论煤地质学与碳中和

煤基碳排放构成了中国碳排放总量中最重要的部分,做好煤基碳减排和煤炭高效洁净低碳化利用是实现“碳中和”国家目标的重要途径,碳中和背景下的煤地质学发展值得关注。系统评述与碳中和相关的煤地质学研究领域,分析煤地质学在碳中和研究与工程实践中的作用和应用前景,探讨碳中和背景下煤地质学的重要发展方向。取得以下认识：推进清洁煤地质研究、服务煤的高效洁净化燃烧,勘探开发煤系天然气低碳燃料、优化一次能源结构和化石能源结构,开展煤化工资源勘查与开发地质保障研究、推动煤炭的低碳能源转化和新型煤化工产业发展,深化瓦斯地质研究、提高煤矿瓦斯（井下）抽采率、控制煤矿瓦斯的大气排放和泄漏,研究煤层甲烷天然逸散和煤层自燃排放、控制煤层露头的天然排放,发展煤层CO₂地质封存与煤层气强化开发（CO₂-ECBM）技术、推动碳捕获、利用与封存（CCUS）技术发展及其在火力电厂烟气碳减排中的商业化应用,研究煤炭勘查企业的碳足迹、实现企业净零排放,是与煤地质学紧密相关的碳减排技术路径;其中煤层甲烷与煤系气高效勘探开发、深部煤层CO₂-ECBM、煤层露头气体逸散与自燃发火控制、洁净煤地质与煤炭精细勘查是碳中和背景下煤地质学优先发展的重要领域。     

上地幔超高压流体的金刚石压砧实验研究

地球深部流体主要是NaCl-H2O溶液,越到地球深部,它赋存的温度、压力越高,性质状态也不断变化,反之,亦然。当NaCl-H2O流体进入和脱离(上升过程)超临界状态时,其性质会发生截然不同的变化,影响着各种地质过程。使用金刚石压砧在高温高压下原位观测流体的实验,用谱学方法,结合同步辐射光源技术,成为定量化研究地球深部高温超高压流体的有效方法。作者使用同步辐射光源的红外谱研究了10GPa下的NaCl-H2O溶液;在地球化学动力学实验室研究了3GPa,650℃下的NaCl-H2O溶液红外谱,此测量方法可以提供温度压力和体积等数据,能研究其状态。NaCl-H2O溶液红外谱表明水分子主要振动谱受压力和温度影响是不同的。压力增加促使水分子主要振动谱向低波数变化。但是温度增加的效应相反。常温高压下水被压缩,结晶向紧密堆积变化。高温高压下的水有气、液、固和超临界流体各相。水分子间的氢键在近临界态开始减弱,氢键网络被破坏。     

酸性流体作用下斜长石的稳定性

通过紫外分光光度计分析和扫描电镜观察,开展不同温度下酸性流体与斜长石相互作用实验得出：①在低温条件下斜长石较稳定,以溶解为主;在高温条件下,斜长石不稳定,以溶蚀、溶解为主;随反应温度升高,质量损失增大。②斜长石沿解理形成条带状溶孔,沿表面形成粒内溶孔。③在160℃和190℃条件下,形成新生高岭石沉淀,温度升高高岭石晶形变好,实验反应强度增大。④随反应温度升高, K＋、 SiO2和矿化度浓度升高。     

H2O-CH4-H2-CO2-CO-O2在高温、高压和高密度条件下的状态方程

为了计算高温，高压和高密度流体的热力学性质，提出了一个具有19个参数的维里型状态方程，其中参数与温度间的函数关系采用由Sutherland位能函数导出的维里系数近似式。除临界点附近以外，在已报道的pVT数据所覆盖的大部分超临界区域内，该方程均可适用。用该方程对H2O，CH4，H2，CO2，CO和O2等流体pVT关系的计算结果令人满意，其中pVT上限分别为：91-610GPa,1.6-11.0cm^3/mol,4000-5000K。计算体积的平均偏 小于0．8％，最大偏差小于5．4％。     

Constraints on the application of carbon isotope thermometry in high- to ultrahigh-temperature metamorphic terranes

Nine marble horizons from the granulite facies terrane of southern India were examined in detail for stable carbon and oxygen isotopes in calcite and carbon isotopes in graphite. The marbles in Trivandrum Block show coupled lowering of δ¹³C and δ¹⁸O values in calcite and heterogeneous single crystal δ¹³C values (? 1 to ? 10‰) for graphite indicating varying carbon isotope fractionation between calcite and graphite, despite the granulite facies regional metamorphic conditions. The stable isotope patterns suggest alteration of δ¹³C and δ¹⁸O values in marbles by infiltration of low δ¹³C–δ¹⁸O‐bearing fluids, the extent of alteration being a direct function of the fluid‐rock ratio. The carbon isotope zonation preserved in graphite suggests that the graphite crystals precipitated/recrystallized in the presence of an externally derived CO₂‐rich fluid, and that the infiltration had occurred under high temperature and low f_O2 conditions during metamorphism. The onset of graphite precipitation resulted in a depletion of the carbon isotope values of the remaining fluid+calcite carbon reservoir, following a Rayleigh‐type distillation process within fluid‐rich pockets/pathways in marbles resulting in the observed zonation. The results suggest that calcite–graphite thermometry cannot be applied in marbles that are affected by external carbonic fluid infiltration. However, marble horizons in the Madurai Block, where the effect of fluid infiltration is not detected, record clear imprints of ultrahigh temperature metamorphism (800–1000 °C), with fractionations reaching <2‰. Zonation studies on graphite show a nominal rimward lowering δ¹³C on the order of 1 to 2‰. The zonation carries the imprint of fluid deficient/absent UHT metamorphism. Commonly, calculated core temperatures are > 1000 °C and would be consistent with UHT metamorphism.     

核幔耦合对地球自由核章动的激发影响

地球自由核章动（FCN）是地幔与液核相互作用的重要动力学现象,其激发机制涉及地表流体层、地幔和地核等圈层之间的耦合,此前研究多利用地表流体层角动量数据单独研究其对FCN的激发,对核幔耦合的影响考虑不足.本文基于角动量守恒理论分析了核幔耦合对FCN周期及振幅的影响,并结合多个大气及海洋角动量函数时间序列首次估算了核幔耦合在FCN激发过程中的贡献.结果表明核幔耦合对FCN周期产生的固定和时变影响对FCN激发的作用均不可忽视,尤其时变影响可达几十个微角秒,对于进一步解释FCN时变特征非常重要;核幔耦合对FCN振幅的直接影响是地表流体层的激发与实测FCN不相符的主要原因,黏滞、电磁和地形等耗散耦合的存在对地表流体的激发振幅有67%左右的减弱效果.

     

CE-QUAL-W2模型在福建山仔水库的应用

利用二维横向平均模型CE-QUAL-W2对山仔水库进行水力学和水质模拟,运用半年野外采样监测和室内实验分析数据校正模型主要参数并进行验证.选取2006年4月7日至6月7日的模型输出模拟结果,进一步运用李祚泳修正的营养状态指数法结合层次分析法对山仔水库出水水质进行富营养化评价,评价结果表明:山仔水库存在富营养化状况,其中5月12日营养状态指数最高,接近80;第一次大规模水华爆发从4月29日持续到6月初.通过设定三种情景(原始流量、降低水位、增加出流量)进行模拟分析表明,降低水位以及增加出流量都有利于改善对山仔水库下游取水口水质.     

Tectono–Thermal Evolution, Hydrocarbon Filling and Accumulation Phases of the Hari Sag, in the Yingen–Ejinaqi Basin, Inner Mongolia, Northern China

This work restored the erosion thickness of the top surface of each Cretaceous formations penetrated by the typical well in the Hari sag, and simulated the subsidence burial history of this well with software BasinMod. It is firstly pointed out that the tectonic subsidence evolution of the Hari sag since the Cretaceous can be divided into four phases: initial subsidence phase, rapid subsidence phase,uplift and erosion phase, and stable slow subsidence phase. A detailed reconstruction of the tectonothermal evolution and hydrocarbon generation histories of typical well was undertaken using the EASY R_0% model, which is constrained by vitrinite reflectance(R_0) and homogenization temperatures of fluid inclusions. In the rapid subsidence phase, the peak period of hydrocarbon generation was reached at c.a.105.59 Ma with the increasing thermal evolution degree. A concomitant rapid increase in paleotemperatures occurred and reached a maximum geothermal gradient of about 43-45℃/km. The main hydrocarbon generation period ensued around 105.59-80.00 Ma and the greatest buried depth of the Hari sag was reached at c.a. 80.00 Ma, when the maximum paleo-temperature was over 180℃.Subsequently, the sag entered an uplift and erosion phase followed by a stable slow subsidence phase during which the temperature gradient, thermal evolution, and hydrocarbon generation decreased gradually. The hydrocarbon accumulation period was discussed based on homogenization temperatures of inclusions and it is believed that two periods of rapid hydrocarbon accumulation events occurred during the Cretaceous rapid subsidence phase. The first accumulation period observed in the Bayingebi Formation(K_1 b) occurred primarily around 105.59-103.50 Ma with temperatures of 125-150℃. The second accumulation period observed in the Suhongtu Formation(K_1 s) occurred primarily around84.00-80.00 Ma with temperatures of 120-130℃. The second is the major accumulation period, and the accumulation mainly occurred in the Late Cretaceous. The hydrocarbon accumulation process was comprehensively controlled by tectono-thermal evolution and hydrocarbon generation history. During the rapid subsidence phase, the paleo temperature and geothermal gradient increased rapidly and resulted in increasing thermal evolution extending into the peak period of hydrocarbon generation,which is the key reason for hydrocarbon filling and accumulation.     

DSQ水管仪和SSQ-2I水平摆效能对比研究

SSQ-2I型水平摆仪器和DSQ水管仪同属倾斜类前兆仪器,两者观测原理不同,但观测物理量一致.相对于水管仪而言,SSQ-2I型水平摆属于新型仪器,有关其运行效能的评价很少.延庆地震台从2007年开始两种仪器同场地观测,通过年变幅度、滤波残差、周期分析、Venedikov调和分析、相关性分析、抗干扰能力等角度,对两种仪器...     

地下流体中强震源兆、场兆和强震远兆特征及其物理成因

初步分析了乌鲁木齐9、10号泉地下流体中强震源兆、场兆及强震远兆特征。结果表明,中强震源兆具体表现为震前1~ 2年观测点的绝大多数主测项出现同步性高值异常,临震前可能出现转折或反向,震后恢复正常;绝大多数中强震场兆则表现为观测点仅有部分测项出现短期异常变化;而强震场兆则表现为观测点少数映震性能较好的几个测项出现同步性较好的中期前兆异常;强震(群)远兆则主要表现为个别映震较好的测项出现前兆异常。并对震兆形成的原因进行了初步探讨。