激发态质子转移分子2-(2'-羟基苯基)苯并噻唑溶液的全光开关效应

研究了激发态质子转移(ESPT)分子2-(2'-羟基苯基)苯并噻唑(HBT)在不同极性溶剂中的光开关行为,探讨了溶剂极性对HBT分子光开光效应的影响.揭示了光开关脉冲信号的形成原因,建立了基于光诱导HBT分子激发态非线性折射效应的皮秒全光开关的理论模型.根据对时间响应函数的理论计算和实验结果分析,确定了光开关脉冲信号下降前沿和上升后沿的形成机理以及影响因素,并提出了增强光开关信号下降前沿的关断深度,提升上升后沿的恢复速度的有效途径和方法.本文工作为制成皮秒量级关断,微秒甚至纳秒量级重新打开的快速全光开关器     

相变存储材料Ge1Sb2Te4和Ge2Sb2Te5薄膜的结构和电学特性研究

采用射频磁控溅射方法制备了两种用于相变存储器的Ge₁Sb₂Te₄和Ge₂Sb₂Te₅相变薄膜材料,对其结构、电学输运性质和恒温下电阻随时间的变化关系进行了比较和分析.X射线衍射(XRD)和原子力显微镜(AFM)的结果表明:随着退火温度的升高,Ge₁Sb₂Te₄薄膜逐步晶化,由非晶态转变为多晶态,表面出现均匀的、     

氧化钒晶体的半导体至金属相变的理论研究

本文利用第一性原理方法研究了金红石相和单斜相VO₂晶体的电子结构和热力学性质.在计算中采用局域密度近似结合Hubbard U模型(LDA+U)描述电子的局域强关联效应,同时也利用微扰密度泛函方法计算了两种相结构的声子谱.计算结果表明V原子3d电子轨道中x²-y²轨道能级分裂决定了VO₂晶体在不同相结构下的金属和绝缘体特性.零温状态方程计算揭示了在68 GPa时可以发生从单斜结构     

Spectroscopic ellipsometric study of the optical properties of Ag2O film prepared by direct-current magnetron reactive sputtering

The Ag₂O film, as-deposited by direct-current magnetron reactive sputtering at a substrate temperature of 150 °C, clearly shows a preferential orientation (111), and is capable of lowering the threshold value of the thermal decomposition temperature to about 200 °C, which is helpful to its application in optical and magneto-optical storage. This paper fits its optical constants in terms of a general oscillator model by using measured ellipsometric parameters. The fitted oscillator energy 2.487 eV is close to the optical direct interband transition energy value of the Ag₂O film determined by Tauc equation; whereas, the fitted oscillator energy 4.249 eV is far from the fitted plasma oscillator energy 4.756 eV by single-oscillator energy. The photoluminescence spectrum centred at about 2.31 eV indicates a direct-energy gap photoluminescence mechanism of the Ag₂O film.     

Structurally controlled hydrothermal dolomites in Albian carbonates of the Asón valley,Basque Cantabrian Basin,Northern Spain

Shallow marine carbonate sedimentation dominated during the Albian in the western part of the Basque Cantabrian Basin in Northern Spain, forming the large Ramales Platform. This platform originated on a less subsiding tectonic block facing deeper and more subsiding areas to the south and east, which were created by tectonic activity in the Basin. Fracture-related hydrothermal dolomites hosted in these Albian carbonates are well exposed in the Asón valley area. Mapping in the studied area revealed several dolomite bodies related to main faults that cut the stratification almost at right angles. The bodies show a vertical development along fault-strike up to 900 m thick from which kilometre-scale branches expand following the stratification. Dolomitization is pervasive and independent of the limestone facies. Main dolomite facies are fine replacive, sucrosic and saddle. Petrography, C, O and Sr isotopes and fluid-inclusion analysis support a polyphase hydrothermal dolomitization at fluid temperatures between 75 °C and 240 °C and highly variable salinity of up to 22 wt.% NaCl. Fine dolomite replaced limestone first and then, sucrosic and saddle dolomites replaced part of the first dolomite and cemented newly created fracture porosity together with different calcite cements. Zebra dolomites and hydroclastic breccias are products of this later stage. Burial analysis of the host rock supports maximum burial temperatures of 80 °C and intense tectonic activity from the Albian to Turonian with a latest Albian peak subsidence. Albian stretching of the crust and subsequent ascent of the isotherms in the area is suggested to have produced sufficient heat to the dolomitizing fluids. The structural analysis indicates a strong transtensional tectonic activity in the studied area during Albian to Turonian time with the creation of an overstep between W–E trending and N–S trending faults. Fluids moved from subsiding areas to fractured uplifted parts of the Ramales Platform, enhanced by diapiric activity.     

Balancing deformation in NW Borneo: Quantifying plate-scale vs. gravitational tectonics in a delta and deepwater fold-thrust belt system

Recent GPS measurements demonstrate that NW Borneo undergoes 4–6 mm of plate-scale shortening a year, which is not accommodated by plate-scale structures. The only geological structure in NW Borneo described to accommodate on-going shortening is the Baram Delta System located on the outer shelf to basin floor. Delta toe fold-thrust belts are commonly thought to be caused by margin-normal compressional stresses generated by margin-parallel upslope gravitational extension.     

秋季东海和南黄海表层海水CO_2体系各参数分布及海-气界面通量

根据2007年11月在东海和南黄海海域表层海水测得的TCO2和TA数据,计算了表层海水pCO2,结合现场环境对表层海水CO2体系各参数的分布进行了讨论,探讨了pCO2与海水温度及叶绿素的相关性,利用Wanninkhof(1992)提出的通量模式并采用加权平均法估算了整个调查海域的海-气CO2的净通量。结果表明:观测海域表层海水CO2系统各参量的分布呈明显的不均匀性,在水团的混合处往往是各参量的高值或低值中心。由相关性分析可知,pCO2的分布主要受海水温度的影响,生物活动的影响较弱。受秋季较大风速的影响,调查海域表现为强的CO2源,秋季可向大气释放CO2约为556×104tC。     

“MgO/AC”复合材料对水溶液中Cu~(2+)和Cr(Ⅵ)的吸附性能研究

用造纸草浆黑液和氯化镁为原料制得氧化镁/活性炭("MgO/AC")复合材料,分别测定了该复合材料对水溶液中Cu2+与Cr(Ⅵ)的脱除性能。Cu2+的吸附随pH值的升高而增大,pH=3时基本达到平衡;在实验考察的pH范围内(1~8),Cr(Ⅵ)的吸附呈单调递减趋势。动力学拟合结果表明,"MgO/AC"复合材料对Cu2+和Cr(Ⅵ)的吸附过程均符合伪二级动力学方程;两过程的吸附速率均随吸附温度的升高而增大,表现为吸热吸附;吸附活化能Ea分别为50.19,51.42 kJ.mol-1;"MgO/AC"复合材料对Cu2+的吸附优于对Cr(Ⅵ)的吸附。Cu2+在"MgO/AC"复合材料上的吸附过程用Langmuir模型描述更为合适,在293~323 K范围内,Cu2+的饱和吸附量为19.46~90.91 mg.g-1;Cr(Ⅵ)的吸附过程则更符合Freundlich模型。     

性类固醇激素及其受体在半滑舌鳎性腺分化发育过程中的表达与生理功能

首次用17β-雌二醇(E_2)及其受体(ERα)、睾酮受体(AR)的多克隆抗体在半滑舌鳎(Cynoglossus semilaevisG(u|¨)nther)性腺分化发育过程中进行免疫细胞化学定位研究。结果表明:在半滑舌鳎原始性腺中已有E_2、ERα和AR的分布和表达;卵原细胞、初级卵母细胞、精原细胞、初级精母细胞、次级精母细胞对E_2及ERα、AR抗体均呈现不同程度的阳性反应,在精细胞和精子中对E_2和ERα呈免疫阴性反应,而AR则一直保持较强表达,揭示了半滑舌鳎性腺中类固醇激素可能通过旁分泌调控机制刺激卵子和精子发育和成熟。性类固醇激素及其受体免疫阳性物定位在生殖细胞的胞质、胞膜和核膜等广泛部位并有表达,在性腺分化和不同发育时期的表达强度有所不同,表明其在性腺分化发育过程各阶段所起生理功能不同。这些结果为证明性类固醇激素及受体参与调节半滑舌鳎性腺分化发育提供了重要形态学新证据。     

Experimenta l study on ultrasonic propagation in water-based bentonite slurry

Drilling fluid is a common flushingmedium used in pile foundation, geological drilling and petroleum drilling. Study on ultrasonic propagation properties in drilling fluid is of vital importance, not only for developing equipments to non-contact measuring concrete casting level for bored pile, but also for developing equipments considering drilling fluid as signal channel. The existence of clay particlesmakes the ultrasonic propagation and attenuation in drilling fluid much different from pure water. In order to know the relation among ultrasound frequency, slurry density and depth, a series of laboratory experiments about ultrasound propagation in water-based bentonite slurry were finished. Wavelet method was adopted to process the gained original waves of ultrasonic propagation in slurry, so we knew the velocity and attenuation coefficient of ultrasound propagated in different drilling fluids with different density. The first group experiments shows that with density of drilling fluid increase, ultrasonic velocity will decrease but attenuation coefficient will increase if ultrasonic frequency keep constant. The second group experiments shows that the power of ultrasound will intensify in small bore hole, the attenuation coefficient ismuch smaller than theoretical value.