利用尾矿废石制造微晶玻璃花岗岩的投资可行性分析

在论述尾矿废石利用现状的基础上,对利用尾矿废石制造微晶玻璃花岗岩的投资可行性进行了分析,提供了一套可用于此类决策的分析方法。     

东坪式与正长岩类有关的金矿床成矿机理的同位素地球化学制约

东坪式金矿床产于华北地台北缘金矿成矿带的冀西北金矿集中区,构造上位于华北克拉通北缘深大断裂-尚义-赤城断裂的南侧。金矿床产于泥盆纪早期(386～410Ma)水泉沟正长岩杂岩体内及接触带附近,矿体分布受脆-韧性剪切断裂构造的制约。金矿成矿作用具有多期次的特点,成矿时代为燕山期(156～203Ma)。矿石类型主要为石英脉型、石英网脉 脉旁钾硅化蚀变岩型和钾硅化蚀变岩型,具有典型的碱性岩金矿的金-碲组合,(含)金矿物主要为自然金、碲金矿和碲金银矿。流体包裹体的 H、O 及 He 同位素研究表明,成矿流体为以大气降水主的混合热液流体并可能存在深源流体的参与。矿床的 S、Pb、Sr 和 Si 同位素组成表明,金矿成矿物质主要来源于正长岩杂岩体,部分源于太古宙桑干群变质岩和燕山期花岗岩。因此,东坪式金矿是由燕山期伸展构造环境下热液流体在上涌地幔及岩浆活动的热驱动下对泥盆纪早期形成的正长岩交代改造的产物。     

海南定安富文金矿床矿石特征

从不同标高、不同品位的矿石选矿试验研究入手，论述了富文金矿矿石的物质组成、矿物成分、结构构造、金的赋存状态等。研究表明，该金矿为中型特高硫化物含金石英脉型金矿床，矿体严格受断裂裂隙控制。矿石的有用组分多样，有害杂质少，金矿物主要为自然金。主要金属矿物为黄铁矿、毒砂，同时也是主要的载金矿物；非金属矿物为石英、碳酸盐矿物。矿石多具自形、半自形、他形粒状结构，以脉状、浸染状构造为主。自然金形态为尖角粒状、角粒状、长角粒状，赋存状态以裂隙金为主，其次为粒间金，包裹金占16．9％，自然金为细粒金。矿石类型为富金银多金属硫化物含金石英脉型。     

Effect of hematite on thiosulphate leaching of gold

Hematite, as a typical iron oxide slime in sulphide ore slurries, was artificially added into the leaching systems of pure gold and a sulphide ore respectively, in an attempt to investigate the effect of iron oxide slimes on the ammoniacal thiosulphate leaching of gold. The presence of hematite significantly reduced the dissolution of gold and this detrimental effect became more pronounced with increasing hematite concentration. Hematite formed coatings on gold surfaces, which could prevent leach solution from diffusing to the gold surfaces and hence, inhibit gold dissolution. Hematite catalysed the oxidative decomposition of thiosulphate to polythionates with oxygen present. XPS studies indicated a thin layer of iron oxide coating as well as the deposition of some copper and sulphur species on gold surfaces. SEM images revealed a lesser extent of corrosion for gold after leaching in the presence of hematite. The gold extraction from the sulphide ore was reduced with the addition of hematite and this effect became more noticeable with an addition of hematite at a higher concentration. A natural guar type surfactant (Gempolym M47) reduced the detrimental effect of hematite on gold extraction likely due to the prevention of hematite coating on gold and mineral particles and the dispersion of the mineral slurry. Gempolym M47 stabilised thiosulphate by weakening the interaction between cupric ions and thiosulphate and by minimising the catalytic effect of hematite on thiosulphate decomposition.     

Biomediation of calcrete at the gold anomaly of the Barns prospect,Gawler Craton,South Australia

Anomalously high Au concentrations (2.5 to 50 ppb) in regolith carbonate accumulations, such as calcrete and calcareous sands in aeolian sand dunes overlying Au mineralisation of the Gawler Craton, South Australia, show a marked covariance of Au with K, Mg and most notably Ca. This relationship appears to be linked to the authigenic formation of smectites and carbonates within the aeolian dunes in the region. However, little is known about the processes involved in the formation of carbonates under semi-arid and arid conditions. In this study the geochemical properties of aeolian dunes along several depth profiles of 2 to 4 m are investigated in order to assess the relationship between Au mobility and calcrete formation. In the profiles a strongly systematic relationship between Au and the increasing Ca–Mg contents at depth highlights the close association between the enrichment of Au in the calcrete and the underlying hydrothermal mineralisation. Intense calcrete formation and concurrent Au enrichment also occurs in the vicinity of roots penetrating the dune. Thin section petrography and cathodoluminescence show that most of the calcrete in the regolith profiles is micritic; some sparic crystallites have also been identified. To demonstrate the presence of microbial processes that may mediate the formation of calcrete, samples from a depth profile in the dune were taken under sterile conditions. After amendment with urea and incubation of up to 24 h, up to 18 mg/l of NH₄⁺ were detected in near surface samples. At depth of 2.3 m 1 mg/l NH₄⁺ were detected compared to a control that contained below 0.05 mg/l NH₄⁺. These results suggest that the genesis of calcrete and pedogenic carbonate in the area may be partly biologically mediated via processes such as the metabolic breakdown of urea by resident microbiota which generates a pH and pCO₂ environment conducive to the precipitation of carbonate. In the process of urea breakdown organic Au complexes such as Au-amino acid complexes may become destabilised in solution and Au may be co-precipitated, resulting in the fine, non-particulate distribution of Au throughout the micritic calcrete carbonate. In conclusion, this study suggests a coupled mechanism of biologically mediated and inorganic mechanisms that lead to the formation of Au-in-calcrete anomalies.     

陕西八卦庙金矿成矿流体初步研究

流体包裹体可以探讨金属矿床的形成机理和矿化规律,含金石英脉是研究成矿流体的重要载体。八卦庙金矿包裹体比较发育,主要为液体包裹体、含 CO_2包裹体,其次是气体包裹体。成矿流体温度变化范围是146℃～467℃,成矿早阶段的温度为370℃～400℃;主成矿阶段的温度集中在190℃～280℃,平均约250℃;成矿晚阶段的温度集中在130℃～160℃。成矿流体包裹体类型主要为 Na~ -Cl~-型,少数属于 Ca~(2 )-Na~ -Cl~-(-SO_4~(2-)-F~-)型。计算得到流体体系的酸碱度为弱酸性(pH值=5.6～5.8),硫逸度分布范围是-9.551～-19.265(平均-15.430),氧逸度分布范围是-46.011～-40.303。金主要以[Au(HS)_2]~-的形式迁移,其次以[AuS]~-形式迁移,在成矿活动过程,随温度的下降和压力的降低,伴有沸腾-减压过程,是成矿溶液发生卸载的重要机制。     

金矿的地质地球化学找矿标志

地层和岩浆岩含金高丰度是金矿赋集的物质来源,断裂构造是容矿、储矿的空间。一般说来,金成矿物质越丰富,就越有利于形成大矿、富矿。以江西金矿找矿为例,阐述正确圈定金异常,合理布置探矿工程,获得找金成果新突破的实际意义。     

福建雷潭金矿地质特征及找矿预测

雷潭金矿处于华南褶皱系闽东断拗带的周宁-华安断隆带中段,成矿作用与石英闪长岩和断裂构造密切相关;矿体受NE、NW、近EW向断裂带控制;围岩蚀变以硅化、绢英岩化、黄铁矿化最为重要,它们与金矿密切相关。文章较详细地阐述了区域成矿地质背景和矿床地质特征,总结了矿床的控矿因素,指出了进一步找矿方向。     

爆裂法作为快速测定流体包裹体中二氧化碳（和其它气体）含量的手段及其在勘探中的使用：以中国山东和河北省金矿为例

The acoustic decrepitation method heats a small monomineralic sample and counts pressure impulses as the inclusions burst when they develop high internal pressures.For aqueous fluids,the decrepitation temperature is correlated with the homogenisation temperature,but gas rich fluids give a distinct and characteristic low temperature decrepitation peak which can be used to recognize gas rich fluid inclusions.This information is useful in exploration for Au deposits,which are frequently associated with CO_2 rich and sometimes CH_4 rich fluids. This distinctive decrepitation occurs because the CO_2 rich inclusion fluids expand according to the gas law and develop internal pressures high enough to burst the host mineral grain at temperatures well below their homogenisation temperatures.In contrast,aqueous fluids condense to a liquid and vapour phase during post-entrapment cooling.Upon subsequent heating their internal pressures do not increase significantly until after homogenisation to a single phase occurs and hence they do not decrepitate"prematurely"as gas rich inclusions do. This behaviour is usually regarded as an annoyance in conventional microthermometric homogenisation studies,but can readily be used as an exploration aid to find mineralisation deposited from such gas rich fluids.Decrepitation results on samples from Cowra Ck, NSW,Australia,which have also been microthermometrically measured for CO_2 content,show that amounts of less than 5 mole % CO_2 are easily distinguished by decrepitation and amounts as low as 1 mole % CO_2 may be determinable. Examples of the use of acoustic decrepitation in the study of 6 gold mines in the Shandong and Hebei provinces of China are discussed.     

且末县克孜勒萨依金矿地球化学特征

克孜勒萨依金矿经地表地质工作和平硐控制,初步确定是一个蚀变岩型的金矿,主矿体长度在100m左右,宽度2~3m,金平均品位5×10~(-6),通过本次工作预测深部有隐伏矿体存在,有一定的开采价值,有进一步进行深部工程控制的必要.