Kinetics of redox cycling of iron coupled with fulvic acid

The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10^–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > Fe^III-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)₃(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity.     

勘查油气田化探新方法——土壤相态烃测量法

烃气测量是油气化探最主要的方法。目前应用的烃气测量方法有两类:一类是测量土壤中游离烃气如K—V指纹法、吸附丝法、物上气法及直接取土壤气测量法等。此类方法由于需特殊设备及壤气测量方法本身固有的缺陷,目前还未得到普遍应用,另一类为土壤吸附烃气法即国内外目前普遍使用的酸解烃气法、此法在多数油气田上取得好效果,但也有相当多的地区如黄土、荒漠及水网发育等特殊景观区效果不好或不显著。本文介绍一种新的烃气测量法──土壤相态烃测量法。这是用一种特殊的技术,只选择性提取由油气藏渗漏过程中保存在运移通道围岩及近地表土壤各种次生矿物结构中以"穴居"态存在的轻烃组分。"穴居"态烃为累积性的指标,不受外界温度、修水等的影响,保存较牢固,测定结果稳定。相态烃法避免了酸解烃法存在的生物成因烃、矿物同生烃及碳酸盐的干扰影响,提高了测量指标的信噪比,突出了应有的异常。本方法已在黄土厚覆盖区两个已知油气田和一个风成沙覆盖的断裂发育油田上试验获得成功,结果表明相态烃法优于酸解烃法。     

基于网络药理学与分子对接技术探讨青蛇方外用治疗湿疹的作用机制

目的：基于网络药理学与分子对接技术探讨青蛇方外用治疗湿疹的作用机制。方法：应用TCMSP和UniProt数据库平台查询青蛇方组方的有效活性成分及靶基因,与疾病靶基因取交集后构建蛋白质-蛋白质相互作用(PPI)网络;应用DAVID数据库,对潜在核心作用靶点基因进行基因本体（GO）功能、京都基因与基因组百科全书（KEGG）通路富集分析。利用分子对接原理论证青蛇方生物活性成分与核心靶点的分子结合能力。结果：筛选出青蛇方有效成分63种,作用靶点99个;主要有β-谷甾醇、2,4,7-三羟基-9,10-二氢菲、靛蓝素、豆甾醇、色氨酸等关键成分;转录因子AP-1（JUN）、肿瘤坏死因子（TNF）、原癌基因（RELA）、干扰素γ（IFNG）、转化生长因子-β1（TGF-β1）等核心基因。关键信号通路有癌症信号通路、恰加斯病通路、弓形体病通路、脂质和动脉粥样硬化通路等,分子对接结果显示活性成分与核心靶点基因结合能力较强。结论：青蛇方外用可以通过多种活性成分、多种通路有效抑制免疫炎症反应,促进免疫系统正常运行,从而达到治疗湿疹的目的。     

On the spatial characteristic of the short term and imminent anomalies of underground water behaviors before strong earthquake

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重视和加强岩矿物性的测量研究

本文从物探科学技术的进步,勘查任务的发展变化、物探方法应用范畴的扩大和物性勘探等几个方面,论述了岩石和矿物物理性质测量、研究的重要性,指出：物性工作不可能毕其功于一役,并提出了五点建议：１．深入研究各类矿藏及其围岩（直至地面）物性的空间变化规律,为选择、研究合适的物探方法,提高物探效果,进一步探讨“直接”找矿问题,提供依据;２．这项工作可专门进行,但最好尽可能利用为其他目的而设计的钻井进行;３．物     

洛安江干渠老菁湾滑坡分析

洛安江水库灌溉工程是贵州黔北万亩以上骨干工程之一,中华人民共和国成立初期建成。１９９１年＂７．５Ｆ＂洪灾,连续大暴雨,河水暴涨,倒灌暗河,产生高静、动水压力作用。岸坡岩体受不利结构面组合,发生顺层岩质滑坡,破坏干渠,严重影响灌溉。本文根据滑坡破坏情况,对滑坡产生的地质环境、滑坡特征、滑坡形成机理（滑坡形式和破坏机理,各种稳定性分析与评价）,以及产生滑坡原因进行了初步分析。     

TheROSAT survey of extreme UV sources: a new window on the universe

This paper discusses the first all-sky suvey of cosmic extreme ultra-violet sources, discovered by theROSAT Wide Field Camera. Details of the instrument and the survey are presented, with comparisons made to previous selected surveys in the X-ray regime. The subsequent optical identification program is described, and the major results summarized. I then discuss the main classes of EUV emitters: active chromosphere stars and hot white dwarfs, and describe the importance of EUV obserevations in understanding the astrophysics of these objects. Many bright, and relatively nearby, sources have been identified with hitherto unrecognized active stars, representing the extremes in chromospheric and coronal activity, be it binary or age related. Many new hot DA white dwarfs have also been indentified, and the most exciting result in this area is the discovery that significant traces of heavier elements (e.g. C, N, O, Si, Fe & Al) exist in their atmospheres, substantially increasing their EUV opacities. The importance of hot white dwarfs as standard candles in probing the local interstellar medium is also discussed. Miscellaneous counterparts (AGN, PNN, O-B stars and CVs) that make up the rest of the sample of EUV sources are also briefly mentioned. I conclude the paper with a discussion of the new magnetic cataclysmic variables discovered at SAAO, which have been the subject of intensive follow-up observations.     

冀西北长城纪宣龙式铁矿层中微体植物化石的发现及其意义

本文研究的是笔者等在冀西北长城系串岭沟组宣龙式铁矿层中发现的微体植物化石,这些化石都保存在铁质叠层石(肾状赤铁矿)和铁质核形石(鲕状赤铁矿)的基本层中。微化石以丝状体为主,部分为球状体。归属于原核生物蓝藻门颤藻科的两个属和色球藻科的一个属。化石层同位素年龄约在1800—1757Ma。这些化石与北美冈弗林特组微化石比较,既有些相似,又有些区别。该化石的发现为研究铁矿的成因,指示沉积环境及层位对比都很有意义。     

A combined study of macroseismic data and focal mechanisms applied to the West-Bohemian earthquake,Czechoslovakia

The main shock of the West-Bohemian earthquake swarm, Czechoslovakia, (magnitudem=4.5, depthh=10 km) exhibits an irregular areal distribution of macroseismic intensities 6° to 7° MSK-64. Four lobes of the 6° isoseismal are found and the maximum observed intensity is located at a distance of 8 km from the instrumentally determined epicentre. This distribution can be explained by the energy flux of the directS wave generated by a circular source, the hypocentral location and focal mechanism of which are taken from independent instrumental studies. The theoretical intensity, which is assumed to be logarithmically proportional to the integrated squared ground-motion velocity (i.e.,I=const+log v ² (t)dt), fits the observed intensity with an overall root-mean-square error less than 0.5°. It is important that the present intensity data can also be equally well explained by the isotropic source. The fit was attained by means of a horizontally layered model though large fault zones and an extended sedimentary basin suggest a significant lateral heterogeneity of the epicentral region. The results encourage a broader application of the simple modelling technique used.