Water–rock interaction during the process of steam stimulation exploitation of viscous crude oil in Liaohe Shuguang Oil Field, Liaoning, China

In the process of steam stimulation exploitation of viscous crude oil, the injected water, at high temperature and under high pressure, reacts intensively with the host rock. This kind of water–rock interaction in Liaohe Shuguang Oil Field was studied on the basis of analysis of water composition changes, laboratory experiments, mineral saturation indices analysis, and mass balance calculation. Compared with the injected water, the changes of the composition of discharged water are mainly the distinct decrease of pH, Na⁺, SiO₂ and Cl⁻, as well as the increase of K⁺, Ca²⁺, Mg²⁺, SO ₄ ²⁻ and HCO ₃ ⁻ . Laboratory experiments under field conditions showed: the dissolution sequence of minerals quantitatively is quartz>potassium feldspar>albite, and the main change of clay minerals is the conversion of kaolinite to analcime. Mass balance calculation indicated during the process of steam stimulation, large quantities of analcime are precipitated with the dissolution of large amounts of quartz, kaolinite, potassium feldspar, and CO₂. These results correlated very well with the experimental results. The calculated results of Liaohe Shuguang Oil Field showed that during the steam stimulation for viscous crude oil, the amounts of minerals dissolved (precipitated) are huge. To control the clogging of pore spaces of oil reservoirs, increased study of water–rock interaction is needed.     

Hydrogeochemical evolution of groundwater in a Mediterranean coastal aquifer, Mersin-Erdemli basin (Turkey)

In this study, hydrogeologic and hydrochemical information from the Mersin-Erdemli groundwater system were integrated and used to determine the main factors and mechanisms controlling the chemistry of groundwaters in the area and anthropogenic factors presently affecting them. The PHREEQC geochemical modeling demonstrated that relatively few phases are required to derive water chemistry in the area. In a broad sense, the reactions responsible for the hydrochemical evolution in the area fall into four categories: (1) silicate weathering reactions; (2) dissolution of salts; (3) precipitation of calcite, amorphous silica and kaolinite; (4) ion exchange. As determined by multivariate statistical analysis, anthropogenic factors show seasonality in the area where most contaminated waters related to fertilizer and fungicide applications that occur during early summer season.     

Structural controls on Tertiary orogenic gold mineralization during initiation of a mountain belt, New Zealand

Two types of structurally controlled hydrothermal mineralization have occurred during folding of fissile schist in southern New Zealand: fold-related mineralization and normal fault-related mineralization. Both types have the same mineralogy and textures, and are dominated by quartz–ankerite veins and silicified breccias with ankeritic alteration. Most mineralized zones are thin (centimetre scale), although host schist is commonly impregnated with ankerite up to 20 m away. Thick (up to 5 m wide) mineralized zones are generally gold-bearing and contain pyrite and arsenopyrite with stibnite pods locally. Some of these auriferous zones have been extensively mined historically despite rugged topography and difficult access. Mineralization occurred during regional tectonic compression in the initial stages of development of the Southern Alps mountain belt at the Pacific–Australian plate boundary in the Miocene. Most of the gold-bearing deposits occur in east to south-east, striking normal faults that cut across mesoscopic folds in a belt that coincides with the southern termination of a regional-scale north trending antiform. Mineralized zones have similar structural control and relative timing to a nearby swarm of Miocene lamprophyre dykes and carbonatites. Limited stable isotopic data (C and O) and trace element geochemistry suggest that there was probably no genetic link between the igneous activity and gold mineralization. However, these two types of fluid flow have been controlled by the same tectonically created crustal plumbing system. This Miocene hydrothermal activity and gold deposition demonstrates that orogenic (mesothermal) mineralization can occur during the inception of an orogenic belt, not just in the latter stages as is commonly believed. These Miocene structures have been preserved in the orogen because the locus of uplift has moved northwards, so the early-formed gold deposits have not yet been structurally overprinted or eroded.     

Soluble organic compounds in fog and cloud droplets: what have we learned over the past few years?

We have recently set up a new procedure for characterising the water soluble organic compounds (WSOC) in fog water, for which information is still rather limited. Fog samples collected during the 1998–1999 fall–winter season in the Po Valley (Italy) were analysed following this procedure, which allows a quantitative determination of three main classes of organic compounds (neutral species, mono- and di-carboxylic acids, polycarboxylic acids), together accounting for ca. 85% of the total WSOC. This procedure also provides information on the main chemical characteristics of these three classes of compounds (functional groups, aliphatic vs. aromatic character, etc.). The enhanced chemical knowledge on fog/cloud chemical composition opens new scenarios as far as chemical and microphysical processes in clouds and fogs are concerned.     

液化场地桩-土-桥梁结构动力相互作用振动台试验研究进展

本文在全面归纳与总结液化场地桩－土－桥梁结构动力相互作用振动台试验及与之相关领域的国内外研究进展基础上，直接针对我国桥梁工程中的主要震害问题，提出在我国开展液化场地桩－土－桥梁结构动力相互作用振动台试验研究的必要性，并阐述作者对液化场地桩－土－张桥梁结构动力相互作用振动台试验中若干问题的认识。     

考虑轴向变形、双轴弯曲耦合效应的钢筋混凝土柱的弹塑性分析

在实际地震作用下，高层，特别是高宽比较大的高层结构中，由于倾覆力矩的作用、柱子、特别是外边柱所受轴力的变化将不可忽略。轴向变形与双轴弯曲的耦合作用，将是柱子塑性变形的显著特征。基于材料本构关系的“纤维模型”，能较精确地反映轴向变形，双轴弯曲三者之间的耦合作用。一组钢筋混凝土柱子双轴压弯的计算结果与试验结果的比较，证明了“纤维模型”的有效性和精确性。     

Gneiss-Water Interaction and Water Evolution During the Early Stages of Dissolution Experiments at Room Temperature

Gneiss-distilled water interaction at room temperature was investigated with batch-reactors to study water-rock reaction and geochemical evolution of the aqueous phase with time. The ion concentrations in water were controlled not only by the dissolution of primary minerals, but also by the precipitation of secondary minerals. The decreasing fraction sizes of gneiss could favor dissolution and precipitation simultaneously. Ca^2 and K^ were the major cations, and HCO3^- was the major anion in water. All the ions except Ca^2 increased in concentration with time. The Ca^2 release from the rock to the aqueous phase was initially much faster than the release of K^ , Na^2 and Mg^2 . But after about 5 - 24 hours, the Ca^2 concentrations in water decreased very slowly with time and became relatively stable. During the experiment, the water varied from the Ca-( K)-HCO3-type water to the K-Ca-HCO3-type water, and then to the K-(Ca, Na)-HCO3-type water. The water-gneiss interaction was dominated by the dissolution of Kfeldspar in the solution. The remaining secondary minerals were mainly kaolinite, illite and K (Mg) -mica.     

秦岭显生宙地幔组成及其演化

通过对秦岭造山带及扬子克拉通北缘显生宙时期 3个含地幔捕虏体的煌斑岩、钾镁煌斑岩、碱性玄武岩以及 11个不含捕虏体的辉石岩、辉长岩、玄武岩出露点的岩石地球化学对比研究 ,揭示出研究区地幔演化经历了自古生代的OIB亏损地幔到中生代的高度富集地幔再到中生代末期 -新生代的OIB MORB的亏损地幔的两次明显变更。制约这种变更的主要因素是熔融岩浆时源区发生的层圈相互作用类型。鉴于大陆岩石圈软流层体系的特征 ,有必要划分出岩石圈 /软流层相互作用带(过渡带 ) ,它是大陆岩浆作用的重要源区。     

Effect of asymmetry and irregularity of seismic waves on earthquake-induced differential settlement of buildings on natural subsoil

The effect of asymmetry and irregularity of the inputted seismic waves on the earthquake-induced differential settlement of the buildings on natural subsoil is investigated in terms of the earthquake damage phenomena, theoretical analyses, dynamic triaxial tests and shaking table tests. A conclusion can be drawn from the investigation results that, the asymmetrical and irregular character of the inputted seismic waves themselves may have a significant contribution to the differential settlement of subsoil and buildings in some cases, and this is a necessary factor to be considered in reasonable evaluation for the differential settlement and other problems relating to the soil deformation due to earthquakes.