高纯无硒电解金属锰混合添加剂的研制

采用新型无硒混合添加剂制取高纯无硒电解金属锰，可以使电解金属锰中硒含量控制在O．001％以内，锰含量达到“三九”锰标准，具有显著的经济价值。     

合肥盆地南部侏罗系砂岩碎屑组分及其物源构造属性

根据侏罗系砂岩碎屑的岩矿组成及主元素地球化学分析, 认为合肥盆地南部侏罗系物源主要来自大别造山带, 具有明显的陆壳 岛弧混杂属性。主要物源类型经历了下—中侏罗统的 “再旋回造山带”类型向上侏罗统 “弧造山带”类型的复杂演变, 期间中侏罗世特别是相当于凤凰台组时期由于强烈的剥离作用, 大别造山带切割的 （ｄｉｓｓｅｃｔｅｄ） 岩浆弧物源已有所暴露。据古地理恢复, 推断侏罗纪合肥盆地南部沉积演化曾受控于挤压动力体制, 极可能与扬子板块进一步陆内俯冲作用有关     

合肥盆地基底构造属性

根据合肥盆地及周边地表地质、地震剖面、同位素测年及MT等新资料的综合研究,提出中-新生代合肥盆地的基底是一个不同构造类型基底的叠合与复合.上古生界以前的基底以六安断裂为界,其北为华北板块陆壳型-过渡壳型结晶基底及其上的华北克拉通-被动大陆边缘盆地沉积的上元古-下古生界基底;其南为大别型结晶基底及其上的北淮阳弧后盆地沉积的上元古-下古生界变质基底,而上古生界基底属于弧后前陆盆地型沉积.六安断裂是合肥盆地部位北大别弧、北淮阳晚元古-早古生代弧后盆地在早古生代晚期-晚古生代早期与华北板块的弧-陆碰撞缝合线.     

Hunter–Bowen deformation in South Percy Island,northeastern Australia

South Percy Island is located approximately 50 km off the central Queensland coast and comprises a disrupted ophiolite mass alongside a diverse array of metamorphosed felsic and mafic rocks that record several episodes of magmatism, volcanism and deformation from the Permian to Early Cretaceous. This paper aims to constrain the age, affinity and deformation history of these units, as well as to establish the tectonic significance of the terrane. The trace-element compositions of mafic and felsic meta-igneous rocks record a change from MORB-like prior to ca 277 Ma to subduction-related by ca 258 Ma. Overprinting relationships between intrusive phases and deformation features reveal a relative chronology for the tectonothermal evolution of the area, while U–Pb and ⁴⁰Ar/³⁹Ar geochronology provides absolute age constraints. Deformation is localised around a NNE-striking tectonic contact that separates serpentinised ultramafic rocks from metamorphosed pillow lavas. Early formed ductile fabrics associated with the main episode of deformation (D₁) preserve bulk flattening strains at greenschist-facies conditions. Emplacement and post-kinematic cooling ages of a pre-D₁ quartz-monzonite dyke constrain the age of D₁/M₁ deformation and metamorphism to the period between ca 258 and ca 248 Ma. Minor brittle deformation (D₂) occurred at ca 230 Ma, based on U–Pb dating of a syn-D₂ diorite dyke (ca 231 ± 10 Ma) and several ca 230 Ma ⁴⁰Ar/³⁹Ar cooling ages. The deformation, metamorphism, and supra-subduction zone magmatism preserved on South Percy Island is correlated with the nearby Marlborough Terrane and more broadly with the second pulse of the Hunter–Bowen Orogeny, which affected much of the central and northern parts of eastern Australia in the late Permian and Early Triassic. Our results support previous suggestions that the second pulse of the Hunter–Bowen Orogeny involved coeval thrust systems in both the inboard and outboard parts of the orogen.     

Petrology,Geochemistry, and Fluid Inclusion Microthermometry of Sphalerite from the Laloki and Federal Flag Strata‐Bound Massive Sulfide Deposits,Papua New Guinea: Implications for Gold Mineralization

The Laloki and Federal Flag deposits are two of the many (over 45) polymetallic massive sulfide deposits that occur in the Astrolabe Mineral Field, Papua New Guinea. New data of the mineralogical compositions, mineral textures, and fluid inclusion studies on sphalerite from Laloki and Federal Flag deposits were investigated to clarify physiochemical conditions of the mineralization at both deposits. The two deposits are located about 2 km apart and they are stratigraphically hosted by siliceous to carbonaceous claystone and rare gray chert of Paleocene–Eocene age. Massive sulfide ore and host rock samples were collected from each deposit for mineralogical, geochemical, and fluid inclusion studies. Mineralization at the Laloki deposit consists of early‐stage massive sulfide mineralization (sphalerite‐barite, chalcopyrite, and pyrite–marcasite) and late‐stage brecciation and remobilization of early‐stage massive sulfides that was accompanied by late‐stage sphalerite mineralization. Occurrence of native gold blebs in early‐stage massive pyrite–marcasite‐chalcopyrite ore with the association of pyrrhotite‐hematite and abundant planktonic foraminifera remnants was due to reduction of hydrothermal fluids by the reaction with organic‐rich sediments and seawater mixing. Precipitation of fine‐grained gold blebs in late‐stage Fe‐rich sphalerite resulted from low temperature and higher salinity ore fluids in sulfur reducing conditions. In contrast, the massive sulfide ores from the Federal Flag deposit contain Fe‐rich sphalerite and subordinate sulfarsenides. Native gold blebs occur as inclusions in Fe‐rich sphalerite, along sphalerite grain boundaries, and in the siliceous‐hematitic matrix. Such occurrences of native gold suggest that gold was initially precipitated from high‐temperature, moderate to highly reduced, low‐sulfur ore fluids. Concentrations of Au and Ag from both Laloki and Federal Flag deposits were within the range (<10 ppm Au and <100 ppm Ag) of massive sulfides at a mid‐ocean ridge setting rather than typical arc‐type massive sulfides. The complex relationship between FeS contents in sphalerite and gold grades of both deposits is probably due to the initial deposition of gold on the seafloor that may have been controlled by factors such as Au complexes, pH, and fO₂ in combination with temperature and sulfur fugacity.     

Multi-decadal coastal change in New Zealand: Evidence, mechanisms and implications

Abstract:   Coastal research and monitoring on New Zealand beaches have typically examined seasonal and event-driven (storms) changes in the coast. However, historical records are now of sufficient length to indicate that change occurs at longer timescales. This paper presents examples of multi-decadal change at three case-study locations around New Zealand. Results show that morphological adjustment of the coast occurs at multi-decadal scales and is much larger than short-term dynamics. Physical mechanisms driving changes are ill defined but may be associated with El Niños and La Niña episodes which modulate waves and sea level, as well as changes in sediment supply.     

Chloritoid-bearing rocks associated with blueschists and eclogites, northern New Caledonia

Abstract Chloritoid-bearing metasedimentary rocks occur in close proximity to blueschists and eclogites in the Tertiary high-pressure metamorphic belt of northern New Caledonia. The typical assemblage of chloritoid-bearing rocks in the epidote zone is quartzchlorite-muscovite-garnet-chloritoid. In the omphacite zone, epidote is an additional member of the chloritoid-bearing assemblage. Paragonite is rare, plagioclase was not detected, and rutile and ilmenite are the Fe-Ti oxide phases. Chloritoid-glaucophane is not a common assemblage. Chloritoid-bearing rocks have relatively low (Ca+K+Na)/Al ratios and the chloritoids are relatively Mg-rich with Mg/ (Mg+Fe) up to about 0.4. A comparison of the mineral assemblages and mineral chemistry with experimental and computed phase equilibria suggest an upper temperature limit near 560° C in the omphacite zone and a minimum temperature limit near 450° C at 10 kbar. An empirical garnet-chlorite Fe-Mg exchange thermometer does not yield consistent results for the higher-grade rocks, suggesting T s ranging from 390 to 535° C in the omphacite zone and 420–465° C in the epidote zone. The distribution coefficient K _D = (Fe/Mg)_ctd/(Fe/Mg)_chl for chloritoid and chlorite ranges from 3.9 to 6.4, values which are lower than those (=10) from lower greenschist facies rocks, but are near those of upper greenschist facies and albite-epidote amphibolite facies.     

郯庐断裂带张八岭隆起段走滑运动与合肥盆地的沉积响应

安徽北部的郯庐断裂带位于东侧的张八岭隆起与西侧的合肥盆地之间。断裂带内走滑糜棱岩、超糜棱岩及伴生岩浆岩的同位素测年,表明其走滑时间为早白垩世。一系列构造、沉积学的研究反映,郯庐断裂带在早白垩世的走滑运动,使合肥盆地东侧出现了北北东向延伸的张八岭走滑隆起,成为合肥盆地的沉积物源区。盆地东部相应出现了由下白垩统朱巷组充填、北北东向的大桥-肥东凹陷。该凹陷属于走滑挠曲盆地,其出现于张八岭走滑隆起西侧的走滑挠曲拗陷之中。     

某城市规划新区表层土壤重金属潜在生态风险评价

为评价某城市规划新区表层土壤质量,利用网格法采集表层土样1000件,分析8种重金属(Cd、 Cu、 Zn、 Ni、Cr、Pb、Hg、As)元素的含量,并分别运用污染负荷指数(PLI)和潜在生态危害指数(RI)评价研究区表层土壤中重金属的污染程度和危害等级。利用克里金插值法研究土壤PLI和RI的空间分布特征。结果表明:研究区内表层土壤重金属平均值均大于中国土壤背景值,Cd、Cu、Ni较为富集。研究区Cd和Cu元素为重度污染,Cd的生态危害性较强,87.90%的土样为重金属轻微污染,60.83%的土样为中等生态危害。污染较为严重和风险较强的地区主要位于研究区西南部河流两岸,Cu和Cd可能受到了人类活动的影响而偏高。     

合肥市滨湖新区全新世沉积物粒度特征及其古环境意义

对合肥市滨湖新区大量第四纪钻孔作了地层描述、粒度分析,对代表性钻孔ZK1303采集的样品平均粒径、分选系数、偏度及峰度进行了统计分析,并绘制出样品的频率曲线和概率累积曲线,以及据地层描述绘制出岩性基本层序图,据此探讨了该沉积区全新世以来的沉积环境。结果表明,此钻孔全新世地层自下而上至少存在3个大的沉积旋回,各沉积旋回底层基本以含砾砂土为主,向上变为细砂、粉砂、砂质粉土、粉质粘土、粘土;3个大的沉积旋回中又至少发育了11个次级正向粒序沉积旋回。综合各统计参数在垂向上的分布特征、频率曲线、概率累积曲线特征和研究区地理位置特征,初步判定5、1072．21号样品对应的地层为河床滞留沉积;初步判定该区全新世以来至少经历11次湖泊进退更替,其中有3次巨大的湖退;对应于每个沉积旋回,沉积环境有各沉积旋回底层河流相向上过渡到河湖相沉积。