Origin,discovery, exploration and development status and prospect of global natural hydrogen under the background of “carbon neutrality”

Global energy structure is experiencing the third transition from fossil energy to non-fossil energy, to solve future energy problems, cope with climate change, and achieve net-zero emissions targets by 2050. Hydrogen is considered to be the most potential clean energy in this century under the background of carbon neutrality. At present, the industrial methods for producing hydrogen are mainly by steam-hydrocarbon (such as coal and natural gas) reforming and by electrolysis of water, while the exploration and development of natural hydrogen had just started. According to this literature review: (1) Natural hydrogen can be divided into three categories, including free hydrogen, hydrogen in inclusions and dissolved hydrogen; (2) natural hydrogen could be mainly from abiotic origins such as by deep-seated hydrogen generation, water-rock reaction or water radiolysis; (3) natural hydrogen is widely distributed and presents great potential, and the potential natural hydrogen sources excluding deep source of hydrogen is about (254±91)×10⁹ m³/a according to a latest estimate; (4) at present, natural hydrogen has been mined in Mali, and the exploration and development of natural hydrogen has also been carried out in Australia, Brazil, the United States and some European countries, to find many favorable areas and test some technical methods for natural hydrogen exploration. Natural hydrogen is expected to be an important part of hydrogen energy production in the future energy pattern. Based on a thorough literature review, this study introduced the origin, classification, and global discovery of natural hydrogen, as well as summarized the current global status and discussed the possibility of natural hydrogen exploration and development, aiming to provide reference for the future natural hydrogen exploration and development.©2022 China Geology Editorial Office.     

韧性剪切带中的香炉碗子金矿床成因和黄铁矿找矿矿物学研究

香炉碗子金矿床产于韧性剪切带内,具有多期成矿的特点。矿床成因属浅成低温热液—蚀变岩型金矿床。黄铁矿形成于两个成矿阶段。早期黄铁矿含金量较少,其晶体形态主要为{hko}、{hko}+{100}。晚期黄铁矿以富含金为特征,主要为它形晶,呈细脉浸染状产出。黄铁矿的热电性特征可作为金矿的找矿标志。利用成矿阶段形成的黄铁矿所求出的产矿系数可以圈定矿体。其产矿系数<4010×10~(-2)者为工业矿体。     

某钼-铀矿床矿化特征及成因类型探讨

矿床产于中元古代地层中。矿区内酸性脉岩发育,常密集成带,矿床受穿过脉岩带的构造破碎带控制。矿化岩石主要为构造碎裂岩和角砾岩,其原岩为长英质脉岩、变石英砂岩、变安山岩、板岩及粉砂岩等。矿化以裂隙充填为主,对围岩化学成分的选择性不大。围岩蚀变有:绢云母化、硅化、钾长石化、黑云母化、黄铁矿化、赤铁矿化及水合多水高岭石化等。铀矿物主要为沥青铀矿、铀黑、铀石,其次有钛铀矿、水铀矾,含铀矿物有锐钛矿、金红石、赤铁矿、水合多水高岭石和褐铁矿等;其它金属矿物主要有辉钼矿、黄铁矿、方铅矿和黄铜矿。矿石具脉状、角砾状、块状和浸染状构造,沥青铀矿具胶状结构。矿床中钼的储量远大于铀,铀矿体产于钼矿体之中或其边部。通过室内、外研究,可以认为本矿床为与中酸性小侵入体有关的中-低温热液成因的钼-铀型复合矿床。     

安徽池州铜山铜矿床元素地球化学分带特征及意义

铜山铜矿是长江中下游成矿带内安庆-贵池矿集区中的一个中型矽卡岩型矿床,矿体赋存于铜山岩体与下二叠统栖霞组碳酸盐岩间的接触带内.典型剖面系统取样分析结果显示:从岩浆岩、矽卡岩到碳酸盐岩,元素地球化学组成总体上表现为渐变分带特征,即靠近岩体的矽卡岩富集Si、Fe、Mg及亲铁元素Co和亲铜元素Cu、Ag;远离岩体的矽卡岩富集Ca、Mn、Al、Ti、REE和亲铜元素Pb、Zn;远离大理岩带的强硅化蚀变岩富集Si、Fe、Li和Co,而强烈亏损Ca、Sr和REE.这种分带可以依据元素活化迁移理论加以解释.在矽卡岩形成过程中,岩浆热液携带Si、Fe、Mg、Al、Li、REE、大离子亲石元素Rb、Cs、亲铁亲铜元素Co、V、Zn以及高场强元素Ta、Zr、Nb、Hf、Ga、Be向大理岩迁移并富集于形成的矽卡岩中;大理岩中的Ca被活化后进入矽卡岩体系,而Sr、K及Pb则随流体搬运迁出.蚀变及矿化较弱的矽卡岩稀土总量较高(ΣREE=122.0×10-6),LREE富集[(La/Sm)N =3.99],HREE亏损[(Gd/Yb)N=2.85],Eu显示负异常(δEu =0.69),重稀土配分形式与新鲜石英二长斑岩相似,但La、Ce等轻稀土元素相对亏损.矽卡岩剖面元素分带特征及稀土配分模式指示铜山矽卡岩铜矿床为接触交代成因.结合已有氢氧同位素结果,认为铜山铜矿成矿流体主要来自岩浆热液,在矽卡岩退化蚀变和成矿期间有大气降水混入成矿流体.     

Geochemical characterization of the Paleoproterozoic (ca. 1.98-1.97) Darguwan-Surajpura mafic sills within the Bijawar basin,North-Central India: Genetic aspects and geodynamic implications

The widespread records of mafic intrusives (both sills and dykes) are reported from the Proterozoic sedimentary basins of the Indian Shield. Amongst them, the Bijawar basin is also intruded by Paleoproterozoic (ca. 1.98−1.97 Ga) mafic sills. We provide first hand information on petrological and geochemical characteristics of these mafic sills together with a few NW-trending mafic dykes belong to the Jhansi swarm emplaced within the Bundelkhand craton, adjacent to the Bijawar basin. These Paleoproterzoic mafic intrusive rocks, i.e. sills and dykes, are believed to be integral parts of the Jhansi LIP, identified in the Bundelkhand craton. The studied mafic magmatic samples are medium- to coarse-grained and contain doleritic mineral compositions and textures. Geochemically, the mafic sill samples of the Bijawar basin, which belong to the Darguwan-Surjapura mafic sills (DSMS), are sub-alkaline basaltic-andesite to andesite in character. They are co-genetic in nature and show close geochemical similarities with a set of NW-trending mafic dykes (low-Ti) emplaced in the Bundelkhand craton. On the other hand, another set of NW-trending mafic dykes (high-Ti) of the Bundelkhand craton have distinct geochemical nature; likely to have different genetic history. The rare-earth element contents and trace-element modeling suggest that the DSMS and low-Ti dyke samples are likely to be derived from a melt generated ≥20 % melting of a shallower mantle source (spinel stability field), whereas the high-Ti dyke samples show their derivation from a melt generated through ≤15 % melting of the similar mantle source but at deeper level (garnet or garnet-spinel transition stability field); with a substantiate percentage of olivine fractionation of melts before crystallization. Their emplacement in an intracratonic tectonic regime and role of plume in the genesis of these rocks are suggested. The geochemical signature also indicates the role of an ancient (Archean) subduction event that has metasomatized the mantle before the cratonization. Their spatiotemporal correlation with other similar magmatic events of the globe indicate that the Bundelkhand craton was closer to the Karelia-Kola craton (Baltica Shield), North China craton and northern Superior craton, which could be part of the Columbia supercontinent, during its assembly.     

贵州罗甸玉矿区滑石矿的发现及其成因探讨

罗甸滑石矿是贵州首次发现的白滑石矿,矿体呈似层状、透镜状产于辉绿岩体与围岩的接触带内,与罗甸玉共生。罗甸滑石为低铝、低铁质矿石,MgO含量接近滑石的理论值,结晶细、质纯、白度高,具有较高的开发利用价值,填补了贵州没有优质滑石矿的空白。罗甸滑石矿与罗甸玉矿的地质背景及其空间产出部位相同,并且具有相似的稀土元素组成及配分模式,揭示二者为相同成因,属于接触交代型矿床。     

云南祥云马厂箐斑岩微量元素与稀土元素特征

马厂箐斑岩体与铜、钼、金等多金属矿成矿关系密切.斑岩体微量元素与稀土元素显示斑岩体物质来源具有壳幔混合特征.     

南京市水西门市民广场防洪墙地段滑坡成因机制与工程地质灾害防治对策

概述了南京市水西门市民广场地质环境背景 ,分析了广场建设和灾害发生过程中存在的工程地质条件、工程、管理等方面的问题 ,剖析了该滑坡产生的机制 ,针对近年南京地区边坡失稳和滑坡灾害时有发生的状况 ,提出了防治对策。     

滇东北渔户村组内的富铅锌矿床成矿地质特征及成因

渔户村组为滇东北富铅锌矿床的重要产出层位。通过茂粗、金沙厂、五星、乐红、大海等矿床，总结了滇东北渔户村组内的富铅锌矿床的地质特征及成因，认为其与喷流沉积成矿作用和后期改造作用有关，为海底火山喷流沉积－改造成因。     

兰坪金满沉积-热液改造型铜矿

金满铜矿位于澜沧江大断裂与大箐山大断裂夹持的南北向紧密褶皱带，赋存于层间破碎带中。应属沉积-热液改造型。