Short-period Jupiter family comets after Stardust

The NASA Stardust mission has provided for laboratory study an extensive data set of cometary dust of known provenance (from comet 81P/Wild 2) yielding detailed insights into the composition of the comet. Combined with the results of data from other missions to short-period Jupiter family comets (JFC), this has greatly deepened the understanding of such objects. If depressions on the surface of comet 81P/Wild 2 are all taken as evidence of impact cratering, their number suggests a long occupancy in the outer region of the Solar System. The dust from comet 81P/Wild 2 has been shown to be heavily deficient in pre-Solar grains and rich in materials formed at high temperatures in the inner Solar System. Although it is too early to know if this is typical of JFC, it does argue for rapid and thorough mixing of materials in the disk on timescales related to comet formation, and may also suggest outward migration of small icy bodies after their formation. Thus, instead of providing mainly new knowledge of the pre-Solar materials expected to be rich in comets, Stardust and comet 81P/Wild 2 have instead focussed attention on large-scale transport processes during the critical period when cometary parent bodies were forming in the early Solar System.     

X-ray spectral evolution of the extragalactic Z source LMC X-2

We present the results obtained by a detailed study of the extragalactic Z source LMC X-2, using broad-band Suzaku data and a large (∼750 ks) data set obtained with the proportional counter array (PCA) onboard the Rossi X-ray Timing Experiment ( RXTE ). The PCA data allow the study of the complete spectral evolution along the horizontal, normal and flaring branches of the Z track. Comparison with previous studies shows that the details of spectral evolution (like the variation of Comptonizing electron temperature) are similar to those of GX 17+2 but unlike those of Cyg X-2 and GX 349+2. This suggests that Z sources are a heterogeneous group, with perhaps LMC X-2 and GX 17+2 being members of a subclass. However, non-monotonic evolution of the Compton y parameter seems to be generic to all sources. The broad-band Suzaku data reveal that the case in which the additional soft component of the source is modelled as disc blackbody emission is strongly preferred over the one where it is taken to be a blackbody spectrum. This component, as well as the temperature of seed photons, does not vary when the source goes into flaring mode, and the entire variation can be ascribed to the Comptonizing cloud. The bolometric unabsorbed luminosity of the source is constrained to be  ∼2.23 × 10³⁸ erg s⁻¹  , which, if the source is Eddington-limited, implies a neutron star mass of  1.6 M_⊙  . We discuss the implications of these results.     

GPS观测研究青藏东北缘的水平变形特征

推导了利用位移场计算主应变、面膨胀、最大剪应变的公式,通过2次重复GPS观测结果,计算了新青藏高原东北缘在1999～2001年间的水平主应变、面膨胀、最大剪应变等水平变形特征量的分布,并分析了在观测后发生的德令哈6．6级地震活动与变形场特征量之间的分布关系。采用力学理论对该地区的地质构造运动、局部形变特征与地震活动的关系进行了讨论。得出了一些有意义的结论和认识。     

Decompression and H<Subscript>2</Subscript>O exsolution driven crystallization and fractionation: development of a new model for low-pressure fractional crystallization in calc-alkaline magmatic systems

Magma ascent, decompression-induced H₂O exsolution and crystallization is now recognized as an important process in hydrous subduction zone magmas. During the course of such a process calculations suggest that the ascent rate of a degassing and crystallizing mafic magma will be greater than crystal settling velocities. Thus, any crystals formed as a consequence of volatile exsolution will remain suspended in the magma. If the magma erupts before the percentage of suspended crystals reaches the critical crystallinity value for mafic magma (~55 vol.%) it will produce the commonly observed crystal rich island arc basalt lava. If the magma reaches its critical crystallinity before it erupts then it will stall within the crust. Extension of compaction experiments on a 55 vol.% sand-Karo syrup suspension at different temperatures (and liquid viscosities) to the likely viscosities of interstitial andesitic to dacitic liquid within such a stalled magma suggest that small amounts (up to ~10%) can be expelled on a time scale of 1–10 years. The expelled liquid can create a new intermediate to silicic body of magma that is related to the original mafic magma via fractional crystallization. The short time scale for liquid expulsion indicate that decompression-induced H₂O exsolution and crystallization can be an important mechanism for fractional crystallization. Based on this assumption a general model of decompression-induced crystallization and fractionation is proposed that explains many of the compositional, mineralogical and textural features of Aleutian (and other andesites).     

On the swelling potential of compacted high plasticity clays

We conducted a study of the spatial distributions of seismicity and earthquake hazard parameters for Turkey and the adjacent areas, applying the maximum likelihood method. The procedure allows for the use of either historical or instrumental data, or even a combination of the two. By using this method, we can estimate the earthquake hazard parameters, which include the maximum regional magnitude Mˆ_max, the activity rate of seismic events and the well-known bˆ value, which is the slope of the frequency-magnitude Gutenberg-Richter relationship. These three parameters are determined simultaneously using an iterative scheme. The uncertainty in the determination of the magnitudes was also taken into consideration. The return periods (RP) of earthquakes with a magnitude M ≥ m are also evaluated. The whole examined area is divided into 24 seismic regions based on their seismotectonic regime. The homogeneity of the magnitudes is an essential factor in such studies. In order to achieve homogeneity of the magnitudes, formulas that convert any magnitude to an M_S-surface scale are developed. New completeness cutoffs and their corresponding time intervals are also assessed for each of the 24 seismic regions. Each of the obtained parameters is distributed into its respective seismic region, allowing for an analysis of the localized seismicity parameters and a representation of their regional variation on a map. The earthquake hazard level is also calculated as a function of the form Θ = (Mˆ_max,RP_6.0), and a relative hazard scale (defined as the index K) is defined for each seismic region. The investigated regions are then classified into five groups using these parameters. This classification is useful for theoretical and practical reasons and provides a picture of quantitative seismicity. An attempt is then made to relate these values to the local tectonics.     

Nucleation and crystallization of otavite, witherite, calcite, strontianite, hydrozincite, and hydrocerussite by CO2 membrane diffusion technique

Otavite, witherite, calcite, strontianite, hydrozincite and hydrocerussite nucleation was induced by CO₂ diffusion through a polyethylene membrane into a metal bearing solution. Nucleation and ongoing precipitation was followed at 25 ± 1 °C by the chemical evolution of the solution and the consumption of sodium hydroxide (pH-stat conditions). X-ray diffraction patterns as well as FT-infrared and Raman spectra confirmed the formation of well crystallized solids, except for less crystalline hydrozincite. In several experiments simonkolleite and laurionite precipitated concurrently with hydrozincite and hydrocerussite. The carbonate end-member minerals, smithsonite and cerussite, however were not formed. Carbonate minerals crystallized as spherical aggregates of thin layered otavite, spherical orientated witherite needles, rhombohedral calcite, pseudo-hexagonal strontianite laths, fibrous lumps of hydrozincite and planar hexagonal hydrocerussite crystals. Crystal and aggregate sizes range between 1 and 100 μm. Nucleation occurred at well defined reaction times and distinct critical supersaturation indices (SI_crit). The time for nucleation at constant pH decreased as the initial metal concentration increased for a given solid. The SI_crit values decreased in the order of hydrocerussite (3.2), otavite (2.5), strontianite (1.6), witherite (0.9) and calcite (0.7).     

Lithospheric flexure, uplift and expected horizontal strain rate in the Pannonian Carpathian region

The Apuseni Mountains are located between the Pannonian Basin and the Transylvanian Basin along a direction of SE convergence with the Carpathian belt. A flexural model based on the cylindrical bending of a semi-infinite, isostatically supported, thin elastic plate is here examined with the Apuseni playing the role of flexural bulge, and under the assumption that the plate is deforming under the action of a vertical shear force and a bending moment applied at the end of the plate, beneath the Carpathians. The model yields estimates of the plate thickness ranging between 13 and 14.5 km, depending on the assumed density contrast between crust/sediments and mantle providing buoyancy. The vertical shear force which is necessary to bend the plate is in the range between 60 and 300 × 10¹¹ N m^− 1, depending on the assumed density contrast. This force is shown to be modelled by a gravitational ‘slab pull’ force, using model parameters derived from seismic tomography. If the height of the flexural bulge, after correction for erosion, is allowed to increase, the model yields an estimate of the horizontal strain rate at the top of the bulge. For example, 5 mm/yr vertical change of the flexural bulge of a 14 km thick plate results in a horizontal deformation rate of approximately 7 nanostrain/yr at the top of the bulge, a value which is at the threshold of sensitivity of continuous GPS measurements. Different vertical rates will change the horizontal strain rate almost proportionally.     

Comparison of Fry strain ellipse and AMS ellipsoid trends to tectonic fabric trends in very low-strain sandstone of the Appalachian fold–thrust belt

In moderately to highly strained sandstones, both the long axis of the bedding-parallel finite-strain ellipse, as calculated by the normalized Fry method, and the projection of the long axis of the AMS ellipsoid on the plane of bedding, align well with local “structural grain” (trends of cleavage, folds, and faults). This relationship implies that results of both 2D Fry and AMS analyses represent the local layer-parallel tectonic strain component. Do both methods provide comparable results for very low-strain sandstone (e.g., <5%)? To address this question, Fry and AMS analyses were conducted in very low-strain sandstone from two localities in the Appalachian foreland fold–thrust belt: near Rosendale in New York and the Lackawanna synclinorium of Pennsylvania. We compared the map projections of both bedding-parallel Fry ellipses and AMS ellipsoids to the local structural grain. In both study areas, projections of the long axis of Fry strain ellipses do not cluster in a direction parallel to structural grain, whereas the projection of the long axes of AMS ellipsoids do cluster closely to structural grain. This observation implies that in very low-strain sandstone, AMS analysis provides a more sensitive “quick” indicator of tectonic fabric than does normalized Fry analysis.     

高效液相色谱-紫外光谱分析氢醌-双(β-羟乙基)醚

建立了高效液相色谱-紫外光谱法测定聚氨酯扩链剂氢醌-双(β-羟乙基)醚(HQEE)工业品中HQEE主含量和对苯二酚残留的方法。在氰基柱上,以甲醇-水-1%乙酸溶液(体积比10∶50∶40)为流动相,流速1.0 mL/min时,HQEE、对苯二酚及其他相关杂质得到良好分离,紫外光谱285 nm检测。方法简便、快捷,结果准确可靠,在工业生产中可有效地指导HQEE合成过程的质量控制。     

电感耦合等离子体质谱法测定岩石样品中的锆铌铪钽两种预处理方法的比较

研究了微波消解酸溶和过氧化钠碱熔两种测定岩石样品中锆、铌、铪、钽前处理方法,利用电感耦合等离子体质谱法进行测定。对所选用不同种类的岩石国家标准物质样品进行了条件实验,结果表明:采用过氧化钠碱熔法处理岩石样品后,锆、铌、铪、钽的测量值准确度高,且相对标准偏差(RSD,n=10)小于6%,该方法更适用于岩石样品中锆、铌、铪、钽的测定。