Selective Solid Phase Extraction for Separation and Preconcentration of Palladium from Gold Ore and Anode Slime after Complexation with a N4O2 Mixed Donor Ligand Derivative

A selective and sensitive method for the preconcentration, separation, and determination of palladium with flame atomic absorption spectrometry using 4,15‐bis[(4‐methylphenyl)sulfonyl]‐20,21‐dinitro‐2,3,4,5,6,7,9,10,12,13,14,15,16,17‐tetradecahydro‐8,11‐ethano‐1,18,4,8,11,15‐benzodioxa tetraaza cycloicosine (TNACIN) on XAD‐2010 was developed. TNACIN–Pd(II) complex formed acidic aqueous solution (0.075–0.100 M HNO₃) was accumulated on XAD‐2010 and then eluted with 1 M HCl in acetone. The effects of some analytical parameters including pH, TNACIN amount, sample volume, eluent type, and concentration, sample flow rate and matrix ions were studied for optimization of the method. Detection limit and precision were calculated for Pd(II). This method was also verified with CRM and internal standard, and satisfactory results were obtained.     

Metal Ion Extraction with Bipyridine Derivatives as Chelating Ligands in Supercritical Carbon Dioxide

Three fluorinated bipyridine ligands have been designed and synthesized as chelating agents for the extraction of metal ions in supercritical CO₂ (sc‐CO₂). The ligand solubilities in sc‐CO₂ were investigated at different temperatures and pressures, and the measured data have been correlated using a semiempirical model. The calculated results showed satisfactory agreement with the experimental data. Based on these data, metal ion extraction with the three compounds as chelating agents in sc‐CO₂ was performed from spiked filter paper, whereby ligand 1 showed the highest extraction efficiency, especially for Ni²⁺ and Cu²⁺. The extraction constants, K_ex, of the three chelating ligands were seen to increase with increasing extraction efficiency for the same metal ion in the same extraction system.     

Silicate‐oxide mineral chemistry of mafic–ultramafic rocks as an indicator of the roots of an island arc: The Chilas Complex,Kohistan (Pakistan)

The Chilas Complex is a major lower crustal component of the Cretaceous Kohistan island arc and one of the largest exposed slices of arc magma chamber in the world. Covering more than 8000 km², it reaches a current tectonic width of around 40 km. It was emplaced at 85 Ma during rifting of the arc soon after the collision of the arc with the Karakoram plate. Over 85% of the Complex comprises homogeneous, olivine‐free gabbronorite and subordinate orthopyroxene–quartz diorite association (MGNA), which contains bodies of up to 30 km² of ultramafic–mafic–anorthositic association (UMAA) rocks. Primary cumulate textures, igneous layering, and sedimentary structures are well preserved in layered parts of the UMAA in spite of pervasive granulite facies metamorphism. Mineral analyses show that the UMAA is characterized by more magnesian and more aluminous pyroxene and more calcic plagioclase than those in the MGNA. High modal abundances of orthopyroxene, magnetite and ilmenite (in MGNA), general Mg–Fe–Al spatial variations, and an MFA plot of whole‐rock analyses suggest a calc‐alkaline origin for the Complex. Projection of the pyroxene compositions on the Wo–En–Fs face is akin to those of pyroxenes from island arcs gabbros. The presence of highly calcic plagioclase and hornblende in UMAA is indicative of hydrous parental arc magma. The complex may be a product of two‐stage partial melting of a rising mantle diaper. The MGNA rocks represent the earlier phase melting, whereas the UMAA magma resulted from the melting of the same source depleted by the extraction of the earlier melt phase. Some of the massive peridotites in the UMAA may either be cumulates or represent metasomatized and remobilized upper mantle. The Chilas Complex shows similarities with many other (supra)subduction‐related mafic–ultramafic complexes worldwide.     

The Godzilla Megamullion,the largest oceanic core complex on the earth: a historical review

The Godzilla Megamullion is the largest known oceanic core complex (OCC) on the Earth, located in the Parece Vela Basin in the Philippine Sea. In this article, the history of Godzilla Megamullion study is reviewed for the first time, dividing it into three major phases: (i) the early studies done before Japan's extended continental shelf survey program; (ii) the studies during Japan's extended continental shelf survey program that discovered the OCC; and (iii) the studies by the post‐discovery cruises. The early studies included an interpretation of US nautical chart of the southwestern Pacific and the site surveys for Deep Sea Drilling Project cruises (DSDP Legs 6, 31 and 59). The early studies recognized the presence of the Parece Vela Rift, the extinct spreading axis of the Parece Vela Basin, and established the currently accepted model that the Philippine Sea evolved with eastward progression of backarc spreading and arc migration. The modern understanding of the Parece Vela Basin comes from Japan's extended continental shelf survey program. The program revealed the ultramafic petrology as well as a two‐stage evolution model of the basin. Following these results, the discovery of the Godzilla Megamullion was made in 2001. The studies by the post‐discovery cruises further revealed important characteristics of the OCC, such as the presence of abundant plagioclase‐bearing peridotite and the systematic temporal changes in both deformation microstructures and composition of plagioclase and amphibole in gabbroic mylonites and ultramylonites. Zircon U–Pb ages of gabboric and leucocratic rocks indicate that the terminal phase of Parece Vela Basin spreading was with a significant decline in spreading rate and asymmetry accompanying formation of the Godzilla Megamullion. The estimated denudation rate of the OCC was approximately 2.5 cm/yr; significantly slower than the previous estimate based on poorly constrained magnetic data.     

Genetic algorithm for fitting a mixed Bingham distribution to 3D orientations: a tool for the statistical and paleostress analyses of fracture orientations

The clustering of fracture orientations is important for tectonic studies and for geotechnical engineering. In this study, a real‐coded genetic algorithm was adopted to fitting a mixed Bingham distribution to orientation data by maximizing the log‐likelihood function of the distribution. The maximization is a difficult problem, because the function has multimodality and singularity. It was found that the algorithm was effective for this problem. Given the orientations of dilational fractures, the present method determines not only the stress axes and stress ratio of each of the fracture groups but also the maximum non‐dimensionalized fluid pressure at the time of their formation. In addition, the software calculates the 95 % error ellipses of the concentration axes. The present method found that the orientations of ore veins of the Akenobe Mine, SW Japan, should be partitioned into three clusters. It is shown that two of the groups had distinctive Zn and Sn contents, and that the ore fluids had overpressures only slightly greater than the minimum principal stress at the time of the deposition of Zn‐ and Sn‐rich veins.     

A new Lower Triassic (Induan) Jerus Limestone locality in northwest Pahang,Peninsular Malaysia: Conodont fauna,depositional and tectonic settings

Limestones exposed north of Raub, Pahang, Malaysia, and sandwiched between the Bentong‐Raub Suture Zone and the westernmost margin of the Sukhothai Arc terrane, yield a late Dienerian (late Induan) conodont fauna. The co‐occurrence of Neospathodus dieneri Sweet (morphotypes 1, 2 and 3) and Neospathodus pakistanensis Sweet represents the Neospathodus dieneri morphotype 3 sub‐zone of the Neospathodus dieneri Zone. The sampled limestones are interpreted as the northwards extension of the Jerus Limestone which crops out near Cheroh and Jerus villages, significantly extending the known outcrop of the Jerus Limestone northwards. The Jerus Limestone is interpreted as hemipelagic and formed in a foredeep or forearc setting on top of the accretionary complex formed by eastwards subduction of the Palaeo‐Tethys during the Lower to Middle Triassic.     

Seismic fragility of traction elevators

Second‐generation performance‐based earthquake engineering (PBEE‐2) requires a library of component fragility functions to estimate probabilistic damage to a wide variety of building components. The present work draws on a large body of (mostly) post‐earthquake reconnaissance and (some) post‐earthquake survey observations of traction elevators to create fragility functions useful in PBEE‐2. Two surveys provide detailed observations of 115 representative elevators at 12 hospitals shaken in the 1989 Loma Prieta and 1994 Northridge earthquakes and selected without regard to or foreknowledge of damage. Of these, 55 failed and 60 did not. Approximately half were installed after an important code change of 1972, so one can distinguish the performance of pre‐1973 and post‐1973 elevator construction. They experienced a range of strong motion: 22 with peak ground acceleration (PGA) < 0.25 g, 93 with 0.25 g < PGA < 0.85 g. The hospitals had elevator failure rates as low as 0% and as high as 100%. A third survey describes damage qualitatively for six sites with PGA ≤ 0.25 and per‐site failure rates of 0% to perhaps 30%. Fragility functions are offered where the damage state is the loss of functionality of the elevator. The elevators in these surveys exhibit a median capacity of PGA ≈ 0.35 g with a logarithmic standard deviation of 0.40. Capacity is modestly sensitive to whether the elevator was installed before or after 1973. Using building‐specific intensity measures such as S_a(T₁) does not improve the fragility functions. Copyright © 2015 John Wiley & Sons, Ltd.     

Isolated Archosaur teeth from the green sandstone capping the Coralline Limestone (Bagh Group) of the Narmada valley: Evidence for the presence of pre‐Late to Late Maastrichtian abelisaurids in India

Recent field prospecting in the Cretaceous sequences of the lower Narmada valley has led to the discovery of three isolated archosaur teeth from the upper part of marine Cretaceous rocks of the Bagh Group. The specimens were recovered by surface prospecting from an oyster‐bearing green sandstone bed occurring at the top of the Coralline Limestone (Coniacian) from a site near Phutibawri village, Dhar District, Madhya Pradesh, India. Of the three teeth recovered from this horizon, two are identified with abelisaurid dinosaurs and the third one with an indeterminate crocodile. The abelisaurid teeth conform to the premaxillary and maxillary tooth morphology of Majungasaurus and Indosuchus. Earlier reports of abelisaurid dinosaurs from India are from the Upper Cretaceous (Maastrichtian) Lameta Group of Jabalpur, Pisdura (Central India) and Balasinor (Western India) and Upper Cretaceous (Late Maastrichtian) Kallamedu Formation (South India). As no associated age diagnostic fossils are found, the specimens described here are considered to represent pre‐Late to Late Maastrichtian age based on the known ages of the underlying and overlying formations. The new finds, therefore, document stratigraphically the oldest occurrence of abelisaurid dinosaurs known from the Indian subcontinent.     

基于CryoSat-2的东南极PANDA断面考察沿线DEM制作及精度分析

基于卫星测高数据,国际上先后发布了ICESat DEM、Bamber DEM等全南极DEM.相对于传统高度计,大轨道倾角、长重访周期的设计使CryoSat-2具有更大的数据覆盖范围以及更加密集的轨道覆盖;同时,SARIn模式的启用也提高了CryoSat-2对于南极边缘区域的监测能力.针对利用CryoSat-2数据提取DEM问题,对CroySat-2的轨迹覆盖特征、数据滤波方法、最优内插参数选取以及DEM精度验证等方面进行了探讨,并利用克里金插值法生成了东南极PANDA断面考察沿线1 km分辨率的DEM.结果表明：通过与ICESat数据对比,发现PANDA断面考察沿线DEM整体高程精度约为（1.57±3.30）m;但是,局部区域高程精度分析表明,DEM精度具有不均一性,随着坡度的增加DEM高程精度逐渐下降,高程稳定性也同时下降.