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101.
叶蜡石、高岭石和迪开石的吸收光谱研究 总被引:3,自引:0,他引:3
对不同地区叶蜡石、高岭石、迪开石的吸收光谱测量及其高斯谱拟合说明,三各矿物的吸收光谱均由一个吸收边和三个吸收峰叠加而成。主吸收峰在562nm左右,峰高以迪开石为最大,高岭石次之,叶蜡石最低。同一地区不同颜色的叶蜡石,其主吸收峰位置随铁含量的增加向短波方向移动,相对峰高也随之增大。叶蜡石的颜色主要取决于主吸收峰的位置、高度和吸收边位置。可以认为,此吸收边为Fe^3 →O^2-荷移谱的低能拖尾部分,吸收峰则为铁离子的晶场谱带或晶场谱与Fe^2 →Fe^3 荷移的叠加。 相似文献
102.
辐照绿柱石的色心与赋色机制 总被引:4,自引:1,他引:4
在不同辐照剂量的带电粒子作用下,四川无色绿柱石因赋色而呈现浅蓝色,蓝绿色,黄绿色,浅黄色及橙黄色,紫外可见吸收光谱(UV-VIS)和阴极发光光谱(CLS)研究表明,辐照绿柱石中存在两组与赋色密切相关的色心组合,其一为相对稳定的[Fe^3 ]OH和[Fe^3 4]心,其二则为不稳定的[H^0]i心和F^ 心,二者对可见光的能量分别具有不同程度的选择性吸收和发射,由此产生特征的吸收与发射光谱。低温退火处理(210℃),有助于消除辐照绿柱石中不稳定的色心,使相对稳定的[Fe^3 ]OH心黉度再度聚集,并形成新的缺陷(二次缺陷),进而提高稳定色心的主波长和饱和度。研究证实,二次缺陷形成的初始温度,可近似代表辐照绿柱石的最佳热固色温度点,经辐照与热固色作用而形成的黄色,橙黄色绿柱石的颜色相对稳定,并不因长期日照或低温受热(<280℃)而褪色。 相似文献
103.
本文研究了镉-5-Br-PADAP-溴化十六烷基三甲基铵-peregalo显色体系的光谱特征,显色条件,络合物的组成、干扰及其消除。实验证明该法灵敏度高,ε=1.3×10~5l·mol~(-1)·cm~(-1)。选择性较好,显色酸度范围较宽pH=8.0-9.5,络合物最大吸收波长为560nm,镉在0-10μg/25ml的含量范围内服从比尔定律。经标准水样、工业废水及生活用水验证,不经分离可测定水中PPb级的微量镉。 相似文献
104.
样品经硝酸、氢氟酸、高氯酸分解,制成硝酸溶液,经巯基棉层析柱过滤富集Ag,并用2mol/LHBr溶液洗脱,用火焰原子吸收法测定洗脱液中的Ag和滤液中的Cu,Pb,Zn。用该法测定化探样品中银和铜铅锌,检出限低,结果准确度和精密度均令人满意。 相似文献
105.
The analysis and interpretation of coda waves have received increasing attention since the early seventies. In the past few years interest in this subject has spread worldwide, and the study of high-frequency seismic coda waves has become a very important seismological topic. As a conclusion of the studies accomplished in this time, coda waves are considered the result of scattering processes caused by heterogeneities acting on seismic waves.P andS waves play a particularly important role in this interaction. The process introduces an attenuation which, added to the intrinsic absorption, gives the observed apparent attenuation. Therefore, coda waves constitute a thumbprint left by the heterogeneities on the seismograms. Coda waves offer decisive information about the mechanism of how scattering and attenuation take place. This review describes coda waves in detail, and summarizes the work done in this subject to 1986. The relation between coda waves and attenuation in the context of research on seismic scattering problems is stressed. Particular attention has been given to the application of coda waves to estimate source and medium parameters. The state-of-the-art of the temporal variations of coda wave shape, and the possible use of these variations as an earthquake precursor also are presented. Care has been taken to introduce the statistical models used to deal with the heterogeneities responsible for scattering. 相似文献
106.
A number of problems associated with detailed investigation of subsurface geological structure below the bottoms of freshwater reservoirs (rivers, ponds, and lakes) arise during the study of the upper portions of geological sections. The present study is aimed at marginal estimation of the penetrating depth of ground radar investigations in freshwater reservoirs (based on bottom reflections), taking into account the complex nature of conductivity and its dependence upon the frequency under ideal conditions with no noise. The same method can be applied for estimating any given dynamic recording range. 相似文献
107.
B. P. Harlamov 《Mathematical Geology》2003,35(4):431-449
Zones of increased concentration formed by a solvent flowing from a source are considered. A matehmatical model for forming such zones is proposed. It takes into account that such a zone is composed of a set of independent particles. Hence the distribution of a substance around the source can be explained by movement of an individual particle. In the model this movement is a continuous semi-Markov process with terminal stopping at some random point in space. Parameters of the process depend on the velocity field of the flow. Forward and backward partial differential equations for the distribution density of a random stopping point of the process are derived. The forward equation is investigated for the centrally symmetric case. Solutions of the equation demonstrate either a maximum or a local minimum at the source location. In the latter case a concentric ring around the source is formed. If different substances vary in their absorption rates, they can form separable concentration zones as a family of concentric rings. 相似文献
108.
The compact source 0125 + 628 in the centre of the galactic supernova remnant G 127.1 + 0.5 has been re-observed in HI absorption
using the Westerbork Synthesis Radio Telescope (WSRT). The outer arm HI absorption atV = -95km s-1 has been confirmed. The absorption spectrum is similar to that of the nearby extragalactic source 0123 + 633. We discuss
the arguments concerning an extragalactic origin of 0125 + 628 and conclude that it is most likely extragalactic and not an
SS 433 type object.
The National Radio Astronomy Observatory is operated by Associated Universities Inc. under contract with the National Science
Foundation. 相似文献
109.
火焰原子吸收法间接测定磷矿中氯 总被引:2,自引:0,他引:2
火焰原子吸收法间接测定磷矿中氯达刘生1云南个旧市化肥厂中心化验室个旧661411目前磷矿中Cl-含量的测定多采用浊度法、氯离子选择电极法及离子色谱法。本文采用火焰原子吸收法来间接测定磷矿中Cl-,即在试样溶液中加入定量的Ag+,试样中Cl-与Ag+生... 相似文献
110.
石墨炉原子吸收分光光度法测定土壤样品中痕量镉 总被引:2,自引:0,他引:2
研究了土壤样品中痕量镉的石墨炉原子吸收分光光度法测定最佳条件以及磷酸二氢铵与硝酸镁作基体改进剂对测定镉的基体改进效应,并比较了两种试样分解体系。方法检出限为0.01pg/L,精密度(RSD,n=8)为3.29%-7.69%,经国家一级标准物质分析验证,结果与标准值符合。 相似文献