磷循环的非线性动力学特性及富营养化

本文在假设湖泊受单一营养盐磷限制和不考虑湖底沉积物影响的情形下,建立了一个单层箱体磷循环的非线性动力学模型,研究湖泊中颗粒磷、可溶性磷和藻类中的磷这三种磷之间的相互关系,理论上分析了磷循环系统的稳定特性,得出三种形式的磷共存是系统趋向稳定的平衡点．然后论文又从人工治理的角度,通过数值计算综合考虑外源性磷、水力冲刷、生物调控和基质浓度因素对磷循环的影响,分析不同因素的改变对系统和湖泊水质的影响,进而对这一类的富营养化现象防治提供可行性的工程上的实际建议．     

饮马河流域典型湿地植物净化河流水环境效果研究

采取单种及混种方式,通过小型湿地模拟实验,研究松花江支流饮马河流域河流湿地中常见的芦苇、香蒲、槽秆荸荠、藨草、慈姑、花蔺、菱角、紫背浮萍和金鱼藻9种湿地植物及其组合对河流水体中化学需氧量(COD_(cr))、氮、磷等的净化效果。结果表明:所选湿地植物,在模拟环境条件下均能有效提升取自河流水体的水质;不同的湿地植物对污水中各污染物净化具有明显的差异,花蔺对总磷(TP)、COD_(cr)和氨氮(NH_3-N)净化效果最好,去除率依次为99.65%、68.22%和99.54%;香蒲、菱角、金鱼藻混合组对总氮(TN)的净化效果最好,去除率是66.19%;槽杆荸荠、芦苇和金鱼藻对亚硝酸盐氮(NO_2-N)的净化效果最好,去除率是83.64%。两种植物混种后对某一种污染物指标的处理效果弱于分别独种时的处理效果,但对多种污染物指标的综合处理效果一般要好于独种时的处理效果。     

中国主要河流控制站氮、磷含量变化规律初探

根据黄河洛口站,长江武汉站和珠江高要站１９８０到１９８９年的水文,水化学资料,分别计算中国３条主要河流下游控制站８０年代营养元素氮,磷平均含量,比较氮,磷含量的季节变化规律,并探讨影响它们含量变化的主要因素。     

长江口海域表层沉积物中磷的形态分布及环境意义

用分级浸取的方法对2009年2月采自长江口海域27个表层沉积物样品中P的形态和相关环境特征进行了研究。结果表明,物质来源和沉积物粒度是各形态P的含量与分布的主要控制因素。Ex-P（可交换态磷）,Fe-P（铁结合态磷）,Al-P（铝结合态磷）,Lea-OP（可浸取有机磷）和CFA-P（自生钙磷）5种形态的沉积磷在适当条件...     

不同植被类型对土壤全氮随降雨径流流失的控制研究--以抚仙湖流域磷矿开采区为例

地表径流挟带土壤氮进入水体是造成水体面源污染的主要途径之一。本研究依区域年降雨量的差异，将抚仙湖磷矿开采区年降雨量分别为1200-1300mm和1000-1100min的区域划分为东大河流域磷矿区和帽天山磷矿区两个研究单元，通过设置野外径流小区，在自然降雨状态下对磷矿开采废弃地与矿区现有主要植被类型土壤营养元全氮随径流流失量进行比较研究。研究结果表明：降雨强度是矿山废弃地产流的关键因子，在大、暴雨状态下矿山废弃地土壤TN流失量远大于各植被类型，对抚仙湖水质产生不利的影响。各植被类型土壤TN随径流流失量主要取决于地表径流量，径流中TN含量对其影响不大，流失总量次序与径流总量次序相一致，表现为：灌草丛〉云南松灌丛〉云南松混交林〉华山松林〉竹林〉桉树林，除灌草丛外各植被类型均能对土壤TN流失起到较强的截留作用。     

Sources and sinks of nutrients in a New Zealand hill pasture catchment II. Phosphorus

The management of the riparian zone has been suggested as a technique for controlling the amounts of phosphorus (P) entering watercourses draining pasture catchments. A study was therefore made of P entering a stream from various sources (rainfall, surface and subsurface derived runoff, direct fallout from aerial topdressing), with the object of providing a rational basis for the design of effective riparian management schemes. P entrained in surface runoff could account for virtually all of the P entering the stream during storms. Approximately 20 per cent of the annual P export from the catchment could be accounted for by direct aerial input of P to the stream during autumn fertilizer topdressing. More than 85 per cent of the P was exported from the catchment as particulate P. Stream sediment had higher P sorption capacities, and were enriched with P relative to the soils from which they were derived. There was a pronounced seasonal variation in sediment enrichment which could be predicted (r² = 0.92) by the logarithm of the rainfall since fertilizer topdressing (LNFERT) and flood intensity. The amount of P lost in streamflow during any flood event was predicted (r² = 0.94) by peak flow, seven day antecedent peak flow and LNFERT. Approximately 40 per cent of the 1.3 kg P ha^?1 exported during 1981 occurred in four storms with recurrence intervals of more than three months. From a P budget compiled from nine events it was hypothesized that the stream acted as a net sink for P at baseflow and low-medium intensity floods but was a source of P at higher flood intensities. It was concluded that P losses from hill pasture catchments could be reduced by avoidance of direct application of P fertilizer to the stream channel, and by fencing out stock from seasonally saturated areas during periods of saturation. The ultimate success of the latter technique would depend on whether buffer vegetation could retain accumulated P during extreme storm events.     

Phosphorus distribution in sinking oceanic particulate matter

Despite the recognition of the importance of phosphorus (P) in regulating marine productivity in some modern oceanic systems and over long timescales, the nature of particulate P within the ocean is not well understood. We analyzed P concentration in particulate matter from sediment traps and selected core tops from a wide range of oceanic regimes: open ocean environments (Equatorial Pacific, North Central Pacific), polar environments (Ross Sea, Palmer Deep), and coastal environments (Northern California Coast, Monterey Bay, Point Conception). These sites represent a range of productivity levels, temporal (seasonal to annual) distributions, and trap depths (200–4400 m). P associations were identified using an operationally defined sequential extraction procedure. We found that P in the sediment traps is typically composed of reactive P components including acid-insoluble organic P ( 40%), authigenic P ( 25%), and oxide associated and/or labile P ( 21%), with lesser proportions of non-reactive detrital P depending on location ( 13%). The concentrations and fluxes of all particulate P components except detrital P decrease or remain constant with depth between the shallowest and the deepest sediment traps, indicating some regeneration of reactive P components. Transformation from more labile forms of P to authigenic P is evident between the deepest traps and core top sediments. Although for most sites the magnitudes of reactive P fluxes are seasonally variable and productivity dependent, the fractional associations of reactive P are independent of season. We conclude that P is transported from the upper water column to the sediments in various forms previously considered unimportant. Thus, acid-insoluble organic P measurements (typically reported as particulate organic P) likely underestimate biologically related particulate P, because they do not include the labile, oxide-associated, or authigenic P fractions that often are or recently were biologically related. Organic C to reactive P ratios are typically higher than Redfield Ratio and are relatively constant with depth below 300 m suggesting that preferential regeneration of P relative to C occurs predominantly at shallow depths in the water column, but not deeper in the water column (> 300 m). The view of P cycling in the oceans should be revised (1) to include P fractions other than acid-soluble organic P as important carriers of reactive P in rapidly sinking particles, (2) to include the efficient transformation of labile forms of P to authigenic P in the water column as well as in sediments, and (3) to consider the occurrence of preferential P regeneration at very shallow depths.     

Dynamics of phosphorus exchange between sediment and water in a gravel-bed river

ABSTRACT

Phosphorus (P) stores in gravel-bed rivers are released for uptake by periphyton when pH levels exceed 8.5. The Tukituki River has low alkalinity water and frequently experiences periphyton blooms, and daytime pH?>?9 during summer low-flows. We measured dissolved reactive P (DRP) and EPC₀, the water concentration of DRP at which no net release or sorption from the river bed occurs, in sediment samples from the Tukituki River subject to controlled pH levels before (2014) and after (2017) changes to two wastewater discharges that reduced P release to the river by 95%. DRP released from 2014 sediments at pH 8.5–10 were 30?±?10?mg/m³ above background (pH 8) whereas those released from 2017 sediments were 5?±?3?mg/m³ above background. EPC₀ levels in 2014 and 2017 were 11?±?6 and 7?±?2?mg/m³, respectively. Field estimates of released DRP calculated from continuous pH and the Redfield equation suggested that most of the readily available DRP released from sediments at elevated pH is derived from material attached to recently deposited sediment. Subsequently, a reduction in wastewater inputs or agricultural runoff should reduce sediment DRP stores, and hence sediment fluxes, within a few years and mitigate periphyton blooms in addition to directly lowering water column concentrations.     

Study of the N, P and Si fluxes between fish farm sediment and seawater. Results of simulation experiments employing a benthic chamber under various redox conditions

The rapidly expanding industry of marine cage fish farming of sea bream (Sparus aurata) and sea bass (Dicentrarchus labrax) in the Mediterranean Sea over the last decade has often had damaging effects on the benthic aquatic environment near the fish farm installations. It has been observed that the food-remains, together with the pellets and metabolic products from fish, frequently form a “nepheloid” sediment layer covering large areas of the seabed. Under these conditions anoxia and/or hypoxia develop and affect benthic communities while the quality of the marine environment deteriorates for long periods, extending even beyond the life span of the fish farm itself. In most cases the affected areas act initially as sediment traps and in a second phase as secondary sources of organic carbon, nutrients and other substances.The aim of this paper is to explore the behaviour of such an affected area under different redox regimes by measuring the fluxes of ammonium, nitrite, nitrate, TDN, phosphate, TDP and silicate between the surface sediment and the overlying waters. To achieve this goal we constructed a prototype benthic chamber capable of sampling considerable quantities of affected undisturbed sediment along with its overlying water. The chamber was transported to the laboratory where simulation experiments reproducing the conditions occurring in nature, including the extreme ones, were carried out and studied carefully. The chamber allows the full and fine control of the dissolved oxygen concentration – and thus of the redox potential – as well as water temperature while subsamples of both water and sediment could be obtained and analysed for a series of chemical substances. The controlled laboratory chamber experiments reproduced four successional phases: 1) deoxygenation, 2) hypoxia, 3) reoxygenation and 4) anoxia.The results showed that even minor changes in the redox conditions at a relatively narrow zone near the water sediment interface have significant impacts on the concentrations of dissolved nitrogen, phosphorus and silicate compounds.With decreasing oxygen supply (phases 1, 2 and 4), the concentrations of ammonium, nitrite, TDN, phosphate, TDP and silicate rapidly increase, those of nitrate decrease. DON and DOP exhibit remarkable fluctuations.During reoxygenation (phase 3) the concentrations of ammonium stabilise, the nitrate concentration decreases while nitrite shows an increasing trend. Decreases in phosphate and silicate concentrations were also observed paralleled by TDP stabilization and DOP increasing trend. TDN shows a relatively small increase while the DON concentration fluctuates significantly.