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591.
Abstract Fluid inclusion studies of rocks from the late Archaean amphibolite-facies to granulite-facies transition zone of southern India provide support for the hypothesis that CO2,-rich H2O-poor fluids were a major factor in the origin of the high-grade terrain. Charnockites, closely associated leucogranites and quartzo-feldspathic veins contain vast numbers of large CO2-rich inclusions in planar arrays in quartz and feldspar, whereas amphibole-bearing gray gneisses of essentially the same compositions as adjacent charnockites in mixed-facies quarries contain no large fluid inclusions. Inclusions in the northernmost incipient charnockites, as at Kabbal, Karnataka, occasionally contain about 25 mol. % of immiscible H2O lining cavity walls, whereas inclusions from the charnockite massif terrane farther south do not have visibile H2O Microthermometry of CO2 inclusions shows that miscible CH4 and N2 must be small, probably less than 10mol.%combined. Densities of CO2 increase steadily from north to south across the transitional terrane. Entrapment pressures calculated from the CO2 equation of state range from 5 kbar in the north to 7.5 kbar in the south at the mineralogically inferred average metamorphic temperature of 750°C, in quantitative agreement with mineralogic geobarometry. This agreement leads to the inference that the fluid inclusions were trapped at or near peak metamorphic conditions. Calculations on the stability of the charnockite assemblage biotite-orthopyroxene-K-feldspar-quartz show that an associated fluid phase must have less than 0.35 H2O activity at the inferred P and T conditions, which agrees with the petrographic observations. High TiO2 content of biotite stabilizes it to lower H2O activities, and the steady increase of biotite TiO2 southward in the area suggests progressive decrease of aH2O with increasing grade. Oxygen fugacities calculated from orthopyroxene-magnetite-quartz are considerably higher than the graphite CO2-O2 buffer, which explains the absence of graphite in the charnockites. The present study quantifies the nature of the vapours in the southern India granulite metamorphism. It remains to be determined whether CO2-flushing of the crust can, by itself, create large terranes of largeion lithophile-depleted granulites, or whether removal of H2O-bearing anatectic melts is essential. 相似文献
592.
When all balloon-borne measurements of NO2 in the stratosphere are reviewed, the profiles show a wide spread. Measurements of the total amount in a vertical column suggest that variability should be low when only profiles measured at mid-latitudes close to equinox are selected. With this selection, the standard deviation of the profiles measured by each technique is often less than ±20%, but the mean profiles measured by each technique differ by up to a factor 2. Despite the profiles not being measured simultaneously, these differences are identical to those revealed by the simultaneous measurements of the Balloon Intercomparison Campaigns of 1982 and 1983-a comparison can be made from the historic data alone. This suggests that measurements of other gases should be similarly reviewed and appropriate selection criteria be found that reduces the standard deviations of the measurements by any one technique. The techniques can then be intercompared without new simultaneous flights. 相似文献
593.
黄铁矿与沥青铀矿的共生条件及在沥青铀矿形成过程中所起作用的实验研究 总被引:5,自引:0,他引:5
高价铁与高价铀混合溶液在还原场中形成了共生的黄铁矿与沥青铀矿,该过程必须在弱酸性-中性-碱性介质中进行,其中在弱酸性至中性介质中易形成大的黄铁矿单晶。高价铀溶液流经黄铁矿矿区时,若在高温高压条件下,有新生的黄铁矿或白铁矿与沥青铀矿共生。黄铁矿还原六价铀形成沥青铀矿时,起还原作用的是二价硫。赤铁矿常与沥青铀矿共生,但它们是热液演化过程中不同阶段的产物,赤铁矿形成于体系氧逸度高的氧化环境,沥青铀矿形成于体系氧逸度低的还原环境,赤铁矿形成于沥青铀矿之前。 相似文献
594.
595.
新疆索尔库都克类夕卡岩铜(钼)矿床地质特征及矿床成因 总被引:2,自引:1,他引:2
索尔库都克矿床是近年来新疆境内探明的中型铜(钼)矿床。对其成矿地质环境、矿床地质特征、夕卡岩其分带的研究表明,该矿床之夕卡岩与Д.C.柯尔仁斯基所划分的类夕卡岩相类似。该夕卡岩是由凝灰砂岩、安山玢岩等变质形成的。流体包裹体和稳定同位素的研究表明,该矿床是我国特殊的层状夕卡岩矿床,与接触交代夕卡岩矿床明显不同。 相似文献
596.
597.
金刚石生长阶段所捕虏的不纯净组分,能够提供大量地幔流体的信息。本文从金刚石的成因研究,表征地幔流体的固体包裹体、流体包裹体及流体的制药因素等方面讨论了金刚石不纯净组分与地幔流体的关系。 相似文献
598.
油藏地球化学的基础与展望 总被引:6,自引:0,他引:6
在系统综述国内外油藏地球化学研究现状和研究方法的基础上,着重介绍了其4个研究领域及地质意义,即:油藏地球化学描述、油藏原油混合作用原理、油藏中的有机隔层-沥青垫、油藏内有机-无机相互作用及储层润湿的改变。 相似文献
599.
Sheng Jifu Zhang Dequan Li YanInstitute of Mineral Deposits Chinese Academy of Geological Sciences Beijing Jiang M inxi 《《地质学报》英文版》1995,69(3):289-302
Physicochemical parameters of mineralization such as temperature, pressure, salinity, density, composition and boiling of ore fluids as well as pH, Eh, fo2 and reducing parameter in theprocess of mineralization of major ore deposits in the study district have been obtained by the authors through systematic observation and determination of characteristics and phase changes of fluid inclusions at different temperatures and analysis of gaseous and liquid phase compositions of the inclusions, thus providing a scientific basis for the division of mineralization-alteration stages, types of mineral deposits and minerogenetic series and the deepening of the knowledge about the ore-forming processes and mechanisms of mineral deposits. It is indicated that the deposits of the same type have similar fluid inclusion geochemical features and physicochemical parameters though they belong to different minerogenetic series, while the compositions of inclusions are not conditioned by deposit types but closely related to 相似文献
600.