Stable isotopes of pedogenic carbonates from the Somma–Vesuvius area,southern Italy,over the past 18 kyr: palaeoclimatic implications

Stable isotopes were measured in the carbonate and organic matter of palaeosols in the Somma–Vesuvius area, southern Italy in order to test whether they are suitable proxy records for climatic and ecological changes in this area during the past 18000 yr. The ages of the soils span from ca. 18 to ca. 3 kyr BP. Surprisingly, the Last Glacial to Holocene climate transition was not accompanied by significant change in δ¹⁸O of pedogenic carbonate. This could be explained by changes in evaporation rate and in isotope fractionation between water and precipitated carbonate with temperature, which counterbalanced the expected change in isotope composition of meteoric water. Because of the rise in temperature and humidity and the progressive increase in tree cover during the Holocene, the Holocene soil carbonates closely reflect the isotopic composition of meteoric water. A cooling of about 2°C after the Avellino eruption (3.8 ka) accounts for a sudden decrease of about 1‰ in δ¹⁸O of pedogenic carbonate recorded after this eruption. The δ¹³C values of organic matter and pedogenic carbonate covary, indicating an effective isotope equilibrium between the organic matter, as the source of CO₂, and the pedogenic carbonate. Carbon isotopes suggest prevailing C₃ vegetation and negligible mixing with volcanogenic or atmospheric CO₂. Copyright © 2000 John Wiley & Sons, Ltd.     

长江中下游中生代岩浆岩及铜铁成矿带的深部构造背景

地球物理和中、新生代幔源岩浆岩同位素地球化学研究表明华北和华南陆块的深部岩石圈地缝合线较地表地缝合线南移。在郯庐断裂带以东南移至南京一镇江一线，并从南京往西呈南西走向延伸至桐城一带；在郯庐断裂带以西的大剐山区，深部地缝合线至少南移至岳西以南。这一贴近长江中下游的深部地缝合线，有可能在郯庐断裂系早白垩世发生大规模左行走滑作用下而导致引张，从而诱发了地幔上隆和大规模岩浆事件及铜铁成矿作用。     

鲁西地区中生代碳酸岩类的微量元素和锶、钕同位素组成特征

对鲁西地区早白垩纪的碳酸岩岩体的稀土、微量元素和同位素组成的研究表明 ,鲁西碳酸岩不同于任何沉积成因的灰岩和变质成因的大理岩 ,而与世界典型的幔源碳酸岩具有相似的稀土元素组成 ,说明其为幔源成因 ,碳酸岩极度富集轻稀土元素。鲁西碳酸岩的锶、钕同位素组成表明其地幔源区为具有EMI和EMII端元混合特征的富集地幔。     

中国大气降水的氧同位素温标

中国北部中 高纬度地区大气降水δ1 8O与地面气温的相关性与中国其他地区不同 ,前者是正相关 ,后者是负相关。海口与香港的年均δ1 8O 温度系数为 - 0 .42‰ /℃ ,二者都属于热带季风型气候。高纬度地区年均δ1 8O 温度系数与月均系数相近 ,约为 0 .4‰ ℃ ,例如 ,兰州 0 .35‰ ℃ ,张掖 0 .46‰ ℃ ,乌鲁木齐 0 .42‰ ℃。中纬度地区石家庄月均δ1 8O 温度系数 (0 .11‰ ℃ )小于年均δ1 8O 温度系数 (0 .34‰ ℃ )。华北平原古大气降水δ1 8O 古地面气温系数为 0 .36‰ ℃ ,与石家庄现代大气降水年均δ1 8O 现代年均地面气温系数相近。因此 ,中国中高纬度地区大气降水的年均δ1 8O 温度系数 ,可用作氧同位素温标再造当地古气温。     

青藏高原现代降水中dδ^18O／dT的变化

不同时间尺度ｄδ＾１８Ｏ／ｄＴ的天气气候意义是不同的，其数值大小也是不一样的。本根据对青藏高原沱沱河、德令哈、西宁三站大气降水中δ＾１８Ｏ与温度关系的分析，并与具有长序列资料的地区进行比较。初步给出了青藏高原不同时间尺度ｄδ＾１８Ｏ／ｄＴ之间的差异。     

离子质谱计测定地质样品中镁同位素组成方法学研究

应用信通公司研制的离子质谱计（ＳＴ－ＩＭＳ），建立了地质样品镁同位素分析的实验流程和误差分析方法，为进一步分析微量地质样品中镁同位素组成和分布奠定了基础。     

Implications of εNd—La／Nb,Ba／Nb,Nb／Th Diagrams to Mantle Heterogeneity—Classification of Island—arc Basalts and Decomposition of EMII Component

A group of εNd/Nb,Ba/Nb,Nb/Th diagrams are used to study mantle heterogeneity.Island-arc basalts(IAB) are distributed in a triangle of these diagrams. Three end-member components (the MORB-type depleted mantle, the fluid released from subducted oceanic crust and the sediments from the continental crust) of the source of IAB may be displayed in these diagrams. Two types of IAB are identified .They are of the two-component type (with little continental sediments), such as the basalts from Aletians and New Britain ,and the three-compeonent type, such as those from Sunda, Lesser Antilles and Andes. In addition ,the EMII type mantle-derived rocks may also be divided into two groups. One is exemplified by continental flood basalts and some peridotite xenoliths, similar to IAB, with high La/Nb and Ba/Nb and low Nb/Th ratios, The other includes the Samoa-type oceanic island basalts, with low La/Nb and Ba/Nb and high Nb/Th ratios. The corresponding two sub-components of EMII are EMIIM, which is related to the metasomatism of lithosphere mantle by fluids released from the subducted oceanic crust, and EMIISR, related to the intervention of recycling continental sediments into the convective mantle.     

我国最大古岩溶型铀矿床成因的同位素地球化学研究

据对某大型古岩溶型铀矿床中铀－铅同位素体系及硫、碳、氧、氢同位素组成的研究结果，表明该矿床成矿物质源自矿区众多地层，成矿流体的变质水和古岩溶水（古大气降水）的混合水；成矿经历了古岩溶铀淋积富集，燕山早、晚期构造运动促使两次含铀热水溶液改造、叠加成矿（１３５～１１９。６５Ｍａ），成矿作用与古岩溶和区域地质构造演化密切相关，属古岩溶型热造铀矿床。     

云南镇康芦子园铅-锌矿的成矿年龄

芦子园铅锌矿为保山-镇康地块中一个重要的热液矿床。矿床赋存于早古生代碳酸盐岩中,经人工分选出矿石中的闪锌矿、黄铜矿、与矿石硫化物密切共生的热液石英及石英钾长石脉中的钾长石等共10件单矿物样品,采用Rb-Sr同位素定年分析,获得等时线年龄141.9±2.6 Ma,初始锶同位素组成为87Sr/86Sr(t=141.9 Ma)=0.714 497。揭示成矿作用时代与中特提斯怒江洋闭合时期大致相当,矿石初始锶同位素组成也与保山-镇康地块中燕山期花岗岩初始Sr同位素组成基本一致,指示矿床的成因可能与燕山期岩浆活动有关,是中特提斯怒江洋闭合过程中碰撞造山作用的响应。     

江南隆起带中段新元古代花岗岩锆石U-Pb年代学和Hf同位素组成研究

对江南隆起带中段湘东西园坑岩体和赣西九岭岩体的LA-ICPMS锆石U-Pb年代学测定和LA-MC-ICPMS锆石Hf同位素原位分析测试表明:西园坑岩体形成于(804±3)Ma,赣西九岭岩体的年龄为(813±4)Ma和(823±2)Ma,均为新元古代花岗岩.上述三个样品的εHf(t)的加权平均值分别为0.68±0.71,...