Upscaling: Effective Medium Theory, Numerical Methods and the Fractal Dream

Upscaling is a major issue regarding mechanical and transport properties of rocks. This paper examines three issues relative to upscaling. The first one is a brief overview of Effective Medium Theory (EMT), which is a key tool to predict average rock properties at a macroscopic scale in the case of a statistically homogeneous medium. EMT is of particular interest in the calculation of elastic properties. As discussed in this paper, EMT can thus provide a possible way to perform upscaling, although it is by no means the only one, and in particular it is irrelevant if the medium does not adhere to statistical homogeneity. This last circumstance is examined in part two of the paper. We focus on the example of constructing a hydrocarbon reservoir model. Such a construction is a required step in the process of making reasonable predictions for oil production. Taking into account rock permeability, lithological units and various structural discontinuities at different scales is part of this construction. The result is that stochastic reservoir models are built that rely on various numerical upscaling methods. These methods are reviewed. They provide techniques which make it possible to deal with upscaling on a general basis. Finally, a last case in which upscaling is trivial is considered in the third part of the paper. This is the fractal case. Fractal models have become popular precisely because they are free of the assumption of statistical homogeneity and yet do not involve numerical methods. It is suggested that using a physical criterion as a means to discriminate whether fractality is a dream or reality would be more satisfactory than relying on a limited data set alone.     

环境硒污染的植物修复研究进展

硒污染已成为全球性的环境问题,严重威胁人类健康和环境安全。本文概述了环境硒污染植物修复技术的研究进展,包括硒富集植物的应用、富集硒的机理及生物技术对它们的改造。指出了当前研究在硒富集植物富集机理及田间应用时的不足;并展望了今后如何进一步寻找和使用生物技术培育硒超富集植物、探求富集机理和田间试验。     

Hydraulic parameters and solute velocities in triple-porosity karstic-fissured-porous carbonate aquifers: case studies in southern Poland

 Rock and flow parameters of three karstic-fissured-porous aquifers in the Krakow-Silesian Triassic formations were measured using various methods and compared. Though cavern and fissure porosities are shown to be very low (cavern porosity below 0.5% and fracture porosity below 0.2%), they contribute dominantly to the hydraulic conductivity (from about 1.3×10^–6 to about 11×10^–6 m/s). Matrix porosity (2–11%) is shown to be the main water reservoir for solute transport and the main or significant contributor to the specific yield (<2%). Though the matrix porosity is shown to be much larger than the sum of the cavern and fissure porosities, its contribution to the total hydraulic conductivity is practically negligible (hydraulic conductivity of the matrix is from about 5×10^–11 m/s to about 2×10^–8 m/s). On the other hand, the matrix porosity (for neglected cavern and fissure porosities) when combined with tracer ages (or mean travel times) is shown to yield proper values of the hydraulic conductivity (K) by applying the following formula: K≅(matrix porosity×mean travel distance)/(mean hydraulic gradient×mean tracer age). Confirming earlier findings of the authors, this equation is shown to be of great practical importance because matrix porosity is easily measured in the laboratory on rock samples, whereas cavern and fracture porosities usually remain unmeasurable. Received: 21 February 1997 · Accepted: 13 May 1997     

Numerical estimation of effective diffusion coefficients for charged porous materials based on micro-scale analyses

In order to describe diffusive transport of solutes through a porous material, estimation of effective diffusion coefficients is required. It has been shown theoretically that in the case of uncharged porous materials the effective diffusion coefficient of solutes is a function of the pore morphology of the material and can be described by the tortuosity (tensor) (Bear, 1988 [1]). Given detailed information of the pore geometry at the micro-scale the tortuosity of different materials can be accurately estimated using homogenization procedures. However, many engineering materials (e.g., clays and shales) are characterized by electrical surface charges on particles of the porous material which strongly affect the (diffusive) transport properties of ions. For these type of materials, estimation of effective diffusion coefficients have been mostly based on phenomenological equations with no link to underlying micro-scale properties of these charged materials although a few recent studies have used alternative methods to obtain the diffusion parameters (Jougnot et al., 2009; Pivonka et al., 2009; Revil and Linde, 2006 2, 3 and 4). In this paper we employ a recently proposed up-scaled Poisson–Nernst–Planck type of equation (PNP) and its micro-scale counterpart to estimate effective ion diffusion coefficients in thin charged membranes. We investigate a variety of different pore geometries together with different surface charges on particles. Here, we show that independent of the charges on particles, a (generalized) tortuosity factor can be identified as function of the pore morphology only using the new PNP model. On the other hand, all electro-static interactions of ions and charges on particles can consistently be captured by the ratio of average concentration to effective intrinsic concentration in the macroscopic PNP equations. Using this formulation allows to consistently take into account electrochemical interactions of ions and charges on particles and so excludes any ambiguity generally encountered in phenomenological equations.     

浙北平原区土壤硒地球化学研究

基于嘉善县基本农田质量调查和嘉善县富硒土地资源专项调查中高密度的土壤硒数据及其它测试指标,对浙北嘉善表层土壤硒的含量、分布及影响因素进行了初步研究。分析结果显示,嘉善土壤总量硒平均值为0.33mg/kg,在干窑——姚庄一带存在约57km~2的富硒土壤(Se≥0.40mg/kg);不同土属硒含量差别不大;硒在土壤剖面中分布的总体趋势是硒在表土层聚集;嘉善富硒土壤以有机结合态和腐植酸态两种形态为主,残渣态也占有一定比例。结合全量硒与有机碳的相关性分析和富硒土壤的硒形态分析等结果,本研究认为高硒背景与有机质吸附对嘉善富硒土壤的形成起到了关键作用,改变了嘉善缺硒的认识。     

Experimental evaluation of reservoir quality in Mesozoic formations of the Perth Basin (Western Australia) by using a laboratory low field Nuclear Magnetic Resonance

Accurate porosity and permeability evaluation of rock formations is critical to estimate the quality and resource potential of a reservoir. In addition to directly measure the porosity and pore size distribution, low field Nuclear Magnetic Resonance (NMR) is able to measure the effective porosity and estimate the in-situ formation permeability, though its robustness is arguable and requires calibrations on cores with specific lithologies.The Mesozoic formations of the central Perth Basin (Western Australia) host hot sedimentary aquifers and recently became key targets for geothermal heat extraction. A collection of cores was retrieved from three wells intersecting these units. The characterisation of their flow properties complements the current evaluation of the Perth Basin by adding new data on effective porosity, pore size distribution, pore geometry and calibration of predictive models for the permeability according to a comprehensive facies classification scheme.This study highlights the consistency of the NMR approach when compared to conventional helium injection method. Most favourable lithologies for well production correspond to very coarse to fine sandstones of fluvial channel fill with porosities >15% and permeabilities >>1 mD. Similarly, these facies exhibit (i) the highest effective porosities, (ii) the highest pore space to pore throat ratio, and (iii) the lowest contribution of clay bound water. These aspects confirm the importance of clay occurrence in the assessment of the flow efficiency of a formation.The Yarragadee Formation presents the best reservoir quality regarding its porosity and permeability, even though high discrepancies occur locally owing to the great variability of lithofacies encountered. The scattered values observed for the Lesueur Sandstone are likely to be due to the basin architecture and fault system which generate different mechanical compaction and secondary cementation. Given an adequate facies analysis, the NMR method represents a powerful tool to estimate the flow efficiency of a reservoir.     

南黄海沿岸滩涂文蛤中痕量硒的周年变化探讨

采用4︰1混合酸湿法消解,氢化物发生原子荧光光谱法(HG-AFS)测定了南黄海沿岸滩涂文蛤生物体中微量元素硒的周年变化,并用质控样和加标回收保证结果的可靠性。结果显示:硒的周年含量为0.2~0.5 mg/kg,平均值为0.330 mg/kg,文蛤体内硒的含量呈一定规律性变化,春、秋季高,夏、冬季低。说明文蛤中硒含量因不同季节而具有明显差异,其含量变化与海水温度、饵料生物及文蛤生长繁殖等因素有关。     

National comprehensive approaches for rebuilding fisheries in South Korea

Korea's coastal and offshore fisheries have experienced reduction in their catch in the early 2000. The amount of catch from coastal and offshore fisheries dropped from 1.7 million tons in 1986 to 1 million tons in 2004. To address such catch reduction, fish stock enhancement programs have been constantly developed and implemented. However, as fish stocks have been estimated to decrease since 2000 in spite of various management measures, the Korean Government genuinely acknowledges the necessity to enhance fisheries productivity through the recovery of depleted fish stocks. Based on such acknowledgement, a fish stock rebuilding plan (FSRP) combined with conventional fish stock enhancement programs was established in 2005. For stocks which have shown drastic decrease, a FSRP was set up and promoted. So far, 10 FSRPs have been established and operated, and plan is being made to expand them to 20 species by 2012. The result of pilot projects shows that stocks have been increasing after the introduction of FSRPs. For instance, the catch per unit effort (CPUE) of sandfish in the East Sea has increased from 0.44 in 2005 to 0.78 in 2011. Consequently, fishing income has increased by 15%. The key lessons learned during the implementation of FSRP are: the causes for the decrease of stock vary and are complicated and it is necessary to adjust and eliminate some conventional policies that could have unforeseen negative impacts on fish stocks. The FSRP-based fisheries management policy in Korea carries great significance, for it has changed the focus of policy from simply maintaining the status quo to stock recovery and it allows relevant stakeholders to get actively involved in the procedures of establishing and promoting the plan, leading to effective implementation of the plan. The current FSRP is operated with species, but if it can be gradually expanded to encompass the whole ecosystem, it will greatly contribute to more effective management and fish stock recovery for all species in offshore and coastal waters surrounding Korea.     

江西会昌周田镇地面塌陷灾害CSAMT法勘查实例分析

介绍了江西会昌县周田镇地面塌陷灾害物探CSAMT法勘查技术、资料分析、勘查成果及验证情况。对了解塌陷区盖层有效厚度、塌落现状、塌陷区后续具体治理方案及决策有十分重要的意义,对在类似地电条件下地质灾害物探勘查方法的选择、资料解释等具一定的借鉴意义。     

硒(Ⅳ)-氯化四苯胂盐酸盐络合物的吸附波及其应用

本文研究了在HCl介质中,Se(Ⅳ)-氯化四苯胂络合物的极谱行为。在0.05mol/LHCl溶液中,该络合物于-0.58V(vs.SCE)处出现灵敏的吸附波。Se的检测下限可达0.0001μg/ml。本文拟定的方法应用于天然水中痕量Se的直接测定,结果良好。