A review of the occurrence, form and origin of C-bearing species in the Khibiny Alkaline Igneous Complex, Kola Peninsula, NW Russia

The Khibiny Complex hosts a wide variety of carbon-bearing species that include both oxidized and reduced varieties. Oxidised varieties include carbonate minerals, especially in the carbonatite complex at the eastern end of the pluton, and Na-carbonate phases. Reduced varieties include abiogenic hydrocarbon gases, particularly methane and ethane, dispersed bitumens, solid organic substances and graphite. The majority of the carbon in the Khibiny Complex is hosted in either the carbonatite complex or within the so-called “Central Arch”. The Central Arch is a ring-shaped structure which separates khibinites (coarse-grained eudialite-bearing nepheline-syenites) in the outer part of the complex from lyavochorrites (medium-grained nepheline-syenites) and foyaites in the inner part. The Central Arch is petrologically diverse and hosts the major REE-enriched apatite–nepheline deposits for which the complex is best known. It also hosts zones with elevated hydrocarbon (dominantly methane) gas content and zones of hydrothermally deposited Na-carbonate mineralisation. The hydrocarbon gases are most likely the product of a series of post-magmatic abiogenic reactions. It is likely that the concentration of apatite-nepheline deposits, hydrocarbon gases and Na-carbonate mineralisation, is a function of long lived fluid percolation through the Central Arch. Fluid migration was facilitated by stress release during cooling and uplift of the Khibiny Complex. As a result, carbon with a mantle signature was concentrated into a narrow ring-shaped zone.     

对羟基苯甲酸异丙酯合成的研究

以浓硫酸为催化剂，研究了对羟基苯甲酸和异丙醇合成对羟基苯甲酸异丙酯的工艺条件。对影响产率的因素进行了探讨：实验表明，在以7％的浓硫酸为催化剂，反应温度为120℃，醇酸摩尔比为4：1，反应时间为5h的最佳条件下，合成了羟基苯甲酸异丙脂，通过多次重结晶的方法纯化产品，产率可达85．5％，并通过熔点仪、红外光谱等手段对产品加以表征，验证了产品具有较高的纯度。该法简单、快速、产率高、纯度好，具有较高的实用价值。     

Profondeur d'extraction racinaire et signature isotopique de l'eau prélevée par les racines des couverts végétaux

We seek to identify the depth to which water is extracted by the roots in the soil. Indeed, in an isotopic steady-state condition of leaf water, transpiration introduces into the atmosphere a vapour whose isotopic signature is identical to that of root water. In the isotopic models of atmospheric general circulation, it is classically allowed that the signature of transpiration belongs to the meteoric water line. This supposes that the water taken by the roots has escaped with the evaporation of the soil and comes thus from the deep layers of the soil. At the time of experimentation carried out on maize plants (Nemours, Seine-et-Marne, France), this extraction depth was inferred from the comparison between the signature of the water measured on the level of the first internode of the stems of the plants and the isotopic profile of water in the soil. When the flow of transpiration reaches a maximum value, the plant uptakes water resulting from precipitations and which preserves its non-evaporating character after having quickly infiltrated in the deep layers of the soil. This relates to only 55% of the flux transpired by the canopy, the remainder presenting an evaporating character more or less marked according to ambient conditions. This experiment invalidates the classical hypothesis used in isotopic models of general atmospheric circulation in temperate regions. In fact, only half the amount of water vapour transpired by the canopy during the day presents a signature similar to that of the rainwater sampled in deep soil layers. To cite this article: Z. Boujamlaoui et al., C. R. Geoscience 337 (2005).     

Material selection for the gas containment system of a compressed natural gas carrier fleet

In this work, the possible exploitation of fiber-reinforced composites in the context of maritime transportation of compressed natural gas (CNG) is investigated. In addition to a more conventional steel configuration, two different fiber materials, carbon and glass, are considered as construction materials for pressure vessels (PVs) to be stored on board ships, with thickness optimized by FEM analysis.The considered scenario is represented by the transportation of CNG from an offshore well to a terminal on shore. Fleets of ships carrying CNG in pressure vessels manufactured with the investigated materials are generated by means of a ship synthesis model (SSM) software and compared on the basis of technical and economical indicators.The choice of the construction material influences considerably the weight of the PVs, which represent a major item of total ship weight and reflects directly on the general transport performances in terms of resistance, seakeeping and reliability in the service. On the other hand, capital as well as operating expenditures are considerably affected by the choice. When exploring the design space, the ship synthesis model is able, at a preliminary stage of the design, to account for the various technical and economical aspects, their implications and relationships. Results are presented of computations carried out in a specific case, identified by the annual gas production and other characteristics of the well terminal and a cruising route for the ships. The comparison is carried out on the basis of the cost per transported unit of gas and of the percentage of success in the transportation process. The computations show that the choice of the PV material has a key influence on the results in terms of optimal number, dimensions and speed of the ships.     

Accumulation by securitization: Commercial poaching,neoliberal conservation,and the creation of new wildlife frontiers

Part of a broader interest in the escalating securitization of conservation practice, scholars are beginning to take note of an emerging relationship between conservation–securitization, capital accumulation, and dispossession. We develop the concept of accumulation by securitization to better grasp this trend, positioning it in the critical literatures on neoliberal conservation, green grabbing, and conservation-security. The concept captures the ways in which capital accumulation, often tied to land and resource enclosure, is enabled by practices and logics of security. Security logics, moreover, increasingly provoke the dispossession of vulnerable communities, thereby enabling accumulation. We ground the concept by turning to the Greater Lebombo Conservancy (GLC) in the Mozambican borderlands. This is a new privately-held conservancy built as a securitized buffer zone to obstruct the movement of commercial rhino poachers into South Africa’s adjacent Kruger National Park. We show how wildlife tourism-related accumulation here is enabled by, and in some ways contingent upon, the GLC’s success in curbing poaching incursions, and, relatedly, how security concerns become the grounds upon which resident communities are displaced. In terms of the latter, we suggest security provides a troubling, depoliticized alibi for dispossession. Like broader neoliberal conservation and green grabbing, we illustrate how accumulation by securitization plays out within complex new networks of state and private actors. Yet these significantly expand to include including security actors and others motivated by security concerns.     

X射线荧光光谱-电子探针在中酸性火山岩鉴定中的应用

中酸性火山岩多具斑状结构,基质可见微晶状结构、隐晶状结构、玻璃质结构等,由于基质矿物颗粒多细小,常用的偏光显微镜受放大倍数的限制,很难准确鉴定矿物种属及含量,这类岩石仅依靠偏光显微镜分类命名会存在误差。本文采用X射线荧光光谱(XRF)、电子探针(EMPA)和偏光显微镜下观察相结合的方法,对中酸性火山岩进行鉴定。结果表明:对于基质呈隐晶质、显微晶质的中酸性火山岩,基质特征相似,偏光显微镜下无法确定长石、石英的含量,因此无法对岩石准确命名;再通过XRF进行主量元素分析,并对分析结果进行标准矿物QAPF双三角图解分类、TAS图解分类及李氏火山岩定量分类,对比结果显示三种分类命名方法存在差异;通过电子探针对矿物进行校验显示,QAPF及李氏火山岩定量分类图解与显微镜下鉴定相符,TAS图解与其他分析结果存在一定偏差。因此,对于中酸性火山岩准确命名,应采用多种分析方法相结合的方式,避免测试单一引起的误差。     

无锡梅雨期湿沉降综合分析

利用2008—2014年梅雨期间酸雨观测资料及2014年6月16—27日降水个例加密采样资料,结合大气污染物资料分析了近7 a无锡梅雨期酸雨特征,研究降水过程中空气污染物、p H值、电导率的变化及降水对污染物的清除作用。结果表明:无锡市梅雨期酸雨年平均p H值呈现逐年递增趋势。降水过程中,颗粒物质量浓度显著降低;气体浓度变化受其自身日变化及排放源影响大于雨水的清除作用;样品的p H值、K值每个过程变化并不一致,K值变化与颗粒物质量浓度变化大致保持一致。降水、风对颗粒物质量浓度影响大于对气体浓度的影响。长时间连续降水时,降水对颗粒污染物的清除存在极限。小时雨量在0~0.5 mm时,降水对颗粒物浓度做负清除,其值反而略有增加;小时雨量在0.6~5.0 mm时,降水对颗粒物质量浓度做正清除;小时雨量达到5.1 mm及以上时,对PM_(2.5)和PM_(2.5-10)做正清除,对PM_(10)做负清除。降水对SO_2有稀释清除作用;对NO_2的稀释作用取决于其开始浓度值;对CO、O_3的清除作用不显著。     

慢特征分析法在气象上的应用进展

气候系统具有非平稳特征,根本原因在于其外强迫随时间发生改变,因此外部驱动力的分析对于理解气候系统的动力学特征至关重要,而如何有效提取系统外部驱动信息是一个亟待解决的前沿科学问题。最近几年,在生物神经学领域中应用的一种提取非平稳信号中外强迫信息的方法——慢特征分析法(Slow Feature Analysis,SFA),在气象领域中也得到了初步成功的尝试,结果显示出此方法对气候系统的外强迫信息分析及有关动力学机制的探究有较好的应用前景。本文主要介绍SFA方法的理论思想及实施步骤,并通过一个理想的非平稳时间序列检验其提取外强迫信息的能力,结果证明在衰减的Logistic模型中,可利用SFA算法提取出模型中的外强迫,且与真实外强迫的相关系数可达0.99;此外,还介绍将该方法应用于Arosa臭氧时间序列,分析其提取的外强迫信息的动力学特征;并介绍了在气候时间序列建模中引入外强迫因子的预测效果。     

狄洛尼三角网构建的目标点快速定位

针对在狄洛尼三角网构建中现有的目标点定位方法存在算法不够稳定、定位路径不惟一等问题,该文在重心方向定位算法的基础上研究建立一种沿搜索方向移动重心的快速定位方法:当发生目标点与当前重心连线经过三角形顶点或者与某三角形边重合等特殊情况时,利用三角形间的拓扑关系得到下一搜索三角形,以此三角形的重心代替前一重心与目标点构成新的搜索方向,继续搜索,从而解决切点问题;同时采用混合积判定公式确定两条线段的相交关系。仿真实验证明改进方法的定位路径惟一,而且可以大大提高构网效率,算法更稳健。