矿时空分布规律和矿产共生组合规律,划分成矿远景区9处,提交找矿靶区6处。对其中2处找矿靶区进行槽探验证的结果为: 关子镇幅玉杨观找矿靶区圈定了4条含铷矿化伟晶岩脉和多处铁矿化破碎蚀变带,具有形成伟晶岩型铷矿的潜力; 礼县幅李坝金矿床南侧百叶沟—河西沟找矿靶区圈定了14条蚀变破碎带,在矿化蚀变带内圈定了11条金矿(化)体,具有形成构造蚀变岩(微细粒浸染状)型金矿床的潜力。     

西秦岭阳山金矿带控矿因素、找矿标志及深部成矿预测

目前对西秦岭阳山金矿带勘查评价正在加速进行,为了进一步查明该矿带成矿规律和找矿潜力,指导矿田深部勘查找矿工作,武警黄金第十二支队在矿区开展了深部矿产调查和研究。文章在前人研究的基础上,通过最新的地质、地球物理勘查和室内综合研究,分析和总结了阳山金矿带主要控矿因素和找矿标志以及各因素的控矿机制。研究显示:区内的北东东向、近东西向断裂系统多沿葛条湾-草坪梁复背斜南翼层间褶皱岩层薄弱面或不同岩性接触面发育,在成矿过程中起到通道作用,限定了矿体的展布,为主要控矿因素。在明确找矿标志的基础上,以安坝矿段为研究对象,采用三维地质建模找矿信息量法进行了定量成矿预测,共圈定出深部找矿靶区4处,为矿区下一步的勘查指明了方向。