硼的地球化学性质及其在俯冲带的循环与成矿初探

硼是广泛应用于化工、农业、材料科学及核工业领域的重要元素。硼与氢的核聚变反应是未来具备运用潜力的清洁能源。硼作为典型的亲石元素,是高度不相容元素。硼元素容易富集于蚀变洋壳及蛇纹石化地幔橄榄岩中。而在板块俯冲过程中,由于硼具有强的流体活动性,会优先赋存于流体中。因此,当蛇纹石化的大洋岩石圈及覆于其上的沉积物在俯冲过程中发生脱水,这使得弧前地幔楔发生大规模的蛇纹石化。此时大量硼元素很可能随俯冲流体释放并封存于弧前地幔楔中。目前已发现的超大型硼矿床主要位于聚合型板块边缘,尤其土耳其拥有世界上最大的硼酸盐储量。我们推测这些矿床的形成基础条件之一可能与弧前高度蛇纹石化的地幔楔有关。尤其是在洋 陆俯冲环境,弧前蛇纹岩或蛇绿混杂岩首先通过俯冲侵蚀再循环到火山弧岩浆中,使得岩浆更富集硼。随后弧火山喷发大量富硼的火山岩、岩浆热液及水气。在岩浆冷却过程中,硼元素析出、沉淀于火山表面,并伴随风化、侵蚀过程汇聚至碰撞造山带的封闭湖盆之中。此外,干冷的气候条件下也进一步促进了硼的成矿。我国具有形成大型、超大型硼矿的地质条件,应加大研究及探勘力度,并适当购买硼作为战略储备。     

内蒙古东乌旗北部早古生代火山岩年代学、地球化学特征及地质意义

内蒙古北部二连-东乌旗地区出露早古生代火山岩,为兴蒙造山带北缘构造-岩浆岩带的组成部分,对研究造山带早古生代构造格局及演化具有重要作用。本文对东乌旗北部早古生代中基性及酸性火山岩进行了锆石U-Pb年代学、岩石学、全岩地球化学及Sr-Nd-Hf同位素分析。定年结果显示,中基性火山岩成岩年龄为452±2Ma,酸性火山岩为430±20Ma,表明早古生代岩浆活动可延续至中志留世。地球化学组成上,中基性火山岩稀土总量中等,Eu异常不明显,富集Rb、Sr、Th、U等大离子亲石元素,亏损Nb、Ta等高场强元素,特征类似岛弧岩浆岩;酸性火山岩富集Th、U,Eu负异常显著,但Rb、Ba等大离子亲石元素富集程度不高,Nb、Ta等高场强元素亏损不明显,表现出板内岩浆特点。中基性和酸性火山岩均具有亏损的同位素组成:中基性火山岩ε_(Nd)(t)=+203～+267,ε_(Hf)(t)值介于+79～+145之间;酸性火山岩ε_(Nd)(t)=+494,ε_(Hf)(t)值为+99～+153。岩石学及地球化学分析表明,中基性火山岩为岛弧环境下遭受俯冲流体交代的地幔楔部分熔融产物,酸性火山岩则来源于新生基性下地壳熔融并具有板内岩浆特征,可能指示了俯冲的结束。结合前人资料,二连-东乌旗地区早古生代岩浆活动介于晚寒武-中志留世之间,形成时间及阶段性演化特征近似于苏尼特左旗-锡林浩特早古生代岩浆岩带,暗示两者可能具有成因联系,均为早古生代古亚洲洋向北俯冲的产物。     

Characteristics and petroleum origin of the Carboniferous volcanic rock reservoirs in the Shixi Bulge of Junggar Basin,western China

Shixi Bulge of the central Junggar Basin in western China is a unique region that provides insight into the geological and geochemical characteristics of large-scale petroleum reservoirs in volcanic rocks of the western Central Asian Orogenic Belt. Carboniferous volcanic rocks in the Shixi Bulge mainly consist of striped lava and agglomerate, as well as breccia lava and tight tuff. Volcanic rocks differ in porosity and permeability. Striped lava exhibits the highest porosity (average: 14.2%) but the lowest permeability (average: 0.67 × 10⁻¹⁵ m) among the rock types. Primary gas pores are widely developed and mostly filled. Secondary dissolution pores and fractures are two major reservoir storage spaces. Capillary pressure curves suggest the existence of four pore structure types of reservoir rocks. Several factors, namely, lithology, pore structure, and various diagenesis, govern the physical properties of volcanic rocks. The oil is characterized by a high concentration of tricyclic terpane, a terpane distribution of C₂₃ < C₂₁ > C₂₀, and sterane distributions of C₂₇ < C₂₈ < C₂₉ and C₂₇ > C₂₈ < C₂₉. Oil and gas geochemistry revealed that the oil is a mixture derived primarily from P₂w source rock and secondarily from P₁j source rock in the sag west of Pen-1 Well. The gases are likely gas mixtures of humic and sapropelic organic origins, with the sapropelic gas type dominant in the mixture. The gas mixture is most likely cracked from kerogen rather than oils. The Carboniferous volcanic reservoirs in Shixi Bulge share some unique characteristics that may provide useful insights into the various roles of different volcanic reservoir types in old volcanic provinces. The presence of these reservoirs will undoubtedly encourage future petroleum exploration in volcanic rocks up to the deep parts of sedimentary basins.     

Tectonic Settings and Geological Implications of Neoproterozoic Liujiaping VMS Deposit,Northwestern Yangtze Block,China

Liujiaping VMS (volcanic massive sulfide) deposit contains mainly copper and zinc, which is located at the Longmenshan orogenic belt of the northwestern margin of Yangtze block. The deposit is hosted in Neoproterozoic Datan terrane (composed of Datan granitoids and Liujiaping group) and is a typical, and the biggest, VMS deposit in this area. The Datan granitoids and Liujiaping group are contemporary and both parental magmas have the same genesis. The tectonic evolution history of Northwestern Yangtze is complicated. Chronology, isotope and geochemistry of the Liujiaping VMS ores and wall rocks (especially the Datan granitoids) are analyzed to restrict the tectonic progress. High‐precision secondary ion mass spectrometry (SIMS) analysis of the Datan granitoids resulted in two concordant ages, 815.5 ± 3.2 Ma and 835.5 ± 2.6 Ma, which are contemporary with the Liujiaping Cu–Zn ore and volcanics. The wall rocks are characterized by enrichment in LREE and with a weak negative anomaly of Eu. The Pb isotope data of sulfide and volcanics from the Liujiaping deposit indicate that the material source is lower crust. Together with variable negative anomalies of high strength field elements HFSE (Th, Nb, Ta, Zr, Hf, P and Ti), positive ε_Nd (825 Ma) values (+1.8 to +3.1) and the Nd model age T_2DM = 1.2–1.3 Ga, it shows that the Liujiaping deposit and wall rocks were formed by partial melting of Mesoproterozoic lower crust. Geological and geochemical characteristics of Liujiaping deposit indicate that this deposit was formed during subduction of the oceanic crust. This study clarified that that the Liujiaping deposit and the northwestern margin of the Yangtze block were part of an arc setting at ~820 Ma rather than intra‐continental rift.     

基于SVM测井数据的火山岩岩性识别——以辽河盆地东部坳陷为例

辽河盆地东部坳陷储集层由火山多期喷发形成,岩相岩性复杂,岩性以中、基性火山岩为主.本文将火山岩的岩心及岩矿鉴定资料与测井数据进行整合,应用测井数据建立支持向量机(SVM)两分类和多分类岩性识别模式.首先,深入研究支持向量机二分类及"一对一"、"一对多"和有向无环图三种经典多分类算法的基本原理及结构;然后,总结研究区域火山岩岩石特征,分析测井数据的测井响应组合特征,选择40口井中岩心分析和薄片鉴定资料完整、常规五种测井曲线(RLLD,CNL,DEN,AC,GR)齐全的1200个测井数据作为训练样本,构造三种支持向量机岩性识别模式;最后,对4测试井中800个测井数据进行岩性识别,识别结果与取心段岩心描述和岩心/岩屑薄片鉴定资料对比,实验结果表明有向无环图更适合辽河盆地火山岩的识别,识别正确率达到82.3%.     

滁州火山岩地球化学及其对郯庐断裂带内岩石圈减薄的指示

位于郯庐断裂带张八岭隆起北段上的滁州早白垩世火山岩,属于准铝质、硅过饱和岩石,为一套中酸性的高钾钙碱性系列火山岩,部分样品（129~125Ma）具有类似于埃达克岩的地球化学特征。该套火山岩富集大离子亲石元素和轻稀土元素、亏损重稀土元素及高场强元素,并具有类似于EMⅠ型的Sr-Nd-Pb同位素组成。地球化学特征显示该火山岩的岩浆源区属于华北克拉通,早期火山岩（约132Ma）是富集地幔来源岩浆和古老的华北下地壳源区混合的结果;中期和晚期火山岩（129~117Ma）是幔源底侵组分和古老的华北下地壳来源岩浆不同比例混合的产物。由早到晚,滁州火山岩中古老壳源物质比例逐渐增加,源区逐渐变浅,指示软流圈顶面不断抬升、岩石圈内等温面逐渐升高的过程。研究表明,热异常背景下强烈的壳-幔相互作用是该处断裂带内岩浆形成的主要方式,其具体过程是在岩石圈底部持续减薄、软流圈上涌背景下,幔源岩浆底侵而诱发了古老下地壳的部分熔融,从而形成了壳-幔过渡带内混源的岩浆。郯庐断裂带内较浅的岩浆源区、较高的源区熔融程度、强烈而持久的伸展及岩浆活动、强烈的壳-幔相互作用以及现今较薄的岩石圈厚度,都指示郯庐断裂带是华北克拉通东部岩石圈减薄中的强减薄带,在华北克拉通破坏中起着重要的作用。     

辽西四合屯—后燕子沟早白垩世火山机构及火山喷发作用的演化

在四合屯—后燕子沟火山岩区的工作,确定了火山机构的组合、分布及其类型。并将本区的火山作用划分为4个亚旋回。亚旋回Ⅰ的下部为凝灰质胶结复成分细砾岩,上部聚斑状橄榄玄武岩,气孔杏仁状玄武岩。亚旋回Ⅱ的下部为凝灰质杂砂岩、沉凝灰岩、凝灰岩和玄武安山质集块岩。上部杏仁状橄榄玄武岩与玄武安粗岩互层,夹辉石玄武安山岩。亚旋回Ⅲ为玄武安山质晶屑岩屑凝灰岩、岩屑杂砂岩、玄武安山质熔结集块岩、杏仁状橄榄黄长碧玄岩、拉斑玄武岩、安山质集块角砾岩、杏仁状玄武安山岩和杏仁状安山岩夹橄榄玄武岩。亚旋回Ⅳ为火山喷出大量橄榄玄武岩,杏仁状玄武岩和玄武安山岩,盖在凝灰质岩屑长石杂砂岩上。该火山岩区是一个巨大的组合式火山机构,火山机构中心地段由十几个火山口组成 ,构成中心火山群,即中心火山机构。外侧还有5个小火山群形成次级火山机构,围绕其近于有规律地匀称地分布,每个次级火山机构的中心火山口外侧也有数个火山口呈环状围绕其分布。故称其为“组合式”火山机构。“组合式”火山机构中心地带发现了含有地幔岩成分的橄榄玄武岩、碧玄岩。“组合式”火山机构是由含有地幔岩浆物质形成的。     

The lithospheric transition between the Delamerian and Lachlan orogens in western Victoria: new insights from 3D magnetotelluric imaging

The magnetotelluric (MT) method was used to image the crust and upper mantle beneath the Delamerian and Lachlan orogens in western Victoria, Australia. During the Cambrian time period, this region changed from being the extended passive margin of Proterozoic Australia into an Andean-style convergent margin that progressively began to accrete younger oceanic terranes. Several broadband MT transects, which were collected in stages along coincident deep (full crust imaging) seismic reflection lines, have now been combined to create a continuous 500 km east–west transect over the Delamerian–Lachlan transition region in the Stawell Zone. We present the electrical resistivity structure of the lithosphere using both 3D and 2D inversion methods. Additionally, 1D inversions of long-period AusLAMP (Australian Lithospheric Architecture Magnetotelluric Project) MT data on a 55 km regionally spaced grid were used to provide starting constraints for the 3D inversion of the 2D profile. The Delamerian to Lachlan Orogen transition region coincides with the Mortlake Discontinuity, which marks an isotopic discontinuity in Cenozoic basalts, with higher strontium isotope enrichment ratios in the Lachlan Orogen relative to the Delamerian Orogen. Phase tensor ellipses of the MT data reveal a distinct change in electrical resistivity structure near the location of the Mortlake Discontinuity, and results of 3D and 2D inversions along the MT profile image a more conductive lower crust and upper mantle beneath the Lachlan Orogen than the Delamerian Orogen. Increased conductivity is commonly ascribed to mantle enrichment and thus supports the notion that the isotope enrichment of the Cenozoic basalts at least partially reflects an enriched mantle source rather than crustal contamination. Fault slivers of the lower crust from the more conductive Lachlan region expose Cambrian boninites and island arc andesites indicative of subduction, a process that can enrich the mantle isotopically, and also electrically, by introducing carbon (graphite) and water (hydrogen).     

西藏安多早侏罗世火山岩岩石成因及对班公湖-怒江特提斯洋俯冲消减的制约

拉萨地块广泛分布着中生代的岩浆活动,研究它们对于认识特提斯洋的演化过程有着重要的启示。本文报道安多地区新识别出的早侏罗世岛弧型火山岩LA-ICP-MS锆石U-Pb年龄、锆石原位Hf同位素、全岩主微量元素分析和Sr-Nd同位素结果。英安岩206Pb/238U年龄为180.7±4.7Ma(MSWD=0.22,n=10),指示其形成时代为早侏罗世。这些火山岩的SiO_2含量为62.50%~76.15%,MgO含量为0.33%~3.05%,Fe_2O_3T含量为2.35%~6.69%;所有样品都显示轻稀土元素相对富集,具有铕的弱负异常,具有富集大离子亲石元素、亏损高场强元素的地球化学特征;同时这些火山岩锆石原位εHf(t)值均为正值(+15.1~+17.1);全岩Sr-Nd同位素εNd(t)值也均为正值(+7.1~+13.2),指示这些火山岩很可能是特提斯洋俯冲消减过程中新生下地壳部分熔融的产物。结合区域地质资料,认为安多火山岩不可能是龙木错-双湖古特提斯洋或雅鲁藏布江新特提斯洋俯冲消减的产物,而是班公湖-怒江特提斯洋俯冲消减的产物,区域上很可能与改则北、日土地区的侏罗纪侵入岩一起构成了班公湖-怒江特提斯洋北侧的岩浆弧带。由此本文认为安多早侏罗世岛弧型火山岩是班公湖-怒江特提斯洋北向俯冲消减的产物,从而为班公湖-怒江特提斯洋的俯冲消减过程提供了直接的火山岩证据。     

2002~2005年长白山火山气体的释放特征与地球化学异常研究——多源高光谱遥感证据

长白山火山区是我国具有潜在喷发危险的活火山,在2002~2005年火山活动性增强出现了岩浆房扰动。利用卫星遥感技术具有观测范围大、观测时间长且连续的优势。因此,本文利用对流层污染探测仪（MOPITT）和大气红外探测仪（AIRS）高光谱遥感数据提取了2002~2005年长白山天池火山区CO总量、O₃总量、水汽总量和地表温度异常信息,讨论了高光谱遥感气体地球化学异常信息与火山活动性之间的关系,并对2002~2005年长白山天池火山区火山活动性进行了研究。结果表明,高光谱遥感数据观测到的气体地球化学（CO、O₃、水汽）异常与地震、形变监测结果以及地面流体（CO₂、He、H₂）观测结果相一致,表明MOPITT和AIRS高光谱遥感卫星观测到的气体异常变化较好地反映了2002~2005年大规模的深部岩浆局部扰动。在2002~2005年火山活动期间,CO总量、O₃总量、水汽总量和地表温度均出现了显著异常且异常出现时段相应准偏差显著增大,反映了气体逸出量在时间上具有不均一性,可能与火山、地震活动过程中地应力的作用和变化有关。从气体异常持续的时间以及地面观测结果综合分析,2002~2005年岩浆房扰动并没有产生长时间的地幔物质流的上升和迁移。在火山活动性增强的时间段内,地表温度出现异常低值,这可能与太平洋板块俯冲过程中引起的断裂拉张增强有关。此外,火山活动过程中逸出的气体进入大气圈产生大气化学反应也会导致高光谱遥感所观测到的气体地球化学异常。研究结果为2002~2005年长白山火山活动性的研究提供了来自高光谱遥感数据的气体地球化学新证据,也对高光谱分辨率遥感数据在火山活动规律的研究以及火山监测中的应用具有一定意义。