Kinetic and equilibrium studies of copper-dissolved organic matter complexation in water column of the stratified Krka River estuary (Croatia)

An interaction of dissolved natural organic matter (DNOM) with copper ions in the water column of the stratified Krka River estuary (Croatia) was studied. The experimental methodology was based on the differential pulse anodic stripping voltammetric (DPASV) determination of labile copper species by titrating the sample using increments of copper additions uniformly distributed on the logarithmic scale. A classical at-equilibrium approach (determination of copper complexing capacity, CuCC) and a kinetic approach (tracing of equilibrium reconstitution) of copper complexation were considered and compared. A model of discrete distribution of organic ligands forming inert copper complexes was applied. For both approaches, a home-written fitting program was used for the determination of apparent stability constants (K_i^equ), total ligands concentration (L_iT) and association/dissociation rate constants (k_i¹,k_i^- 1).A non-conservative behaviour of dissolved organic matter (DOC) and total copper concentration in a water column was registered. An enhanced biological activity at the freshwater–seawater interface (FSI) triggered an increase of total copper concentration and total ligand concentration in this water layer. The copper complexation in fresh water of Krka River was characterised by one type of binding ligands, while in most of the estuarine and marine samples two classes of ligands were identified. The distribution of apparent stability constants (log K₁^equ: 11.2–13.0, log K₂^equ:8.8–10.0) showed increasing trend towards higher salinities, indicating stronger copper complexation by autochthonous seawater organic matter.Copper complexation parameters (ligand concentrations and apparent stability constants) obtained by at-equilibrium model are in very good accordance with those of kinetic model. Calculated association rate constants (k₁¹:6.1–20 × 10³ (M s)^− 1, k₂¹: 1.3–6.3 × 10³ (M s)^− 1) indicate that copper complexation by DNOM takes place relatively slowly. The time needed to achieve a new pseudo-equilibrium induced by an increase of copper concentration (which is common for Krka River estuary during summer period due to the nautical traffic), is estimated to be from 2 to 4 h.It is found that in such oligotrophic environment (dissolved organic carbon content under 83 µM_C, i.e. 1 mg_CL^− 1) an increase of the total copper concentration above 12 nM could enhance a free copper concentration exceeding the level considered as potentially toxic for microorganisms (10 pM).     

大嵛山附近海域游泳动物种类组成和资源现状及其变化分析

2006年1月～10月福建闽东大嵛山附近海域游泳动物调查研究结果表明,该海域的游泳动物有97种,其中鱼类51种（软骨鱼1种,硬骨鱼类50种）,隶属于9目24科42属;甲壳类42种,隶属于2目15科20属;头足类4种,隶属于3目3科3属.暖水性种类为33种,占鱼类总种数的64.7%;暖温性鱼类18种,占鱼类总种数的35.3%,未出现冷温性和冷水性鱼类.种类数的季节变化依次呈夏季〉冬季〉秋季〉春季.生物量的季节变化,依次呈夏季〉秋季〉春季〉冬季;而生物量尾数的季节变化,依次呈夏季〉春季〉秋季〉冬季.平均单位网次渔获生物量和密度分别为9.53kg/h和1 319 ind/h.生物量优势种和密度优势种分别为大黄鱼和中华管鞭虾.扫海面积法估算年平均现存资源量为57 370 ind/km^2和404.51kg/km^2.同时,本文对该海域游泳生物的资源结构现状与历史调查数据作了对比分析,并讨论了多样性结构与生物量的季节性变化规律.结果表明,该海域渔业资源有严重衰退的现象,多样性结构与生物量的季节性变化并不具有必然的一致性.     

南海北部海区软骨鱼类种类组成和资源密度分布

根据2006～2007年南海北部海区4季的调查资料,分析该海区软骨鱼类的种类组成和资源密度的分布．结果表明,软骨鱼类有32种,分隶于9目17科,优势种为斑鳐、曾氏兔银鲛、褐黄扁缸、橙黄鲨;渔获率D断面最高（10．19kg／h）,B断面最低（4．52kg／h）;渔获率有明显的季节变动,夏季最高（12．16kg／h）,秋季最低（3．71kg／h）,平均渔获率为7．05kg／h;密集分布于180m和140m水深处;其年均资源密度为94．00kg／km^2．文中并讨论合理利用和保护该类群的措施．     

四川雪宝顶W-Sn-Be矿床中矿物化学组成及矿床成因

雪宝顶矿床位于四川省的松潘甘孜造山带中,以出产大颗粒含W-Sn-Be-F-P的矿物而闻名,前人对该矿床已经开展了大量的研究,但缺乏对粗粒矿物的主次痕量元素研究.本次研究采用X射线荧光光谱(XRF)、电子探针(EMPA)和电感耦合等离子体质谱(ICP-MS)技术对矿床中各矿物的主次痕量元素进行测试分析.结果显示,雪宝顶矿...     

EFFECTS OF COMPOSITION AND STRUCTURE OF ALGINATES ON ADSORPTION OF DIVALENT METALS

Results of a series of experiments(on the adsorption of divalent metal ions by dried alginic acid, Na and Ca alginates of different composition and block structure) conducted in this systematic study of the effects of the composition and structure of alginates on the static adsorption equilibrium of divalent metal ions indicate that the properties of alginate adsorption to divalent metal ions are highly different, depending not only on the cations used, but also on the form and structure of the alginates. There is close correlation between the adsorption properties and the structure of the alginates. The selectivity coefficient of Na alginate for Cd-Sr ion exchange tends to increase with the increase of the M/G ratio in alginate, whereas the adsorption capacity of Ca alginate for Cu~(2+) ion decrease with the increase of the G-block or the average length of the G-block ((?)_G) and the total adsorption capacity of alginic acid is found to vary in the same order as the F_(MM)(diad frequency) in alginate in     

Mapping of aggregated floodplain plant communities using image fusion of CASI and LiDAR data

Combined optical and laser altimeter data offer the potential to map and monitor plant communities based on their spectral and structural characteristics. A problem unresolved is, however, that narrowly defined plant communities, i.e. plant communities at a low hierarchical level of classification in the Braun-Blanquet system, often cannot be linked directly to remote sensing data for vegetation mapping. We studied whether and how a floristic dataset can be aggregated into a few major discrete, mappable classes without substantial loss of ecological meaning. Multi-source airborne data (CASI and LiDAR) and floristic field data were collected for a floodplain along the river Waal in the Netherlands. Mapping results based on floristic similarity alone did not achieve highest levels of accuracy. Ordination of floristic data showed that terrain elevation and soil moisture were the main underlying environmental drivers shaping the floodplain vegetation, but grouping of plant communities based on their position in the ordination space is not always obvious. Combined ordination-based grouping with floristic similarity clustering led to syntaxonomically relevant aggregated plant assemblages and yielded highest mapping accuracies.     

试论大厂锡多金属矿田矿化蚀变分带特征

大厂矿田矿化蚀变分带特征十分明显, 在水平方向, 整个矿田可分为西、中、东３ 个矿带。西、东矿带主要产出锡石—硫化物型矿床, 围岩蚀变类型主要有硅化、钾长石化、电气石化、绢云母化、碳酸盐化等。中矿带主要分布矽卡岩型锌铜硫化物矿床, 并有锑钨石英脉型矿床叠加其上。整个矿田矿化蚀变分带又具明显的不对称性, 并且每一种矿化类型又表现出各自的分带特点。大厂矿田的总体矿化蚀变分带特征与传统的顺向或逆向分带不同, 反映了多成因、多期次叠加成矿及蚀变的特点     

利用U—1000型激光拉曼探针测定流体包裹体气体成分的研究

本文利用U－1000型激光拉曼探针成功地测量出单个流体包裹体中H2S、CH4、CO2气体成分，并讨论了包裹体中这些气体的拉曼谱峰位移与包裹体内压的关系，分析了影响激光拉曼探针定量测定包裹体气相成分的取面积和拉曼定量因子因素。     

梯级水库运行期设计洪水理论和方法

人类活动和气候变化显著地改变了河川径流及洪水的时空分配过程，直接影响下游断面的设计洪水。本文综述水库对下游水文情势的影响，提出梯级水库运行期设计洪水理论方法和研究内容；重点探讨非一致性洪水频率分析和基于Copula函数的最可能地区洪水组成法，比较各种方法的实用性；推荐采用运行期设计洪水及汛控水位指导水库调度运行，建议进一步加强水库运行期设计洪水计算理论和方法研究。