江南造山带黄金洞金矿床成矿机制:矿物形成环境与金成矿物理化学条件制约

黄金洞超大型金矿床位于江南造山带中段,赋存于新元古界浅变质岩系中,受控于NNE-NE向长平断裂带,金资源储量达100吨。该矿床可由南至北分为金福、金塘、杨山庄和曲溪矿段,主要矿化类型有石英-硫化物脉型、构造角砾岩型和黄铁毒砂绢英岩型。金属矿物主要发育有自然金、毒砂、黄铁矿、黄铜矿、闪锌矿、方铅矿、磁黄铁矿等;非金属矿物有石英、绢云母、方解石和菱铁矿等,其中金主要以自然金与不可见金形式存在。根据野外与镜下观察,金成矿作用分为Ⅰ石英-金-毒砂-黄铁矿、Ⅱ石英-金-多金属硫化物-白钨矿和Ⅲ石英-辉锑矿-绿泥石3个阶段,前二者为主要成矿阶段。曲溪矿段Ⅱ阶段毒砂相对不发育、而磁黄铁矿和自然金显著发育,绿泥石主要发育于Ⅲ阶段中,与辉锑矿及闪锌矿共生。根据不同矿段各阶段毒砂与Ⅲ阶段绿泥石成分,计算其温度、lgf(S_2)与lgf(O_2),可见Ⅰ阶段成矿温度与硫逸度高于Ⅱ阶段:杨山庄矿段两阶段成矿温度分别为300～378℃、260～300℃,lgf(S_2)分别为-11～-7.2、-11.9～-10.1;金塘两阶段成矿温度为240～311℃、245～298℃;金福Ⅱ阶段成矿温度上限为297℃;曲溪矿段成矿温度为268～368℃,Ⅱ阶段毒砂lgf(S_2)与Ⅲ阶段绿泥石lgf(O_2)分别为-13.2～-8.7、-50.9～-40.1。根据不同阶段矿物之间的相互关系及成矿温度与硫逸度演化特征,推断Ⅰ、Ⅱ成矿阶段伴随强烈的硫化作用,金以类质同象方式进入毒砂和黄铁矿中,形成不可见金;其中Ⅱ阶段由于成矿流体压力骤降,含金流体发生相分离作用,H2S等气体大量逃逸,导致成矿流体中硫含量骤降,加以硫化作用持续消耗流体中的硫,促进了含金络合物分解与自然金的沉淀。     

南太行山闪长岩的SHRIMP锆石U-Pb年龄及岩石成因研究

南太行山符山和东冶角闪闪长岩岩体的精细SHRIMP锆石U-Pb定年和元素-同位素地球化学研究表明:符山角闪闪长岩体形成于126.7±1.1Ma,东冶角闪闪长岩体形成于125.9±0.9Ma,与区内基性侵入岩和北太行地区侵入杂岩具有相似的形成年龄,表明晚中生代(±130Ma左右)太行山地区经历了与华北陆块同期的重要构造岩浆事件。区内闪长质岩石SiO_2=54.84％～65.75％,MgO=1.31％～3.89％,K_2O Na_2O=6.53％～11.40％,mg值=0.36～0.58,(La/Yb)_(cn)=9.86～22.77,(Gd/Yb)_(cn)=1.51～2.00;Eu/Eu=1.00～1.23,以富集LREE、LILE元素和明显亏损Nb-Ta、Zr-Hf-Ti等高场强元素为特征。~(87)Sr/~(86)Sr(t)=0.705363～0.706165,ε_(Nd)(t)=-13.8～-16.8,源自于EMI型富集岩石圈地幔,可解释为新生地幔底侵物质熔融后经过结晶分异作用的产物。与华北克拉通内部其他地区一样,早白垩世南太行山地区处于软流圈上涌的岩石圈伸展构造背景。     

南大洋深海嗜冷菌2-5-10-1及其低温脂肪酶的研究

从南大洋普里兹湾的水样中筛选到一株产低温脂肪酶的深海嗜冷菌2-5-10-1,对其生长及产酶情况和酶性质做了初步研究.该菌株的最适生长温度为5℃,此时分泌的胞外脂肪酶最多;添加Tween80,橄榄油可显著促进脂肪酶的产生.该脂肪酶的最适作用温度为35℃,在0～20℃均保持较高的酶活性,在0℃可保持37%的相对酶活性;酶的最适作用的pH值为7.5,在pH6～9的范围内均存在较高酶活性;对热较敏感,在60℃保温15min可丧失50%以上的酶活性.该脂肪酶的催化作用不需要金属离子的参与,Cu2+和Zn2+对酶活有着强烈的抑制作用.     

Nitrogen forms and decomposition of organic carbon in the southern Bohai Sea core sediments

Study on form characteristics of nitrogen in marine sediments is the primary method to research its biogeochemical cycling and nitrogen form characteristics in core sediments can reflect the process and results of early diagenesis in a certain degree. In this paper, Sequential extraction process in natural grain size was used for studying the existent forms of nitrogen in five core sediments of the southern Bohai Sea for the first time. Nitrogen was divided into two parts -transferable and fixed based on whether it could be extracted by the reagent. Distributions and early diagenesis of transferable nitrogen forms in the southern Bohai Sea were researched integratedly. Results indicate that IEF - N and OSF-N are predominant forms in transferable part in the studied core sediments. Contents of different nitrogen forms vary differently with depth, and have different diagenesis process. Decomposition constant of organic nitrogen (ON) and OC are about 15.51 × 10~(-3)a~(-1)and 4.79× 10~(-3)a~(-1) respective     

形变地球对不同驱动力的响应

地球形变位移场和重力场的时空变化无论在基础理论研究,还是在地理空间信息建设中都具有重要的意义.地球在各种力学机制的作用下产生了形变,形变又导致地球引力位的变化,即形变附加位或Euler引力位增量.基于矢量球函数的基本理论,讨论了引潮力、负载力和地表应力对地球形变和引力位增量的影响,给出了均匀不可压缩地球模型的Euler引力位增量的具体表达式和Love数的理论关系.可为地球形变的理论研究提供参考和依据.     

Neotectonic deformation in the transition zone between the Dead Sea Transform and the East Anatolian Fault Zone, Southern Turkey: a palaeomagnetic study of the Karasu Rift Volcanism

In southern Turkey ongoing differential impingement of Arabia into the weak Anatolian collisional collage resulting from subduction of the Neotethyan Ocean has produced one of the most complex crustal interactions along the Alpine–Himalayan Orogen. Several major transforms with disputed motions, including the northward extension of the Dead Sea Fault Zone (DSFZ), meet in this region. To evaluate neotectonic motion on the Amanos and East Hatay fault zones considered to be northward extensions of the DSFZ, the palaeomagnetism of volcanic fields in the Karasu Rift between these faults has been studied. Remanence carriers are low-Ti magnetites and all except 5 of 51 basalt lavas have normal polarity. Morphological, polarity and K–Ar evidence show that rift formation occurred largely during the Brunhes chron with volcanism concentrated at 0.66–0.35 Ma and a subsidiary episode at 0.25–0.05. Forty-four units of normal polarity yield a mean of D/I=8.8°/54.7° with inclination identical to the present-day field and declination rotated clockwise by 8.8±4.0°. Within the 15-km-wide Hassa sector of the Karasu Rift, the volcanic activity is concentrated between the Amanos and East Hatay faults, both with left lateral motions, which have rotated blocks bounded by NW–SE cross faults in a clockwise sense as the Arabian Block has moved northwestwards. An average lava age of 0.5 Ma yields a minimum cumulative slip rate on the system bounding faults of 0.46 cm/year according with the rate deduced from the Africa–Arabia Euler vector and reduced rates of slip on the southern extension of the DSFZ during Plio-Quaternary times. Estimates deduced from offsets of dated lavas flows and morphological features on the Amanos Fault Zone [Tectonophysics 344 (2002) 207] are lower (0.09–0.18 cm/year) probably because they are limited to surface fault breaks and do not embrace the seismogenic crust.Results of this study suggest that most strike slip on the DSFZ is taken up by the Amanos–East Hatay–Afrin fault array in southern Turkey. Comparable estimates of Quaternary slip rate are identified on other faults meeting at an unstable FFF junction (DSFZ, East Anatolian Fault Zone, Karatas Fault Zone). A deceleration in slip rate across the DSFZ and its northward continuation during Plio-Quaternary times correlates with reorganization of the tectonic regime during the last 1–3 Ma including tectonic escape within Anatolia, establishment of the North and East Anatolian Fault Zones bounding the Anatolian collage in mid–late Pliocene times, a contemporaneous transition from transpression to transtension and concentration of all basaltic magmatism in this region within the last 1 Ma.     

Control of syntectonic erosion and sedimentation on kinematic evolution of a multidecollement fold and thrust zone: Analogue modeling of folding in the southern subandean of Bolivia

Several analogue modeling studies have been conducted during the past fifteen years with the aim to discuss the effects of sedimentation and erosion on Foreland Fold and Thrust Belt, among which a few have analyzed these processes at kilometric scale (Malavieille et al., 1993; Nalpas et al., 1999; Barrier et al., 2002; Pichot and Nalpas, 2009). The influence of syn-deformation sedimentation and erosion on the structural evolution of FFTB has been clearly demonstrated. Here, we propose to go further in this approach by the study of a more complex system with a double decollement level. The natural study case is the Bolivian sub-Andean thrust and fold belt, which present all the required criteria, such as the double decollement level. A set of analogue models performed under a CT-scan have been used to test the influence of several parameters on a fold and thrust belt system, among which: (i) the spatial variation of the sediment input, (ii) the spatial variation of the erosion rate, (iii) the relative distribution of sedimentation between foreland and hinterland. These experiments led to the following observations:

• 1. The upper decollement level acts as a decoupling level in case of increased sedimentation rate: it results in the verticalization of the shallower part (above the upper decollement level), while the deeper parts are not impacted.
• 2. Similarly, the increase of the erosion rate involves the uplift of the deeper part (below the upper decollement level), whereas the shallower parts are not impacted.
• 3. A high sedimentation rate in the foreland involves a fault and fold vergence reversal, followed by a back-thrusting of the shallower part.
• 4. A high sedimentation rate in the hinterland favours thrust development toward the foreland in the shallower parts.

     

华北克拉通南缘潘河~1.5Ga正长岩的厘定及其构造意义

华北克拉通是否曾是Columbia超大陆的组成部分并具有一致的裂解过程一直存在争议,而已知的中元古代非造山岩浆组合集中分布于华北克拉通北缘是引起有关裂解过程争论的重要原因。作者近来在华北克拉通南缘,河南省卢氏县潘河地区,厘定了一组中元古代走向近东西的正长岩脉群。正长岩LA-ICP-MS锆石U-Pb年龄为1469±8Ma(MSWD=1.4)。岩石类型主要为黑云母正长岩,局部有少量霞石正长岩。岩体的SiO2变化于51.3%～65.7%之间,碱含量较高,K2O+Na2O总量8.32%～13.0%,铝含量较高(Al2O3=18.7%～20.0%),为碱性过铝质岩类。岩体轻重稀土分馏较为显著(La/Yb)N=14.5～34.5,具有显著的Eu负异常(δEu=0.2～0.3),强烈富集Rb、Ba、Th等大离子亲石元素和Nb、Ta、Nd、Tb等高场强元素,而Sr、Ti、P、Eu等元素显著亏损。岩石εHf(t)=-14.79～+8.16,Hf模式年龄为2.93～1.74Ga,指示成岩物质主要来源于富集岩石圈地幔的部分熔融并有地壳物质的加入。岩体形成于板内伸展构造环境,这表明华北克拉通的南缘也同时记录了华北克拉通曾经在中元古代发生过大规模的伸展作用,其伸展过程可能与Columbia超大陆的裂解有关。     

4—5月南亚高压在中南半岛上空建立的年际变化特征及其与亚洲南部夏季风的关系

利用1979--2008年NCEP／NCAR逐日再分析资料和向外长波辐射资料讨论了4-5月南亚高压在中南半岛上空建立的年际变化特征及其与亚洲南部夏季风的关系。发现南亚高压建立偏早年其建立过程时间长,中南半岛高空反气旋环流强,建立开始前位于菲律宾群岛以东洋面上空的反气旋环流中心位置较为偏西;偏晚年南亚高压建立过程时间短,中南半岛高空反气旋环流弱,建立开始前西太平洋上空无闭合的反气旋性环流中心。南亚高压建立的早晚与中南半岛地区对流建立发展关系密切,当中南半岛地区对流建立发展较早时,南亚高压建立较早;反之,对流建立发展偏晚时,南亚高压建立偏晚。南亚高压建立早晚年,亚洲南部夏季风的爆发存在明显差异。南亚高压建立偏早年,孟加拉湾东部一中南半岛夏季风和南海夏季风爆发早;建立偏晚年,孟加拉湾东部一中南半岛夏季风和南海夏季风爆发晚,因此南亚高压在中南半岛上空建立的早晚对后期亚洲南部夏季风的爆发具有较好的指示意义。     

胶东郭家岭花岗闪长岩U--Pb年代学、地球化学特征及地质意义

郭家岭花岗闪长岩岩石地球化学特征表明其SiO2含量较高,为71.3%~73.28%,K2O=2.14%~4.29%,属于高钾钙碱性--钙碱性I型花岗岩。锆石LA--ICP--MS U--Pb年龄显示郭家岭花岗岩体成岩年龄为127.9±1.3 Ma,属早白垩世。岩石的Rb/Sr和Nb/Ta比值,以及暗色闪长质包体研究表明郭家岭花岗闪长岩为壳幔混合源,岩浆源区为具有幔源特征的新生镁铁质下地壳。结合区域地质分析认为郭家岭花岗闪长岩的形成与太平洋板块俯冲引起的大陆弧伸展作用最密切。