Geometry and architectural associations of co-genetic debrite–turbidite beds in basin-margin strata, Carboniferous Ross Sandstone (Ireland): Applications to reservoirs located on the margins of structurally confined submarine fans

Co-genetic debrite–turbidite beds are most commonly found in distal basin-plain settings and basin margins. This study documents the geometry, architectural association and paleogeographic occurrence of co-genetic debrite–turbidite beds in the Carboniferous Ross Sandstone with the goal of reducing uncertainty in the interpretation of subsurface data in similarly shaped basins where oil and gas is produced.The Ross Sandstone of western Ireland was deposited in a structurally confined submarine basin. Two outcrops contain co-genetic debrite–turbidite beds: Ballybunnion and Inishcorker. Both of the exposures contain strata deposited on the margin of the basin. An integrated dataset was used to characterize the stratigraphy of the Ballybunnion exposure. The exposure is divided into lower, middle, and upper units. The lower unit contains laminated shale with phosphate nodules, structureless siltstone, convolute bedding/slumps, locally contorted shale, and siltstone turbidites. The middle unit contains co-genetic debrite–turbidite beds, siltstone turbidites, and structureless siltstone. Each co-genetic debrite–turbidite bed contains evidence that fluid turbulence and matrix strength operated alternately and possibly simultaneously during deposition by a single sediment-gravity-flow event. The upper unit contains thin-bedded sandy turbidites, amalgamated sandy turbidites, siltstone turbidites, structureless siltstone, and laminated shale. A similar vertical facies pattern is found at Inishcorker.Co-genetic debrite–turbidite beds are only found at the basin-margin. We interpret these distinct beds to have originated as sand-rich, fully turbulent flows that eroded muddy strata on the slope as well as interbedded sandstone and mudstone in axial positions of the basin floor forming channels and associated megaflute erosional surfaces. This erosion caused the axially dispersing flows to laterally evolve to silt- and clay-rich flows suspended by both fluid turbulence and matrix strength due to a relative increase in clay proportions and associated turbulence suppression. The flows were efficient enough to bypass the basin center/floor, physically disconnecting their deposits from coeval lobes, resulting in deposition of co-genetic debrite–turbidite beds on the basin margin. The record of these bypassing flows in axial positions of the basin is erosional surfaces draped by thin siltstone beds with organic debris.A detailed cross-section through the Ross Sandstone reveals a wedge of low net-to-gross, poor reservoir-quality strata that physically separates sandy, basin-floor strata from the basin margin. The wedge of strata is referred to as the transition zone. The transition zone is composed of co-genetic debrite–turbidite beds, structureless siltstone, slumps, locally contorted shale, and laminated shale. Using data from the Ross Sandstone, two equations are defined that predict the size and shape of the transition zone. The equations use three variables (thickness of basin-margin strata, thickness of coeval strata on the basin floor, and angle of the basin margin) to solve for width (w) and trajectory of the basinward side of the low net-to-gross wedge (β). Beta is not a time line, but a facies boundary that separates sandy basin floor strata from silty basin-margin strata. The transition zone is interpreted to exist on lateral and distal margins of the structurally confined basin.Seismic examples from Gulf of Mexico minibasins reveal a wedge of low continuity, low amplitude seismic facies adjacent to the basin margin. Strata in this wedge are interpreted as transition-zone sediments, similar to those in the Ross Sandstone. Besides defining the size and shape of the transition zone, the variables “w” and “β” define two important drilling parameters. The variable “w” corresponds to the minimum distance a well bore should be positioned from the lateral basin margin to intersect sandy strata, and “β” corresponds to the deviation (from horizontal) of the well bore to follow the interface between sandy and low net-to-gross strata. Calculations reveal that “w” and “β” are related to the relative amount of draping, condensed strata on the margin and the angle of the basin margin. Basins with shallowly dipping margins and relatively high proportions of draping, clay-rich strata have wider transition zones compared to basins with steeply dipping margins with little draping strata. These concepts can reduce uncertainty when interpreting subsurface data in other structurally confined basins including those in Gulf of Mexico, offshore West Africa, and Brunei.     

Provenance of deep-water reservoir sandstones from the Jubarte oil field,Campos Basin,Eastern Brazilian Margin

The provenance of the Maastrichtian deep-water reservoir sandstones from the Jubarte oil field (Campos Basin, eastern Brazil), was studied using an integrated approach that included quantitative petrography, conventional heavy mineral analysis, garnet mineral chemistry and zircon geochronology. The reservoirs are predominantly coarse, poorly-sorted sandstones with feldspathic composition derived from uplifted basement terrains. The fourth- and fifth-order depositional sequences analyzed show no major variations in composition or in provenance through time. However, variations in apatite:tourmaline presents potential to be used as a parameter for sandstone correlation within the field. The composition of heavy minerals indicates derivation from high temperature and low-to-medium pressure aluminous metapelitic rocks, from granites and subordinate mafic rocks, derived from the Cabo Frio Tectonic Domain and the Oriental terrain of Ribeira orogen, characterizing a supply route from SW to NE. The low ZTR index, as well as the absence of low-grade stable heavy minerals and of metasedimentary rock fragments, suggest that by the end of Cretaceous all supracrustal, low-grade terrains had already been totally eroded, and that plutonic, infracrustal rocks were exposed, similarly to the present situation.     

Geochemical overview and undiscovered gas resources generated from Hamitabat petroleum system in the Thrace Basin,Turkey

Since the first drill in 1957, three oil, 19 gas and condensate fields have been discovered in the Thrace Basin. However, any petroleum system with its essential elements and processes has not been assigned yet. This study consists of two parts, (1) geochemical overview of the previous work in order to get a necessary help to construct a petroleum system and (2) calculation of quantitative undiscovered hydrocarbon resources generated from this system. An extensive overview study showed that the primary reservoir and source rocks in the Thrace Basin are the Middle Eocene Hamitabat sandstones and shales, respectively, hence it appears that the most effective petroleum system of the Thrace Basin becomes the Hamitabat (!) petroleum system. Currently, 18.5 billion m³ of in-place gas, 2.0 million m³ (12.7 million bbl) in-place waxy oil as well as minor amount of associated condensate were discovered from this system. This study showed that the regional distribution of the oil and gas fields almost overlapped with the previously constructed pod of active Hamitabat shales implying that short and up-dip vertical migration pathway of hydrocarbons from the source to trapping side was available. Thermal model demonstrated that hydrocarbon generation from the Hamitabat shales commenced in the Early Miocene. The amount of quantitative gas generation based on the mean-original TOC = 0.94 wt%, mean-original HI = 217 HC/g TOC and the volume of the pod of active source rock = 49 km³ is approximately 110 billion m³ of gaseous hydrocarbons that results in a high generation–accumulation efficiency of 17% when 18.5 billion m³ of already discovered hydrocarbons are considered.     

Petroleum composition in the Cuu Long Basin (Mekong Basin) offshore southern Vietnam

The Cuu Long Basin (Mekong Basin) is a rift basin off southern Vietnam, and the most important petroleum producing basin in the country. However, information on petroleum type and characteristics has hitherto been largely unavailable to the public. This paper presents petroleum geochemical data on nine oil samples from four different producing fields in the Cuu Long Basin: the Dragon (Rong), Black Lion (Sutu-Den), Sunrise (Rang ?ong) and White Tiger (Bach Ho) Fields. The oils are highly paraffinic with bimodal normal alkane distributions and show moderate pristane to phytane ratios and a conspicuous hyperbolic decrease in abundance with increasing carbon number of hopane homologues from C₃₀ to C₃₅. The TPP-index of Holba et al. (Holba, A.G., Dzou, L.I., Wood, G.D., Ellis, L., Adam, P., Schaeffer, P., Albrecht, P., Greene, T., Hughes, W.B., 2003. Application of tetracyclic polyprenoids as indicators of input from fresh–brackish water environments. Organic Geochemistry 34, 441–469) is equal to 1 in all samples which in combination with tricyclic triperpane T26/T25 ratios >1 and the n-alkane and hopane distributions mentioned above provide a strong indication of an origin from lacustrine source rocks. This is supported by the absence of marine C₃₀ desmethyl steranes (i.e. 24-n-propylcholestanes) and marine diatom-derived norcholestanes. Based on the overall biological marker distributions, the lakes probably belonged to the overfilled or balanced-fill types defined by Bohacs et al. (Bohacs, K.M., Carroll, A.R., Neal, J.E., Mankiewicz, P.J., 2000. Lake-basin type, source potential, and hydrocarbon character. An integrated sequence-stratigraphic–geochemical framework. AAPG Studies in Geology 46, 3–34). The oils were generated from source rocks at early- to mid-oil-window maturity, presumably Oligocene lacustrine shales that are present in the syn-rift succession. Oils from individual fields may, however, be distinguished by a combination of biological marker parameters, such as the oleanane index, the gammacerane index, the relative abundance of tricyclic terpanes, the proportions of diasteranes and 28-norspergulane, complemented by other parameters. The oils of the Cuu Long Basin show an overall similarity to the B-10 oil from the Song Hong Basin off northern Vietnam, but are markedly different from the seepage oils known from Dam Thi Nai on the coast of central Vietnam.     

Mantle plumes and the metamorphism of the lower crust and their influence on basin evolution

Since the stretching model appears to be not applicable to the subsidence of accretionary crust, basins located on this crust type may have an alternative origin. Examples of such basins are the West Siberia Basin and the North German Basin. Both basins showed intensive volcanism and magmatism during the initial phase of their development. Remarkably, the West Siberia Basin is closely located to the (hotspot related) Siberian flood basalts with a similar Permo-Triassic age, and the location of the North German Basin in Permian times is identical with the present day position of the Tibesti hotspot in Northern Africa. These two basins may have specific relations to hotspot heat sources of the Earth's underlying mantle. Due to these heat sources, thermal metamorphism within the lower layers of the (accretionary) crust may occur, resulting in rock density increase and subsequent shrinkage of the affected rock volumes. These shrinkage processes will lead to the development of topographic lows, their filling with sediments, and the subsequent start of an exponentially declining isostatic/metamorphic basin subsidence. In addition to the analyses of metamorphic processes, potential field anomalies, temperature fields, and histories of subsidence have been integrated into one single model that can explain the development of the North German Basin. Similarly, the East African Rift and Eifel Hotspots affected parts of the overriding continental plates. The East African Rift Hotspot can be traced back to the Afar flood basalts and the Dniepr–Donets Basin, whereas the Eifel Hotspot can be linked to the North Sea Basin. Continental drift templates, present day hotspot locations, flood basalt areas, metamorphic facies as function of temperature, and crust categories are taken as published in recent literature.     

Modeling an atypical petroleum system: A case study of hydrocarbon generation,migration and accumulation related to igneous intrusions in the Neuquen Basin,Argentina

In the Altiplanicie del Payún area (Neuquen Basin, Argentina), immature source rock sections intruded by up to 600 m thick Tertiary laccoliths show full spectrum maturity aureoles over hundreds of meters from the contacts. Commercial oil accumulations (20–33°API) and oil shows are located along the entire column, both in sandstone/carbonate and fractured igneous reservoirs. A challenging numerical model that included the emplacement of the intrusive bodies, with extreme temperature ranges and unusually short calculation time steps, has been done with the aim to better understand hydrocarbon generation and migration processes related to these thermal anomalies.     

Ecophysiological characteristics of invasive Spartina alterniflora and native species in salt marshes of Yangtze River estuary,China

Biological invasions represent one of the significant components of global change. A comparative study of invaders and co-occurring natives is a useful approach to gaining insights into the invasiveness of exotic plants. Spartina alterniflora, a C₄ grass, is a widespread invader in the coastal wetlands in China and other regions of the world. We conducted a comparative study of S. alterniflora and native C₃ species, Phragmites australis and Scirpus mariqueter, in terms of their gas exchange and efficiencies in resource utilization. We tested the hypothesis that S. alterniflora has growth-related ecophysiological advantages over the natives in its non-native range, which result in its rapid growth and enhance its invasiveness. Photosynthesis, leaf area index (LAI), specific leaf area (SLA), and the efficiency of resource use (light, water, and nitrogen) were examined monthly for eight months in 2004. Overall, S. alterniflora had greater LAI, higher maximal net photosynthetic rate (A_max), and longer growing season than those of the native species. On average, the efficiencies of S. alterniflora in light, water, and nitrogen utilization were respectively 10.1%, 26.1%, and 33.1% higher than those of P. australis, and respectively 70.3%, 53.5%, 28.3% higher than those of S. mariqueter. However, SLA of S. alterniflora was significantly lower than those of P. australis and S. mariqueter. Although there was no general pattern in the relationship between invasiveness and plant photosynthetic types, in this study, most of the ecophysiological characteristics that gave S. alterniflora a competitive advantage in the Yangtze River estuary were associated with photosynthetic pathways. Our results offer a greater understanding of the relationship between invasiveness and plant photosynthetic type. Our results also indicate that LAI and the length of the photosynthetic season, which vary with habitats, are also important in invasion success.     

Distribution and sources of organochlorine pesticides in water and sediments from Daliao River estuary of Liaodong Bay,Bohai Sea (China)

The levels of 19 kinds of organochlorine pesticides (OCPs) in the aqueous phase, suspended particulate matter (SPM), pore water and sediments from Daliao River estuary of Liaodong Bay (Bohai Sea) in northeast China were investigated to evaluate their potential pollution risks. The total OCPs concentrations in the aqueous phase, SPM, pore water and sediments were 3.7–30.1 ng l⁻¹, 4.6–52.6 ng l⁻¹, 157–830 ng l⁻¹ and 2.1–21.3 ng g⁻¹ dry weight, respectively. The concentrations of OCPs, in the Daliao River estuary, are in the mid-range, as compared to those reported in other estuaries worldwide. The distribution of HCHs and DDTs were different indicating different contamination sources. Lindane is the main type of HCH and continuing use in northeast China of ‘pure’ HCH (lindane) rather than technical HCH accounts for the source. The ratios of (DDE + DDD)/DDT in the samples indicate no recent inputs of these chemicals to the estuary.     

珠江口淇澳岛海岸带反硝化作用研究

采用N2通量法,在一套连续流动培养装置中测定珠江口淇澳岛海岸带的反硝化速率,探讨各种因素对淇澳岛海岸带反硝化速率的影响.结果表明,反硝化速率受NO3-的利用率影响,而不是NO3-的绝对浓度.大型红树植物对淇澳岛海岸带的反硝化速率影响最大,其次是硝酸盐利用率,而有机质含量的影响较小.由于大型红树植物的影响,样品Q0411-5的反硝化速率比同在岛内的Q0411-3高出1倍.样品Q0412-14的NO3-培养前后的浓度变化(△NO3-)是Q0412-9的4倍多,因为受硝酸盐利用率的影响,它的反硝化速率却是Q0412-9的2倍多.温度对反硝化速率的影响程度尚不能确定.     

夏季长江口外海区域上升流现象的数值研究

基于Blumberg等(1996)的ECOMSED模式,对长江口外海区域夏季的上升流现象进行了数值模拟.模式综合考虑径流,风应力,环流,热通量和M_2,S_2,K_1,O_1四个主要分潮的作用,从而提高长江口外海区域上升流模拟的准确性和可靠性,并通过各种控制实验分析了其动力机制,进一步说明本区域影响上升流的主要因子.数值实验表明,长江口外水下河谷的南边(杭州湾口门中心东侧),上升流主要是由向北流动的台湾暖流通过底Ekman效应和陆坡的抬升共同作用产生的.夏季偏南风对长江口外水下河谷西侧上升流的产生有一定影响,但作用不大.此外,潮汐潮流对上升流的产生也起着一定的作用,但在本文关注的上升流区潮作用影响不大.