福建罗源湾海滩互花米草盐沼中18种金属元素的分布

本文对福建罗源湾可湖海滩互花米草盐沼中的18种金属进行了测试,结果表明,罗源湾可湖海滩的环境质量基本是好的,并探讨了开发利用互花米草的新途径。     

Defining the geochemical baseline: a case of Hong Kong soils

A geochemical baseline provides the means to distinguish between the pedogenic origin and the anthropogenic origin of the trace element in the environmental compartments. We collected 271 soil samples representative of different parent rocks and soil types from the whole territory of Hong Kong and analyzed the composition of clay mineralogy and the contents of 15 chemical elements (Fe, Cd, As, etc.) for these samples. The baseline was predicted with the method of the normalization procedure combined with the relative cumulative frequency curve. The result indicated that Fe was the best reference element for the normalization procedure among the five potential reference elements (Fe, Al, Sc, Ti, and Mn), followed by Sc and Ti. A poor correlation was found between Sc, Ti, and Cu. The predicted baseline was much lower than the A-value of the Dutch List used usually in screening the polluted soil of Hong Kong, implying that the extent of heavy metal pollution might have been underestimated with respect to local lands. We also applied the cluster analysis to distinguish the geochemical associations of the trace elements due to its importance to the baseline. Approximately three major associations including the Fe–Mn-oxides related, Al oxides or Al-bearing-clay-mineralogy related and sulfide- related associations were observed from the dendrogram.     

Multiple controls on the paleoenvironment of the Early Cambrian marine black shales in the Sichuan Basin,SW China: Geochemical and organic carbon isotopic evidence

In order to understand the paleoenvironment of the Early Cambrian black shale deposition in the western part of the Yangtze Block, geochemical and organic carbon isotopic studies have been performed on two wells that have drilled through the Qiongzhusi Formation in the central and southeastern parts of Sichuan Basin. It shows that the lowest part of the Qiongzhusi Formation has high TOC abundance, while the middle and upper parts display relative low TOC content. Redox-sensitive element (Mo) and trace elemental redox indices (e.g., Ni/Co, V/Cr, U/Th and V/(V + Ni)) suggest that the high-TOC layers were deposited under anoxic conditions, whereas the low-TOC layers under relatively dysoxic/oxic conditions. The relationship of the enrichment factors of Mo and U further shows a transition from suboxic low-TOC layers to euxinic high-TOC layers. On the basis of the Mo-TOC relationship, the Qiongzhusi Formation black shales were deposited in a basin under moderately restricted conditions. Organic carbon isotopes display temporal variations in the Qiongzhusi Formation, with a positive excursion of δ¹³C_org values in the lower part and a continuous positive shift in the middle and upper parts. All these geochemical and isotopic criteria indicate a paleoenvironmental change from bottom anoxic to middle and upper dysoxic/oxic conditions for the Qiongzhusi Formation black shales. The correlation of organic carbon isotopic data for the Lower Cambrian black shales in different regions of the Yangtze Block shows consistent positive excursion of δ¹³C_org values in the lower part for each section. This excursion can be ascribed to the widespread Early Cambrian transgression in the Yangtze Block, under which black shales were deposited.     

Paleo-redox depositional conditions inferred from trace metal accumulation in two Cretaceous-Paleocene organic-rich sequences from Central Egypt

Cretaceous-Paleocene organic-rich sediments in Egypt occur as an east-west trending belt extending from the Quseir-Safaga district (Red Sea) to the Kharga-Dakhla (Western Desert) region. They are associated with the Duwi Formation (phosphate-bearing) and the overlying Dakhla Formation (deeper epicontinental shale/marl). This study aims to reconstruct the paleo-redox conditions during deposition of these thermally immature organic-rich sediments using carbon-sulfur-iron systematics and trace metal proxies in two cores, one each from the Quseir and Abu Tartur areas. Paleoproductivity, based on P content, seems to have been higher in the Quseir section than in the Abu Tartur section. The Quseir section also records a relatively greater occurrence of anoxic conditions during the accumulation of these sediments than the Abu Tartur section. This difference is indicated by its markedly higher total organic carbon (TOC) content as well as higher contributions of redox-sensitive and sulfide-forming metals (Mo, U, Ni, V, and Co). A weak correlation exists between S and TOC, and a positive S intercept (>1) was observed in most of the rock units of the study sections. A high consistency between the TOC-S-Fe relations and trace metals findings was found. The uppermost Duwi and the lowermost Dakhla strata, which have the highest TOC and represent a maximum sea transgression during the Late Cretaceous, have the highest contents of redox-sensitive trace metals. The carbonate-dominated transgressive Baris and Beida members of the Dakhla Formation record relatively stronger oxygen-depleted conditions during their accumulation than others, which led to relatively higher TOC contents and redox-sensitive metal accumulations. A scenario for the environmental conditions that existed during the deposition of these organic-rich successions, based on compiled trace metals and TOC-S-Fe implications, is reconstructed here.     

Selenium and other trace element in phosphorites: A comparison between those of the Bayovar-Sechura and other provenances

Data of trace element composition of phosphorites are scarce and incomplete. Phosphorites of different origins can vary substantially in trace element contents. In this paper 20 trace element concentrations of 35 sample phosphorites are reported. The geographical provenance is: Bayovar-Sechura (Peru), Khouribga, Youssoufia and Boucraa (Morocco), Gafsa (Tunisia), Florida (USA), Idaho and Phosphoria Formation (USA), North Carolina (USA), Algeria, Israel, Senegal, Syria and Togo. Aqua regia extracts were used to estimate the “pseudototal” values, following standard procedures (ISO 11466, 2002) and measured by ICP-AES and ICP-MS.     

The chemistry of bottled mineral and spring waters from Norway,Sweden, Finland and Iceland

Twenty-two bottled mineral and spring waters from Norway, Sweden, Finland and Iceland have been analysed for 71 inorganic chemical parameters with low detection limits as a subset of a large European survey of bottled groundwater chemistry (N = 884). The Nordic bottled groundwaters comprise mainly Ca–Na–HCO₃–Cl water types, but more distinct Ca–HCO₃, Na HCO₃ and Na–Cl water types are also offered. The distributions for most elements fall between groundwater from Fennoscandian Quaternary unconsolidated aquifers and groundwater from Norwegian crystalline bedrock boreholes. Treated tap waters have slightly lower median values for many parameters, but elements associated with plumbing have significantly higher concentrations in tap waters than in bottled waters. The small dataset is able to show that excessive fluoride and uranium contents are potential drinking water problems in Fennoscandia. Nitrate and arsenic displayed low to moderate concentrations, but the number of samples from Finland and Northern Sweden was too low to detect that elevated concentrations of arsenic occur in bedrock boreholes in some regions. The data shows clearly that water sold in plastic bottles is contaminated with antimony. Antimony is toxic and suspected to be carcinogenic, but the levels are well below the EU drinking water limit. The study does not provide any health-based arguments for buying bottled mineral and spring waters for those who are served with drinking water from public waterworks. Drinking water from crystalline bedrock aquifers should be analysed. In case of elevated concentrations of fluoride, uranium or arsenic, most bottled waters, but not all, will be better alternatives when treatment of the well water is not practicable.     

Mesoproterozoic Lakhanda Lagerstätte, Siberia: Paleoecology and taphonomy of the microbiota

The preservation of the organic-walled microbiota of the Lakhanda Lagerstätte in the Kumakha mudstone succession of the late Mesoproterozoic Lakhanda Group (Uchur-Maya region, southeast Siberia) is a result of unusually favorable paleoecologic, taphonomic, and diagenetic conditions. Well known for its marked taxonomic diversity and exquisite preservation, the biota inhabited a warm, shallow, epicontinental basin rich in nutrients into which were dispersed clay minerals, from weathering of continental crust, and minor amounts of volcanic detritus. The fossils were preserved by compression in fine-grained smectite–illite–kaolinite mudstones deposited in a sulfur-deficient disoxic and anoxic environment. Subsequently, the long-term (1 Ga) tectonic stability of the southeast margin of the Siberian platform has provided an exceptional environment for the preservation of the microfossil assemblage without significant diagenetic alteration. Conclusions drawn here from studies of the paleoecology, taphonomy, and diagenesis of the Lakhanda Lagerstätte may provide a globally useful model in the search for additional evidence of the Precambrian rise to dominance of eukaryotes in the Earth's biosphere.     

垂直气柱中大气微量成分总含量的反演

提出了一种利用地面中等光谱分辨率的太阳红外光谱反演整层大气中某几种微量成分总含量的方法,用逐线积分（ Ｌ Ｂ Ｌ） 法计算整层大气分子吸收,采用差分吸收法测量太阳红外光谱得到实际大气中微量成分的吸收,用最大似然法反演出微量成分的总量。详细分析了这种方法的可行性和反演精度,数值模拟分析和实际测量表明该方法有较高的精度,已把该方法用于监测实际大气中甲烷和水汽总含量的变化。     

四川彭州大宝山铜矿矿石与三星堆青铜器关联性研究

四川省广汉三星堆遗址出土了大量青铜器,目前关于三星堆青铜器铜料来源的研究尚无定论,通过对大宝山铜矿遗留矿洞进行实际调查,并在不同采矿点采集矿石以及冶炼弃渣样品进行铅同位素测定以及Cu、Pb、Zn等主要金属元素,Au、Ag、Se、As、Sb等亲铜元素和Ni、Co等亲铁元素的含量测定。采用铅同位素比值法和微量元素示踪法,与前人对三星堆青铜器化学成分的研究结果进行比对,综合分析大宝山铜矿与三星堆青铜器铜料来源的关联性,结果揭示：（1）大宝山铜矿石为普通铅,用铅同位素比值法对三星堆这类含特殊铅青铜器的铜料进行溯源研究不能准确的得到其铜矿石来源。（2）微量元素含量特征表明三星堆青铜器中大部分青铜器的微量元素组合特征与大宝山铜矿的微量元素特征接近。（3）通过微量元素的进一步因子分析和聚类分析,表明三星堆部分青铜器的微量元素组合特征与大宝山铜矿大部分样品相似,该部分青铜器铜料很可能来自大宝山铜矿。