辽宁北部秀水盆地义县组烃源岩生物标志化合物特征及意义——以辽法D1井为例

正辽宁北部秀水盆地位于华北板块北缘陆缘活动带之上,地质构造复杂。秀水盆地是在海西褶皱基底和前寒武纪基底上发育起来的中生代断陷型盆地,面积710 km~2,是前人油气调查工作空白区。秀水盆地早白垩世义县组上部发育优质烃源岩。部署在秀水盆地中部的辽法D1井义县组沉积地层厚度为280 m,暗色泥岩厚度为128 m。本文通过对辽法D1井义县组泥岩样品分析,采用气相色谱、气相色谱—质谱技术,剖析秀水盆地义县组烃源岩     

Geoheritage in New South Wales — a reassessment of sites from the register of the national estate

The geology of New South Wales is diverse, spanning Paleoproterozoic to modern materials and their various associated landforms and soils. In recognition of the intrinsic geological value of the State, around 150 geological sites were nominated to the now defunct Register of the National Estate, with the objective of geoconservation. However, these sites did not encompass the full range of geology of New South Wales; neither did they offer registered sites any protection. Analysis shows that the types of sites nominated were biased towards sedimentary and igneous rocks, and fossils, with under representation of metamorphic rocks, site-restricted soils, geomorphology and hydrogeology. To test the utility of the Brocx and Semeniuk ‘Geoheritage Toolkit’, a subset of the Register listings was re-examined, focusing on the Sydney Basin. Within the Sydney Basin, 59 nominated sites were reassessed using various geoheritage categories and the hierarchical framework of scale of the Toolkit. Four sites within the Sydney Basin were found to have features of international to national significance, and to have national historical value. These sites will need to be renominated for State and National listing. Clearly, to ensure that University teaching sites, as well as stratigraphic and lithologic type sections and reference sites, reflecting the geodiversity of New South Wales are conserved for future generations, a greater number of sites need to be put forward for heritage listing.     

Deformation and mineralisation in the Scotty Creek Basin,Agnew district,Eastern Goldfields,Western Australia: evidence for D1- and D3-related gold mineralisation

Gold deposits in the Agnew district display markedly different structural styles. The Waroonga and Songvang deposits are hosted in layer-parallel extensional shears formed under highly ductile conditions. In contrast, the New Holland–Genesis deposits are shallow-dipping quartz-filled brittle fractures and breccia zones that cut across the tightly folded bedding and formed during east–west compression. It is difficult to attribute their formation to a single compressive event. The Waroonga and Songvang deposits formed during D₁ extension, uplift and exhumation of the Agnew granitic complex and formation of the Scotty Creek Basin at ca 2670–2660?Ma. The New Holland–Genesis deposits formed during east–west D₃ compression at about ca 2650–2630?Ma. An S₁ foliation wraps around the Agnew granitic complex and L₁ stretching lineations form a radial pattern around the granite, consistent with formation during D₁ uplift of the composite granite body. Uplift and erosion of granite bodies in the surrounding area provide a source for the granite clasts in the upper parts of the Scotty Creek Basin. As clasts in the basin are undeformed, no significant deformation occurred prior to the uplift and erosion of the source granites in this area. Syn-tectonic emplacement of the Lawlers Tonalite during formation of the Scotty Creek Basin at ca 2665?Ma may have provided a good heat/fluid source for the mineralising systems during the first gold event. The distribution of the large deposits along the western edge of the Agnew granitic complex indicates that the extensional shear along the granite contact is a first-order control on gold deposition by providing a conduit for rising hydrothermal fluids. The northerly trend of high-grade shoots in the Waroonga deposit coincides with early north-trending growth faults, which are also likely fluid conduits.     

尼日尔Termit盆地上白垩统储层岩石学特征及控制因素分析

本文对尼日尔Termit盆地17口井218个井壁取芯样品开展普通薄片、阴极发光、X衍射、扫描电镜及重矿物分析,研究上白垩统储层的岩石学特征,并探讨其控制因素。实验分析结果表明,Termit盆地上白垩统储层的岩石类型主要为石英砂岩,成分成熟度高,以石英为主,含量达86%以上,钾长石、方解石及斜长石等含少量,占比约5%,这种岩石类型对原生孔隙的保存比较有利;填隙物主要为粘土杂基,含量为7%左右,矿物成分以高岭石为主,利于对晶间孔的保留;岩石中发育硅质、方解石和铁质等胶结类型,胶结物的含量占比较小,对储层的破坏作用不大;重矿物类型为磁铁矿、赤铁矿、锆石、磷灰石,推测物源区的母岩类型主要为花岗岩;以细粒结构和少量的不等粒结构为主,分选中等-差,磨圆度一般为次棱角-次圆状,磨圆差。与国内石英砂岩沉积于高能的滨浅海环境不同,研究区石英砂岩成分成熟度高,但分选程度和磨圆度较低,一方面反映了物源区母岩富含石英,同时也反映了这种石英砂岩沉积于近源的河流-三角洲环境。影响研究区上白垩统储层物性的主要因素是岩石类型及成岩作用,由于储层的岩石类型为石英砂岩,压实作用对储层的破坏作用较一般岩石类型偏小。砂岩埋深小于2500m时,主要发育原生孔隙,面孔率大于15%。溶蚀作用对本区储层产生一定的影响,最常见的为长石的溶蚀,溶蚀作用形成粒内溶孔和粒间溶孔,还会扩大原生孔隙形成混合孔,改善了砂岩的储集性能。     

川西中三叠统雷口坡组三段-四段白云岩特征与成因——来自于岩相学及地球化学的约束

白云岩化是影响储层发育是否的重要沉积-成岩过程。作者通过在对川西地区的中三叠统雷口坡组的雷三至雷四段的岩相学,碳、氧、锶、镁同位素以及元素地球化学等综合研究,划分出含膏的泥晶云岩AD0、泥晶云岩D0、泥粉晶云岩D1、粉细晶云岩D2、微生物云岩MD、含灰质藻云岩CD(交代结构)以及去云化的泥粉晶云岩(CD0CD1)等七类白云岩。白云石有序度及铁、锰含量较低。阴极发光以暗紫、暗紫红、蓝紫为主;次为玫瑰红、橙红及橙黄红色。δ~(13)CPDB=1. 95‰～2. 46‰,δ~(18)OPDB=-4. 05‰～2. 70‰;~(87)Sr/~(86)Sr=0. 70778～0. 70807,δ~(26)Mg=-1. 872‰～-2. 124‰,其中δ~(13)C_(PDB)、~(87)Sr/~(86)Sr的平均值与中三叠世全球海水相似;δ~(18)O_(PDB)为弱负漂及正偏移。从D2、D1至D0、AD0,Sr、Na和大部分微量元素含量及比值和δ~(18)O_(PDB)逐渐增加; AD0、少量D0或MD相对富含硅、铝,并与高(低镁)方解石、黏土、有机质等共生。离子组成反映出白云石的前驱物以方解石型为主,少量为文石、原白云石结构。存在广盐、稍咸和超盐度的碱性等沉积环境。白云岩形成主要受向上变浅米级旋回序列,干燥、炎热为主、偶夹潮湿古气候以及古地貌-古水文条件等因素影响。存在浅潟湖的萨勃哈(AD0或D0)、环潮缘至局限台地(D0-D1、微生物诱导MD)、潮间-潮下的微生物礁(席)构成的障壁的台缘带(MD-CD1-CD)、潮坪-开阔台地(D0-D2-CD1、MD)等环境,以萨勃哈和受蒸发泵-密度差驱动的"渗透-回流白云石化"模式为主。     

姬塬北地区延长组长7-长8油层组泥岩地球化学特征与地质意义

基于对鄂尔多斯盆地姬塬北地区上三叠统延长组长7、长8油层组泥岩样品微量元素和稀土元素的测试分析发现,长7、长8油层组泥岩REE富集,Eu总体上呈明显的负异常;REE分布模式图显示轻、重稀土元素分异明显,曲线在La-Eu段表现为斜率较大的"右倾型",在Gd-Lu段表现为斜率较小的"平缓型"。结合Sr/Cu、Sr/Ba、V/(V+Ni)、Ceanom等特征参数的分析发现,长7、长8油层组泥岩形成于温湿、微咸水、还原水体的沉积环境。泥岩(La/Yb)N地化指标显示悬浮物颗粒总体表现为沉降缓慢,沉积速率低,由下至上泥岩悬浮物沉积速率表现为由高到低的变化趋势。同时,δCe、δEu及La/Lb-∑REE判别图解,指示长7、长8油层组泥岩母岩以花岗岩为主,同时有少量碱性玄武岩的混入,源区构造背景为大陆边缘环境。     

鄂尔多斯盆地南缘上二叠统——中下三叠统地球化学特征及其古气候、古环境指示意义

为探索陆相湖泊环境记录中二叠纪—三叠纪之交古气候演化的信息,以鄂尔多斯盆地南缘陕西铜川石川河剖面上二叠统石千峰组(P3s)和三叠系的刘家沟组(T1l)、和尚沟组(T1h)、纸坊组(T2z)为研究对象,对界面上下地层开展了系统的矿物学、岩石学和地球化学研究。通过主量和微量元素、碳氧同位素以及TOC测试对古盐度、古氧化还原环境和古气候演化规律进行分析。测试结果显示在二叠系—三叠系(P/T)界线附近主、微量元素和碳、氧同位素发生较明显的变化,气候环境代用化学指标的波动指示了从晚二叠世至早中三叠世鄂尔多斯盆地的古气候、古环境的变化。研究结果表明上二叠统石千峰组形成于河流-三角洲沉积环境,氧化程度相对低,古气候相对温暖湿润;下三叠统刘家沟组与和尚沟组的紫红色砂泥岩代表水体较浅的河流-三角洲相,强氧化环境,气候干旱炎热;而到中三叠统纸坊组沉积期,湖平面上升,元素的迁移作用加强,氧化程度变弱,气温降低,气候转为半干旱半湿润气候。碳同位素分析结果显示,鄂尔多斯盆地陆相P/T界线上δ^13CPDB存在显著负偏,与全球范围内的海相P/T界线具有一致性,说明在华北地台陆相P/T界线上同样存在气候突变和生物灭绝等重大地质事件的沉积记录,与海相地层可对比。     

准噶尔盆地南缘齐古背斜复杂构造建模技术应用

齐古背斜构造复杂,变形强烈,地震资料相对较差,构造样式建立存在多解性。为准确落实该区构造特征,从地质“戴帽”、倾角标定及平衡恢复与几何变形正演等关键技术出发,对齐古背斜进行精细构造解析,确立齐古背斜为早期构造三角楔与晚期冲断褶皱复合叠加的构造样式。该背斜主体部位具分层、分块构造特征,西段以南倾冲断断裂为主,东段以北倾反冲断裂为主。复杂构造建模技术的应用将有助于建立更为合理的构造解释方案,大大降低油气勘探风险。     

Prediction Model of Coal Reservoir Pressure and its Implication for the Law of Coal Reservoir Depressurization

The main methods of coalbed methane(CBM) development are drainage and depressurization, and a precise prediction of coal reservoir pressure is thus crucial for the evaluation of reservoir potentials and the formulation of reasonable development plans. This work established a new reservoir pressure prediction model based on the material balance equation(MBE) of coal reservoir, which considers the self-regulating effects of coal reservoirs and the dynamic change of equivalent drainage area(EDA). According to the proposed model, the reservoir pressure can be predicted based on reservoir condition data and the actual production data of a single well. Compared with traditional reservoir pressure prediction models which regard EDA as a fixed value, the proposed model can better predict the average pressure of reservoirs. Moreover, orthogonal experiments were designed to evaluate the sensitivity of reservoir parameters on the reservoir pressure prediction results of this proposed model. The results show that the saturation of irreducible water is the most sensitive parameter, followed by Langmuir volume and reservoir porosity, and Langmuir pressure is the least sensitive parameter. In addition, the pressure drop of reservoirs is negatively correlated with the saturation of irreducible water and the Langmuir volume, while it is positively correlated with porosity. This work analyzed the reservoir pressure drop characteristics of the CBM wells in the Shizhuangnan Block of the Qinshui Basin, and the results show that the CBM reservoir depressurization can be divided into three types, i.e., rapidly drop type, medium-term stability type, and slowly drop type. The drainage features of wells were reasonably interpreted based on the comprehensive analysis of the reservoir depressurization type; the latter was coupled to the corresponding permeability dynamic change characteristics, eventually proving the applicability of the proposed model.     

Geochemistry,Paleoenvironment and Mechanism of Organic-Matter Enrichment in the Lower Silurian Longmaxi Formation Shale in the Sichuan Basin,China

To investigate the mechanism of the organic-matter enrichment in the Lower Longmaxi Formation shale, the geochemistry and total organic carbon(TOC) of the Longmaxi Formation black shales in the Jiaoshiba, Zhaotong, and Weiyuan areas of the Sichuan Basin were analyzed. Paleoproductivity proxy parameters(Babio, Siex, and Ni/Al), clastic influx proxies(TiO_2 and Ti/Al), redox indices(V/Cr, Ni/Co, V/(V+Ni), and U/Th), and hydrothermal indicators(Fe, Mn,and Y concentrations; Fe/Ti ratio and a Ni-Zn-Co diagram) were employed to decipher the paleoenvironment of the Lower Longmaxi Formation shales. TiO_2 and Ti/Al indicated low terrigenous detrital influx in all three areas. However, Babio, Siex,and Ni/Al indicated high productivity in the Jiaoshiba area. V/Cr, Ni/Co, and U/Th indicated higher oxygen content with larger fluctuations in the Zhaotong and Weiyuan areas. Fe, Mn, and Y concentrations and the Fe/Ti ratio implied greater active hydrothermal activity in the Weiyuan area. These heterogeneities were considered to be closely related to the paleoenvironment and paleogeography, and the large basement faults that developed during the Chuanzhong paleo-uplift could have provided vents for deep-hydrothermal-fluid upwelling. The redox indices(V/Cr, Ni/Co, and U/Th) and a paleoproductivity proxy(Ni/Al) displayed a significant correlation with the TOC, suggesting that both excellent preservation conditions and high paleoproductivity were the controlling factors for the enrichment of organic matter in the Longmaxi Formation shale. There was no obvious correlation between the clastic influx proxy(Ti/Al) and the TOC due to the extremely low supply of terrigenous debris. The hydrothermal indicator(Fe/Ti) was negatively correlated with the TOC in the Weiyuan area, indicating that hydrothermal activity may have played a negative role in the accumulation of organic matter. This study suggests that the enrichment of organic matter in the Longmaxi Formation marine shale varied according to the paleogeography and sedimentary environment.