Riddle of arsenic in groundwater of Bengal Delta Plain—role of non-inland source and redox traps

In the Bengal Delta Plain (BDP) the primary arsenic sourcing appears to be different from the global scenario. Here, the Terminal Pleistocene–Holocene depositional platform, the interactive early Holocene depositional morphology with fluvio-estuarine and marine incursions played a crucial role for arsenic sourcing and enrichment. The lenticular silt-fine sand layer between anoxic clay beds favoured entrapment of dissolved organic carbon with decayed phyto-planktons debris. The Terminal Pleistocene–Holocene transgression and regression processes may have acted as major events in the BDP. Interestingly, at the end of the last glacial maxima, the Pleistocene delta had undergone block movements, wherein some parts of the platform were raised above the level of Holocene deposition. Those blocks were found to be free from arsenic in the groundwater. The sea, during re-emerging inundation (10–7 ka BP), has witnessed a monsoon-induced environment in the BDP with the resultant oscillation of sea level leading to higher upsurge towards the north. This might have resulted in the marine incursion and inundation in pre-existing land depressions. Meanwhile arsenic entrapments through marine incursion as well as enrichment in the presence of organic carbon/DOC and/or Fe/Mn/Al catalytic agents could have developed into localised redox traps. It may be of relevance that due to the repetitive transgressive–regressive phases in Holocene, resulting in periodic exposure and weathering of iron-bearing minerals and consequent iron enrichment in the aquifer system. The iron, thus present, had free charge to host arsenic as a sink. It appears that arsenic, wherever found, would likely be of atypical localised exhaustible phenomenon, both in horizontal and vertical context. It also rationalises the cause of the absence of arsenic in the other nearby Pleistocene platform, which has not come across Holocene interaction and marine incursion, as to the likely limiting condition for the search for arsenic in the BDP or beyond.     

Territorializing land conflict: Space,place, and contentious politics in the Brazilian Amazon

Brazil possesses a long history of violent struggle for land, and its most recent phase is occurring predominantly in the Amazon Basin. Consequently, this paper attempts to territorialize land conflict in the Brazilian Amazon, and in so doing, to illuminate the place-specific intersection of historic social, political, and economic circumstance that created a violent landscape in the so-called “South of Pará.” The paper’s premise is that such conflict can be best viewed as resulting from a dialectic between general social processes operating across spatial scales, which create necessary conditions for conflict, and place-specific historical circumstances that transform necessary into sufficient conditions. The paper presents a framework integrating the theory of contentious politics and literatures addressing violence associated with the Amazonian frontier and with resource scarcity (and abundance). The discussion and theoretical application deconstruct the environmental, cognitive, and relational mechanisms that created violence in the South of Pará, and set the stage for the Eldorado dos Carajás massacre in April of 1996.     

Prediction of creep characteristic of rock under varying environment

The strain developed due to creep is mainly proportional to the logarithm of the time under load, and is mostly proportional to the stress and temperature. At higher temperature the creep rate falls slowly with respect to time, and the creep strain is proportional to a fractional power of time, with the exponent increasing as the temperature increases and reaching a value approximately one-third at temperatures of about 0.5°C. At these temperatures, the creep increases with stress according to a power greater than unity and possibly exponentially. It increases with temperature as (−U/kT), where U is an activation energy and k is Boltzman’s constant. There are different methods to determine the creep strain and the energy of Jog (B) including experimental methods, multivariate regression analysis, and by numerical simulation. These methods are less cumbersome and time consuming. In the present investigation, artificial neural network technique has been used for prediction of the creep strain and energy of Jog (B). Two different networks have been tested and validated. Both the networks have four input neurons and one hidden layer with five neurons, and one output neuron. The data for different rocks at temperatures up to 750°C under conditions of compressive or tortional stress are taken from the literatures. The training and testing data sets used were 163 and 14, respectively. To deal with the problem of overfitting of data, Bayesian regulation has been used and network is trained with suitable training epochs. The coefficients of correlation among the predicted and observed values are found high and they improve the confidence of the users. The mean absolute percentage error obtained are also very low.     

The 17 March 2005 Kuzulu landslide (Sivas, Turkey) and landslide-susceptibility map of its near vicinity

Landslides are common natural hazards in the seismically active North Anatolian Fault Zone of Turkey. Although seismic activity, heavy rainfall, channel incisions, and anthropogenic effects are commonly the main triggers of landslides, on March 17, 2005, a catastrophic large landslide in Sivas, northeastern of Turkey, the Kuzulu landslide, was triggered by snowmelt without any other precursor. The initial failure of the Kuzulu landslide was rotational. Following the rotational failure, the earth material in the zone of accumulation exhibited an extremely rapid flow caused by steep gradient and high water content. The Agnus Creek valley, where Kuzulu village is located, was filled by the earth-flow material and a landslide dam was formed on the upper part of Agnus Creek. The distance from the toe of the rotational failure down to the toe of the earth flow measured more than 1800 m, with about 12.5 million m³ of displaced earth material. The velocity of the Kuzulu landslide was extremely fast, approximately 6 m/s. The main purposes of this study are to describe the mechanism and the factors conditioning the Kuzulu landslide, to present its environmental impacts, and to produce landslide-susceptibility maps of the Kuzulu landslide area and its near vicinity. For this purpose, a detailed landslide inventory map was prepared and geology, slope, aspect, elevation, topographic-wetness index and stream-power index were considered as conditioning factors. During the susceptibility analyses, the conditional probability approach was used and a landslide-susceptibility map was produced. The landslide-susceptibility map will help decision makers in site selection and the site-planning process. The map may also be accepted as a basis for landslide risk-management studies to be applied in the study area.     

“雪龙号”2003北极航次气相多环芳烃纬度分布观测

2003年“雪龙号”北极科学考察期间,对沿途海洋大气进行采样,分析其中气相多环芳烃的空间分布。结果显示,气相中主要是2-4环的多环芳烃,其中菲为主要的化合物,平均占到总多环芳烃的55.1%。在整个航程的广泛区域尺度内,气相总多环芳烃浓度在1043.9-92993.1pg/m3。空间分布上,远东亚的海面>北太平洋海面>北极圈以内海面;总多环芳烃的浓度随纬度升高呈现显著降低的趋势。通过Clausius-Clapeyron方程对浓度和温度相互关系的分析表明,温度是控制气相多环芳烃长距离传输的主要因素。     

兰州市2001年沙尘气溶胶质量浓度的特征分析

 分析了2001年沙尘暴期间兰州与靠近沙尘源区的武威的沙尘浓度和粒径分布特征,并运用对数正态分布规律拟合了沙尘粒径的分布。通过对比武威、皋兰和兰州沙尘暴期间沙尘浓度的变化以及武威与兰州的沙尘粒径分布特征,揭示了河西走廊沙漠对兰州市沙尘暴的影响。     

中国陆地净初级生产力的季节变化研究

了解不同季节陆地净初级生产力(NPP)的变化及与气候的相互关系以及在不同地类的差异对深刻理解我国陆地生态系统对全球气候变化的响应和陆地碳循环研究具有重要意义。本文使用1981～2000年间GLO-PEM模型模拟的我国陆地NPP数据和同期气温、降水以及土地利用数据, 研究不同季节我国陆地植被NPP的变化。结果表明,在1981～2000年期间,四个季节的NPP都呈显著增加趋势,春季是NPP增加速率最快的季节,夏季是NPP增加量最大的季节。耕地在春、夏和秋季NPP增长和增长率最高,林地冬季NPP增长最多而水域冬季NPP增长率最高。夏季NPP增长最高的区域分布于我国东部的多数地区、内蒙古东部、四川盆地、贵州东部、藏南和新疆西部;夏季NPP降低最多的区域分布于在呼伦贝尔高原、鄂尔多斯高原、黄土高原、青藏高原东部和新疆西北部。     

Refined modeling and movement characteristics analyses of irregularly shaped particles

Irregularly shaped (IRS) particles widely exist in many engineering and industrial fields. The macro physical and mechanical properties of the particle system are governed by the interaction between the particles in the system. The interaction between IRS particles is more complicated because of their complex geometric shape with extremely irregular and co‐existed concave and convex surfaces. These particles may interlock each other, making the sliding and friction of IRS particles more complex than that of particles with regular shape. In order to study the interaction of IRS particles more efficiently, a refined method of constructing discrete element model based on computed tomography scanning of IRS particles is proposed. Three parameters were introduced to control the accuracy and the number of packing spheres. Subsequently, the inertia tensor of the IRS particle model was optimized. Finally, laboratory and numerical open bottom cylinder tests were carried out to verify the refined modeling method. The influence of particle shape, particle position, and mesoscopic friction coefficient on the interaction of particles was also simulated. It is noteworthy that with the increase of mesoscopic friction coefficient, the fluidity of IRS particle assembly decreases, and intermittent limit equilibrium state may appear. Copyright © 2014 John Wiley & Sons, Ltd.     

Mercury and methylmercury biogeochemistry in a thawing permafrost wetland complex,Northwest Territories,Canada

In arctic and sub‐arctic environments, mercury (Hg), more specifically toxic methylmercury (MeHg), is of growing concern to local communities because of its accumulation in fish. In these regions, there is particular interest in the potential mobilization of atmospherically deposited Hg sequestered in permafrost that is thawing at unprecedented rates. Permafrost thaw and the resulting ground surface subsidence transforms forested peat plateaus into treeless and permafrost‐free thermokarst wetlands where inorganic Hg released from the thawed permafrost and draining from the surrounding peat plateaus may be transformed to MeHg. This study begins to characterize the spatial distribution of MeHg in a peat plateau–thermokarst wetland complex, a feature that prevails throughout the wetland‐dominated southern margin of thawing discontinuous permafrost in Canada's Northwest Territories. We measured pore water total Hg, MeHg, dissolved organic matter characteristics and general water chemistry parameters to evaluate the role of permafrost thaw on the pattern of water chemistry. A gradient in vegetation composition, water chemistry and dissolved organic matter characteristics followed a toposequence from the ombrotrophic bogs near the crest of the complex to poor fens at its downslope margins. We found that pore waters in poor fens contained elevated levels of MeHg, and the water draining from these features had dissolved MeHg concentrations 4.5 to 14.5 times higher than the water draining from the bogs. It was determined through analysis of historical aerial images that the poor fens in the toposequence had formed relatively recently (early 1970s) as a result of permafrost thaw. Differences between the fens and bogs are likely to be a result of their differences in groundwater function, and this suggests that permafrost thaw in this landscape can result in hotspots for Hg methylation that are hydrologically connected to downstream ecosystems. Copyright © 2016 John Wiley & Sons, Ltd.     

A multi‐proxy record of changing environments from ca. 30 000 to 9000 cal. a BP: Onepoto maar palaeolake,Auckland, New Zealand

We present a high‐resolution record of lacustrine sedimentation spanning ca. 30 000 to 9000 cal. a BP from Onepoto maar, northern North Island, New Zealand. The multi‐proxy record of environmental change is constrained by tephrochronology and accelerator mass spectrometric ¹⁴C ages and provides evidence for episodes of rapid environmental change during the Last Glacial Coldest Period (LGCP) and Last Glacial–Interglacial Transition (LGIT) from northern New Zealand. The multi‐proxy palaeoenvironmental record from Onepoto indicates that the LGCP was cold, dry and windy in the Auckland region, with vegetation dominated by herb and grass in a beech forest mosaic between ca. 28 500 and 18 000 cal. a BP. The LGCP was accompanied by more frequent fires and influx of clastic sediment indicating increased erosion during the LGCP, with a mid‐LGCP interstadial identified between ca. 25 000 and 23 000 cal. a BP. Rapid climate amelioration at ca. 18 000 cal. a BP was accompanied by increased terrestrial biomass exemplified by the expansion of lowland podocarp forest, especially Dacrydium cupressinum. Increasing biomass production is reversed briefly by LGIT perturbations which are apparent in many of the proxies that span ca. 14 000–10 500 cal. a BP, suggesting generally increased wetness and higher in situ aquatic plant productivity with reduced terrestrial organic matter and terrigenous detrital influx. Furthermore, conditions at that time were probably warmer and frosts rare based on the increasing importance of Ascarina. The subsequent early Holocene is characterised by podocarp conifer forest and moist mild conditions. Postglacial sea‐level rise breached the crater rim and deposited 36 m of estuarine mud after ca. 9000 cal. a BP. Copyright © 2011 John Wiley & Sons, Ltd.