Zn2+对日本沼虾(Macrobrachium nipponensis)的急性致毒效应

在水温(27.4±1.3)℃条件下,以体长(33.23±1.66)mm、体质量(0.7893±0.1518)g的日本沼虾为实验动物,采用静水停食法开展了Zn2+对日本沼虾的急性毒性实验,并以此为基础,测定了Zn2+不同质量浓度水平下日本沼虾的耗氧率与窒息点.结果表明:(1)Zn2+对日本沼虾的急性致死效应与其呼吸生理代谢受阻密切相关;(2) Zn2+对日本沼虾24h、48h、72h、96h的半致死质量浓度依次为1.493、0.844、0.643和0.464mg/L; (3) Zn2+对日本沼虾昼均、夜均和日均耗氧率均无显著影响的阈值为0.046mg/L,该值为Zn2+对日本沼虾急性毒性的安全质量浓度;(4) Zn2+对日本沼虾产生轻度胁迫和中度胁迫的质量浓度范围分别为0.046-0.064mg/L和0.064-0.082mg/L.     

“MgO/AC”复合材料对水溶液中Cu~(2+)和Cr(Ⅵ)的吸附性能研究

用造纸草浆黑液和氯化镁为原料制得氧化镁/活性炭("MgO/AC")复合材料,分别测定了该复合材料对水溶液中Cu2+与Cr(Ⅵ)的脱除性能。Cu2+的吸附随pH值的升高而增大,pH=3时基本达到平衡;在实验考察的pH范围内(1~8),Cr(Ⅵ)的吸附呈单调递减趋势。动力学拟合结果表明,"MgO/AC"复合材料对Cu2+和Cr(Ⅵ)的吸附过程均符合伪二级动力学方程;两过程的吸附速率均随吸附温度的升高而增大,表现为吸热吸附;吸附活化能Ea分别为50.19,51.42 kJ.mol-1;"MgO/AC"复合材料对Cu2+的吸附优于对Cr(Ⅵ)的吸附。Cu2+在"MgO/AC"复合材料上的吸附过程用Langmuir模型描述更为合适,在293~323 K范围内,Cu2+的饱和吸附量为19.46~90.91 mg.g-1;Cr(Ⅵ)的吸附过程则更符合Freundlich模型。     

2008年1次沙尘暴事件对厦门岛大气中SO2等污染物含量的影响

2008年5月27～29日源自内蒙古南部的沙尘暴于5月30日到达厦门.受其影响,30日晚厦门风速最高达到12.6 m/s;31日本监测站大气中CO、NO2和NO含量明显下降,分别从551.3μg/m^3下降至218.9μg/m^3,从25.0μg/m^3下降至6.7μg/m^3,从8.1μg/m^3下降至0.1μg/m^3;6月1日其分别回升至682.4、28.7、6.5μg/m^3.与CO、NO2和NO不同,PM10和SO2含量在5月31日没有明显变化,PM10含量从5月31日晚的10.1μg/m^3上升至6月1日的232.6μg/m^3,SO2含量从5月底的25.0μg/m^3上升至52.0μg/m^3,并且两者的变化显示出较好的相关性（R2=0.65）.据此认为本次沙尘暴到达厦门时,在引起PM10含量增加的同时还引起了SO2含量的升高.这是沙尘暴引起中国南方城市SO2含量升高的首次报道.尽管目前SO2在中国的分布和传输已有较多研究,但对于沙尘暴在中国南方城市传输SO2的机制仍需进一步的探讨.     

Short-term variabilities of upper ocean current in the warm pool region during TOGA/COARE IOP

Oceanic current data in the warm pool region of the western equatorial Pacific measured by upward-looking moored Acoustic Doppler Current Profilers at two equatorial sites (147°E and 154°E) and two off-equatorial sites (2°N and 2°S, 156°E) during TOGA/COARE Intensive Observing Period (IOP) from November 1992 to February 1993 are used to examine short-term variabilities in the upper layer above 160–240 m. In time series of the zonal and meridional currents in many layers, spectral peaks are found at periods around 2 days and 4 days in addition to high energies in a period range longer than 10 days. The signal with the period of about 2 days has significantly high energies at all sites, and its magnitude is higher for the meridional current than for the zonal one. This signal is especially active in the first half of IOP from November to December in 1992. In this period, the quasi-2-day signal in the current field is coherent between northern (2°N) and southern (2°S) stations, but it has no evident relationship with that in the surface wind field around the stations. The quasi-4-day signal with the period of about 4 days has highest energies in layers above 160 m at the southern station, and is coherent between northern and southern stations. Besides, the signal at the station of 2°S has a significantly high coherence with that in the wind at the southern station, suggesting that it is a local phenomenon.     

九孔鲍BMP-2基因cDNA克隆及表达分析

为探究BMP-2基因在九孔鲍(Haliotisdiversicolorsupertexta)中的功能,采用cDNA末端快速扩增(RACE)技术从九孔鲍外套膜中获得了BMP-2基因cDNA全长,并用实时荧光定量PCR(qRT-PCR)检测了BMP-2基因在各组织和发育时期的表达水平。结果表明:九孔鲍BMP-2基因cDNA全长2572bp,其中5′非编码区(5′UTR)123bp, 3′非编码区(3′UTR)1150bp,开放阅读框(ORF)为1299 bp,编码432个氨基酸,其分子质量为48.59ku,理论等电点(pI)为9.84;具有N端信号肽(1-39 aa)、TGF-β前肽区域(63-294 aa)和TGF-β成熟肽区域(331-432 aa),以及蛋白酶水解位点RLRR (272-275 aa)和7个保守的半胱氨酸残基,符合TGF-β超家族蛋白典型结构特征。系统进化树结果显示九孔鲍BMP-2基因和耳鲍聚为一支。qRT-PCR结果表明BMP-2基因在九孔鲍的6个组织中均有表达,在足、右侧壳肌、外套膜及肝脏中显著高表达;在检测的7个发育时期均表达,其中在受精卵、4细胞、8细胞、原肠胚、稚鲍时期表达量显著高于卵、幼鲍时期。研究表明BMP-2基因可能在九孔鲍贝壳形成中具有重要作用。     

可见光下Li+/CNTS-TiO2光催化剂降解海洋柴油污染的研究

通过溶胶-凝胶法,以CNTS-TiO₂为前驱物制备了Li⁺掺杂CNTS-TiO₂的纳米复合光催化剂(以下均称为Li⁺/CNTS-TiO₂),采用X射线衍射(XRD)、扫描电镜(SEM)等测试手段对光催化剂进行表征,结果表明制得的催化剂为纳米材料且在TiO₂的基础上增大了比表面积。利用掺杂量为3%的Li⁺掺杂CNTS-TiO₂复合光催化剂(以下均称为3%Li⁺/CNTS-TiO₂)光催化降解海洋柴油污染,在可见光条件下考察了Li⁺掺杂量、煅烧温度、光催化剂投加量、柴油初始质量浓度、光催化反应时间、H₂O₂质量浓度等条件对光催化实验的影响。进行正交实验,确定最优化工艺条件为:Li⁺掺杂量为3%,光催化剂的煅烧温度为600 ℃,3%Li⁺/CNTS-TiO₂的投加量为0.1 g/L,降解柴油初始质量浓度为0.4 g/L,光催化反应时间为3 h,H₂O₂质量浓度为0.6 g/L,降解率可以达到95%以上。同时对此光催化剂进行应用试验,试验结果表明光催化剂去除效果优异,去除率可达91.87%。     

基于新型高频声学多普勒流速剖面仪的河口近底部边界层观测初探

河口物质输运、能量交换与底边界层内的水动力过程密切相关,底边界层参数(如切应力、拖曳系数)的确定至关重要。挪威Nortek公司生产的新型声学多普勒流速剖面仪AD2CP相比传统ADCP具有高频、低噪的优点,可用于高频(16Hz)流速剖面观测,而被广泛应用于底边界层观测的ADV只能测量单点高频流速。本文采用AD2CP在长江口南槽最大浑浊带区域进行座底式观测,并与同步近底部三脚架上ADV的观测结果进行对比。结果表明,使用AD2CP测得的近底部平均流速与ADV的测量结果吻合良好;使用惯性耗散法计算了底切应力,基于ADV的单点高频流速数据计算结果为2.16×10~(-2)～5.69×10~(-1)N/m~2,基于AD2CP的结果为2.09×10~(-2)～4.26×10~(-1)N/m~2,二者范围大致相当。在此基础上,基于AD2CP数据计算出摩阻流速为4.55×10~(-3)～2.06×10~(-2)m/s、底拖曳系数范围为1.84×10~(-4)～2.49×10~(-3),与ADV的计算结果基本一致。此外,由于AD2CP可以获得高频的流速剖面数据,优于单点ADV,具备观测近底部边界层参数和边界层内湍流剖面的潜力。     

Global Statistical Assessment and Cross-Calibration with Jason-2 for Reprocessed HY-2 A Altimeter Data

HY-2 A (Haiyang-2 A) satellite was launched on August 16, 2011 and radar altimeter is one of its main payloads. We reprocessed two years of HY-2 A altimeter sensor geophysical dataset records (SGDR) data. This paper presents the main results in terms of reprocessed HY-2 A altimeter data quality: verification of data availability and validity, monitoring several relevant altimeter parameters, and assessment of the HY-2 A altimeter system performances. A cross-calibration analysis of reprocessed HY-2 A altimeter data with Jason-2 was conducted. The reprocessed HY-2 A altimeter data show good quality and have a low level of noise with respect to Jason-2. The same geophysical correction methods were used to calculate the sea surface height (SSH) for the two missions. The mean standard deviations of the crossover differences for HY-2 A and Jason-2 are 5.24 cm and 5.34 cm, respectively. The mean standard deviation of the crossover differences between HY-2 A and Jason-2 is 5.37 cm. These show that HY-2 A can provide SSH measurements at almost the same level of accuracy as Jason-2. The relative SSH bias between HY-2 A and Jason-2 due to the Ultra Stable Oscillator (USO) drift is obviously observed, and it can affect the calculation of mean sea level and should be further studied and corrected.     

基于NS2的TCPW性能改进算法研究

TCP Westwood(TCPW)和Vegas都是基于测量的TCP New-Reno增强算法。TCPW针对ACK流直接估算可用带宽,在慢启动和线性递增部分依然采用传统Reno的盲目递增的机制,导致发送端较为频繁的重传。对这几种算法原理进行分析阐述,并提出1种改进方法,更精确的测量估计带宽,通过网络仿真工具NS2进行验证,明显去除TCP全局同步现象,增强网络性能。     

Microbial photosynthesis in coral reef sediments (Heron Reef, Australia)

We investigated microphytobenthic photosynthesis at four stations in the coral reef sediments at Heron Reef, Australia. The microphytobenthos was dominated by diatoms, dinoflagellates and cyanobacteria, as indicated by biomarker pigment analysis. Conspicuous algae firmly attached to the sand grains (ca. 100 μm in diameter, surrounded by a hard transparent wall) were rich in peridinin, a marker pigment for dinoflagellates, but also showed a high diversity based on cyanobacterial 16S rDNA gene sequence analysis. Specimens of these algae that were buried below the photic zone exhibited an unexpected stimulation of respiration by light, resulting in an increase of local oxygen concentrations upon darkening. Net photosynthesis of the sediments varied between 1.9 and 8.5 mmol O₂ m⁻² h⁻¹ and was strongly correlated with Chl a content, which lay between 31 and 84 mg m⁻². An estimate based on our spatially limited dataset indicates that the microphytobenthic production for the entire reef is in the order of magnitude of the production estimated for corals. Photosynthesis stimulated calcification at all investigated sites (0.2–1.0 mmol Ca²⁺ m⁻² h⁻¹). The sediments of at least three stations were net calcifying. Sedimentary N₂-fixation rates (measured by acetylene reduction assays at two sites) ranged between 0.9 to 3.9 mmol N₂ m⁻² h⁻¹ and were highest in the light, indicating the importance of heterocystous cyanobacteria. In coral fingers no N₂-fixation was measurable, which stresses the importance of the sediment compartment for reef nitrogen cycling.