Geochemistry and potential use of groundwater in the Rocca Busambra area (Sicily, Italy)

In the Rocca Busambra area (mid-west Sicily, Italy), from November 1999 to July 2002, 23 water points including wells and springs were sampled and studied for their chemical and isotopic compositions. Two rain gauges were also installed at different altitudes, and rainwater was collected monthly to determine the isotopic composition. The obtained results revealed the Rocca Busambra carbonate complex as being the main recharge area on account of its high permeability value. From a chemical view point, two main groups of water can be distinguished: calcium–magnesium–bicarbonate-type and calcium–magnesium–chloride–sulphate-type waters. The first group reflects the dissolution of the carbonate rocks; the second group probably originates from circulation within flyschoid sediments. Three water wells differ from the other samples due to their relatively high Na and K content, which probably is to be referred to a marked interaction with the “Calcareniti di Corleone” formation, which is rich in glauconite [(K, Na)(Fe³⁺, Al, Mg)₂(Si, Al)₄O₁₀(OH)₂]. In accordance with WHO guidelines for drinking water (2004), almost all the samples collected can be considered drinkable, with the exception of four of them, whose NO₃ ⁻, F⁻ and Na⁺ contents exceed the limits. On the contrary, the sampled groundwater studied is basically suitable for irrigation.     

The identifiability of parameters in a water quality model of the Biebrza River, Poland

The identifiability of model parameters of a steady state water quality model of the Biebrza River and the resulting variation in model results was examined by applying the Monte Carlo method which combines calibration, identifiability analysis, uncertainty analysis, and sensitivity analysis. The water quality model simulates the steady state concentration profiles of chloride, phosphate, ammonium, and nitrate as a function of distance along a river. The water quality model with the best combination of parameter values simulates the observed concentrations very well. However, the range of possible modelled concentrations obtained for other more or less equally eligible combinations of parameter values is rather wide. This range in model outcomes reflects possible errors in the model parameters. Discrepancies between the range in model outcomes and the validation data set are only caused by errors in model structure, or (measurement) errors in boundary conditions or input variables. In this sense the validation procedure is a test of model capability, where the effects of calibration errors are filtered out. It is concluded that, despite some slight deviations between model outcome and observations, the model is successful in simulating the spatial pattern of nutrient concentrations in the Biebrza River.     

A Zonal Pathway for NADW in the South Atlantic

Several large deployments of neutrally buoyant floats took place within the Antarctic Intermediate (AAIW), North Atlantic Deep Water (NADW), and the Antarctic Bottom Water (AABW) of the South Atlantic in the 1990s and a number of hydrographic sections were occupied as well. Here we use the spatially and temporally averaged velocities measured by these floats, combined with the hydrographic section data and various estimates of regional current transports from moored current meter arrays, to determine the circulation of the three major subthermocline water masses in a zonal strip across the South Atlantic between the latitudes of 19°S and 30°S. We concentrate on this region because the historical literature suggests that it is where the Deep Western Boundary Current containing NADW bifurcates. In support of this notion, we find that a net of about 5 Sv. of the 15–20 Sv that crosses 19°S does continue zonally eastward at least as far as the Mid-Atlantic Ridge. Once across the ridge it takes a circuit to the north along the ridge flanks before returning to the south in the eastern half of the Angola Basin. The data suggest that the NADW then continues on into the Indian Ocean. This scheme is discussed in the context of distributions of dissolved oxygen, silicate and salinity. In spite of the many float-years of data that were collected in the region a surprising result is that their impact on the computed solutions is quite modest. Although the focus is on the NADW we also discuss the circulation for the AAIW and AABW layers.     

六横大岙附近海域环境质量现状评价

根据１９９５年４月对码头工程区附近海域的水质和沉积物的环境质量现场调查,采用环境质量指数法,评价了该海区水质和沉积物的环境质量状况。结果表明,水质中无机氮严重超标,超三类标准的超标率达１００％。无机磷超一类标准的超标率达１００％,有个别测站超二类标准。ＣＯＤ、ｐＨ、ＤＯ、油类均低于一类海水标准。潮间带水质基本符合一类水质要求。底质环境质量现状良好     

Estuary/ocean exchange and tidal mixing in a Gulf of Maine Estuary: A Lagrangian modeling study

A Lagrangian particle method embedded within a 2-D finite element code, is used to study the transport and ocean–estuary exchange processes in the well-mixed Great Bay Estuarine System in New Hampshire, USA. The 2-D finite element model, driven by residual, semi-diurnal and diurnal tidal constituents, includes the effects of wetting and drying of estuarine mud flats through the use of a porous medium transport module. The particle method includes tidal advection, plus a random walk model in the horizontal that simulates sub-grid scale turbulent transport processes. Our approach involves instantaneous, massive [O(500,000)] particle releases that enable the quantification of ocean–estuary and inter-bay exchanges in a Markovian framework. The effects of the release time, spring–neap cycle, riverine discharge and diffusion strength on the intra-estuary and estuary–ocean exchange are also investigated.The results show a rather dynamic interaction between the ocean and the estuary with a fraction of the exiting particles being caught up in the Gulf of Maine Coastal Current and swept away. Three somewhat different estimates of estuarine residence time are calculated to provide complementary views of estuary flushing. Maps of residence time versus release location uncover a strong spatial dependency of residence time within the estuary that has very important ramifications for local water quality. Simulations with and without the turbulent random walk show that the combined effect of advective shear and turbulent diffusion is very effective at spreading particles throughout the estuary relatively quickly, even at low (1 m²/s) diffusivity. The results presented here show that a first-order Markov Chain approach has applicability and a high potential for improving our understanding of the mixing processes in estuaries.     

南极低温降解菌Shewanella sp. NJ49羟化酶分离纯化及最适产酶条件研究

羟化酶是细菌降解烷烃的关键酶,本文以南极低温降解菌Shewanella sp.NJ49为研究对象,通过硫酸铵沉淀、超滤浓缩及葡聚糖凝胶Sephadex G-75柱层析方法,分离纯化NJ49的羟化酶,获得了单一羟化酶组分,研究了温度、p H、表面活性剂和盐度等环境因素对NJ49羟化酶酶活活性影响。结果表明,羟化酶组分由α、β、γ三个亚基组成,分子质量分别为56,45和36 k D。NJ49最适产酶条件为:温度15℃、p H7.2、盐度55;不同类型表面活性剂对酶的活性影响效应不一,两性离子表面活性剂、阳离子表面活性剂、非离子表面活性剂对酶活没有作用,阴离子表面活性剂+非离子表面活性剂混和剂和阳离子表面活性剂+非离子表面活性剂混和剂能提高羟化酶的活性。     

黄河流域冬、夏季水汽输送及收支特征

利用NCEP/NCAR再分析资料和我国实测雨量资料,对黄河流域1月和7月多年平均及旱、涝年整层积分的水汽通量、辐合(辐散)及各分区水汽收支进行了研究。结果表明,1月黄河流域无明显的水汽输送,而7月水汽沿西南、东南及西北3条路径输送,前两支气流在多年平均时主要影响黄河下游区。涝年时影响到黄河中、下游区,而上游区水汽流入较小;旱年,黄河中、上游区均无明显的水汽输送,只有下游的小范围地区受西南气流影响。各区净水汽通量分别与其地面降水的时空演变相对应,而经向净水汽通量是影响水汽收支变化及供给流域降水的主要水汽来源;涝年的水汽净收支与各边界水汽流入明显大于旱年。1月,西边界和北边界微弱的水汽输入远小于东边界和南边界的输出,各区均为水汽净辐散,不利于降水;7月,大量的水汽主要来自西边界和南边界,涝年各区均为水汽盈余,多年平均也以净辐合为主,而旱年则以水汽亏损为主。     

1991年5-7月江淮洪涝:水汽和冷空气的作用比较

对1991年5-7月江淮流域持续性暴雨的环流异常进行分析,比较造成此次洪涝的水汽输送和冷空气活动重要性。结果表明：（1）东亚大槽维持在中国东北上空发展明显,同时鄂霍次克海上空没有建立强大阻高,这种形势有利于冷空气持续向南侵袭,盛行经向环流。此外,低纬度地区,西太平洋副热带高压主体位置于常年同期相比,明显偏西、偏强,有利于暖湿气流沿副热带高压北上到达江淮流域,与北方冷空气辐合形成强降水。（2）通过定义I_T和I_q分别表征温度与水汽对降水的贡献,发现此次江淮流域地区强降水是由对流层低层水汽异常增多和气温异常偏低共同造成的,作用基本相当。     

Cutting of Phragmites australis as a lake restoration technique: Productivity calculation and nutrient removal in Wuliangsuhai Lake, northern China

Reed is one of the most frequent and dominant species in wetlands all over the world, with common reed (Phragmites australis (Cav.) Trin. ex Steud.) as the most widely distributed species. In many wetlands, P. australis plays a highly ambivalent role. On the one hand, in many wetlands it purifies wastewater, provides habitat for numerous species, and is a potentially valuable raw material, while on the other hand it is an invasive species which expands aggressively, prevents fishing, blocks ditches and waterways, and builds monospecies stands. This paper uses the eutrophic reed-swamp of Wuliangsuhai Lake in Inner Mongolia, northern China, as a case to present the multiple benefits of regular reed cutting. The reed area and aboveground biomass production are calculated based on field data. Combined with data about water and reed nutrient content, the impact of reed cutting on the lake nutrient budget (N and P) is investigated. Currently, at this lake around 100,000 tons of reed are harvested in winter annually, removing 16% and 8% of the total nitrogen and phosphorus influx, respectively. Harvesting all available winter reed could increase the nutrient removal rates to 48% and 24%, respectively. We also consider the effects of summer harvesting, in which reed biomass removal could overcompensate for the nutrient influx but could potentially reduce reed regrowth.     

江西2012年5月12日大暴雨过程水汽输送分析

利用NCEP 1°×1°再分析资料、常规气象观测资料和WRF中尺度数值模式,对2012年5月12日江西出现的大暴雨天气水汽输送的过程进行分析。结果表明,从大尺度分析,此次暴雨过程的水汽输送特征并不典型,比湿、水汽通量、水汽通量散度、整层水汽输送等均不能满足江西出现暴雨时应该达到的水汽条件;但模拟的中小尺度水汽指数能够满足江西发生暴雨的水汽条件。此次暴雨过程的水汽主要来自南海地区。暴雨出现的区域与整层水汽大值区的水平梯度最大处相吻合。当整层水汽输送值较小时,水汽输送主要集中在中低层,但当整层水汽输送值较大时,水汽输送的高度高度超过500 hPa高度层,仅分析500 hPa高度层以下的水汽输送对暴雨预报会造成一定的误差。