Magmatic evolution of Li–F, rare-metal granites: a case study of melt inclusions in the Khangilay complex, Eastern Transbaikalia (Russia)

We report compositions of homogenized quartz-hosted melt inclusions from a layered sequence of Li-, F-rich granites in the Khangilay complex that document the range of melt evolution from barren biotite granites to Ta-rich, lepidolite–amazonite–albite granites. The melt inclusions are crystalline at room temperature and were homogenized in a rapid-quench hydrothermal apparatus at 200 MPa before analysis. Homogenization runs determined solidus temperatures near 550 °C and full homogenization between 650 and 750 °C. The compositions of inclusions, determined by electron microprobe and Raman spectroscopy (for H₂O), show regular overall trends of increasing differentiation from the least-evolved Khangilay units to apical units in the Orlovka intrusion. Total volatile contents in the most-evolved melts reach over 11 wt.% (H₂O: 8.6 wt.%, F: 1.6 wt.%, B₂O₃: 1.5 wt.%). Concentrations of Rb range from about 1000 to 3600 ppm but other trace elements could not be measured reliably by electron microprobe. The resulting trends of melt evolution are similar to those described by the whole-rock samples, despite petrographic evidence for albite- and mica-rich segregations previously taken as evidence for post-magmatic metasomatism.

Melt variation trends in most samples are consistent with fractional crystallization as the main process of magma evolution and residual melt compositions plot at the granite minimum in the normative Qz–Ab–Or system. However, melts trapped in the highly evolved pegmatitic samples from Orlovka deviate from the minimum melt composition and show compositional variations in Al, Na and K that requires a different explanation. We suggest that unmixing of the late-stage residual melt into an aluminosilicate melt and a salt-rich dense aqueous fluid (hydrosaline melt) occurred. Experimental data show the effectiveness of this process to separate K (aluminosilicate melt) from Na (hydrosaline melt) and high mobility of the latter due to its low viscosity and relatively low density may explain local zones of albitization in the upper parts of the granite.     

鳞毛蕨天山云杉林林冠空隙特征

林冠干扰作为鳞毛蕨(Dryopteris filix-mas (L.) Schott)天山云杉(Picea schrenkiana Fisch. etMey.)林动态自维持的重要因素,在整个林分的动态发展过程中发挥着重要作用。通过对西天山国家级自然保护区内1 hm2典型的鳞毛蕨天山云杉纯林中林冠空隙特征及其形成木和边界木结构的研究,结果表明:在西天山国家级自然保护区实验区46林班内的1 hm2临时标准地中,共调查到17个林冠空隙,林冠空隙干扰返回间隔期为763年。扩展空隙面积在20~280 m2之间变化,冠空隙面积在0~180 m2之间变动。大多数林冠空隙形状变异较大,不同程度地偏离圆形,且均在20~100年之间形成,拥有多株形成木,边界木多由近熟木和成熟木组成。     

288.15 K-323.15 K下氯化锂、硫酸锂溶液的密度及摩尔体积研究

用振荡管密度计测定了常压下,温度在288.15-323.15 K范围内不同离子强度的LiCl和 Li₂SO₄溶液的密度,计算了两种锂盐在不同温度下的表观摩尔体积,溶液的浓度范围分别为(0.1~18.9) mol·kg-1及(0.03~3.0)mol·kg-1。用Pitzer离子相互作用模型拟合了LiCl和Li₂SO₄不同温度下的的Pitzer单电解质体积参数,模型的计算值与实验值相吻合良好。     

空间思维视角下李白漫游轨迹与其诗歌风格形成的关系解析

从地理空间分析的角度对李白的漫游轨迹以及诗歌中的地理空间进行研究,分析李白的行为空间与诗歌空间。研究表明:(1)李白行程数的积累为他的诗歌创作奠定了基础;(2)在政治行为空间内,李白的空间行为被放大。对于李白来说,政治行为空间对他的影响最大;(3)李白的诗歌风格很大部分在于他在漫游中建立的阔大的空间想象力以及他一生都在不停追求的政治愿望。     

富阳市万市镇十字街岩溶塌陷路基稳定性评价与治理设计探讨

浙江富阳市万市镇十字街位于岩溶塌陷区内,周围环境要求高。经过地质调查、地基稳定性分析和治理方案比选,采用高压喷射注浆法对岩溶塌陷路基进行治理,取得了良好效果。     

应用最大熵方法改进杨赤中负权系数

杨赤中插值法数学模型在解算权系数时存在负权现象,文中初步分析了负权的分布规律,增设非负约束条件,利用最大熵原理分析模型系统对空间权重系数的依赖度,研究消除格网DEM插值的负权问题。通过MATLAB编程验证算法的正确性、准确性,并与二次规划法进行比较。对比显示最大熵法解得权系数大小比例与点位关系相适应,且其估值精度优于二次规划法。     

新书介绍地质学在中国的传播与发展——以地质学教科书为中心（1853~1937）

杨丽娟. 2022. 地质学在中国的传播与发展——以地质学教科书为中心（1853~1937）. 杭州：浙江古籍出版社：1~312.     

Development of Synthetic Clinopyroxene Reference Materials for In Situ Lithium Isotope Measurement by LA-MC-ICP-MS

The isotopic composition of lithium (Li) in clinopyroxene (Cpx), determined via in situ micro-analysis, has been employed as a potential geochemical tool for studying various geological processes such as crust-mantle recycling, silicate weathering and fluid-rock interaction. To obtain precise and accurate Li isotopic compositions in Cpx by LA-MC-ICP-MS, synthetic Cpx matrix-matched reference materials (RMs) were prepared in this study. Six Cpx-matrix RMs were prepared by mixing metallic oxides with GSP-2 (granodiorite) or pure L-SVEC solution and melting them into glasses (GSP-2 + oxide; L-SVEC + oxide). Two representative synthetic glasses, CPXA01 and CPXB01, were subjected to a series of analyses to investigate the possible qualification of the RMs for in situ Li isotope measurement by LA-MC-ICP-MS, including elemental homogeneity analysis (elemental mapping analysis and spot analysis), Li isotopic homogeneity analysis and accurate Li isotopic determination. The applicability of the synthetic Cpx-matrix RMs was highlighted by comparing the δ⁷Li values of three natural Cpx calibrated against the synthetic Cpx-matrix RMs and other commonly used RMs with different matrices (NIST SRM 612, BCR-2G, GOR128-G, StHs6/80-G, KL2-G and T1-G), respectively. Additionally, CPXB01-05 RMs with the same matrix but different Li contents were prepared to explore the Li content mismatch effect, which is significant for accurate determination of in situ Li isotopic composition by LA-MC-ICP-MS. The results of the cross-calibration of Li isotopes in CPXA01 and CPXB01 suggested no obvious Li isotopic fractionation between the two types of glasses (GSP-2 + oxide; L-SVEC + oxide). Thus, the two methods of producing Cpx-matrix RMs are suitable for preparing the matrix-matched RMs for in situ microanalysis for Li isotopes.     

Late-time photometry of two nearby type II-P supernovae： 2004dj and 2004et

We present late-time photometry for two bright type II-P supernovae （SNe） 2004dj and 2004et, extending over 400 d after the explosion, which are measured with a set of intermediate-band filters that have the advantage of tracing the strength variations of some spectral features. Although these two SNe II-P exhibit similar photometric evolution at earlier times, they diverge during the nebular phase. SN 2004dj shows a slow late-time decline rate with - 0.7 ±0.1 mag （100d）^-1 during the period ranging from t ≈ 200 - 300 d after the explosion, while SN 2004et shows a much faster decline rate at a comparable phase, e.g., 1.3 ± 0.1 mag （100d）^-1. The steeper decay rate seen in SN 2004et is likely due to dust formation in the explosion ejecta. Based on intermediate-band photometry, we derived the evolution of the feature lines [e.g., Hα] of SNe 2004dj and 2004et which are similar in flux at comparable phases but perhaps with significantly different decay rates. The origin of the observed variations in the continuum and the feature lines is briefly discussed.