西北印度洋中脊玄武岩源区地幔特征

利用全球岩石地球化学数据库(Pet DB)中有关卡尔斯伯格洋脊(CR)、北中印度洋脊(NCIR)及南中印度洋脊(SCIR)玄武岩的微量元素及同位素组成数据,分析了玄武岩的元素地球化学特征及其沿脊轴的变化,旨在探讨玄武岩源区地幔的(不)均一性及岩浆作用过程的差异。初步研究结果表明:CR、NCIR及SCIR玄武岩组成相近,仅在个别脊段表现有微量稀土元素和同位素组成上的差异,玄武岩整体与N-MORB组成特征相近,与先前通常认为的典型印度洋中脊玄武岩不同。玄武质岩浆主要源自尖晶石二辉橄榄岩地幔的熔融,岩浆源区主要由两个地幔端元构成,即以亏损型地幔(DMM)为主(69%),其次为富集型地幔(EMⅡ,27%)。富集组分可能源自古老陆壳物质的混染。自CR经NCIR到SCIR整个印度洋中脊西北分支玄武岩的Sr、Nd及Pb同位素组成表现出均一性,表明岩浆源区地幔组成相近。在SCIR 19°S附近脊段岩浆源区地幔存在有不均一性,有EMⅡ型地幔端元混入的迹象。在CR 3.5°N附近脊段,玄武岩明显富集K、Ba、La及U等微量元素,但由于缺少同位素数据,源区地幔特征有待进一步研究。在上述研究成果的基础上,提出了该区大比例尺的调查填图及密集采样和精细室内分析是CR深入研究的基础,同时加强Sr、Nd、Pb及Re、Os、Be等同位素分析测试,可提供揭示CR地幔不均一性的可靠依据,而厘清印度洋型地幔对CR的影响程度则有助于深入认识地幔不均一性的成因及地幔动力学过程。     

稳定同位素在天然气水合物地球化学勘查中的应用简介--以"布莱克海隆"海区为例

介绍了国外在布莱克海隆（包括ODP164航次994、995、997站位）进行天然气水合物勘查过程中应用稳定同位素的研究实例；通过对这3个站位样品的甲烷、CO2、DIC（dissolved inorganic carbon)、有机碳以及自生碳酸盐的δ^13C分析，指出浅部（0－30m)甲烷和DIC的δ^13C值随深度迅速降低又迅速升高的变化可以作为天然气水合物存在的地球化学指标。994站位孔隙水δ^18O值深度从0.30‰下降到-0.37‰；氢同位素δD随深度略有下降（从11‰到-12‰），这与水合物形成时氢氧重同位素相对富集于固相有关，表明天然气水合物的存在。997站位δ^37Cl从海底沉积物表层以下30m处为接近海水的最大值0，至钻孔底746.85m处降为-3.68‰，可能也与天然气水合物的形成有关。     

Structure and tectonic evolution of the Southern Eurasia Basin, Arctic Ocean

Multichannel seismic reflection data acquired by Marine Arctic Geological Expedition (MAGE) of Murmansk, Russia in 1990 provide the first view of the geological structure of the Arctic region between 77–80°N and 115–133°E, where the Eurasia Basin of the Arctic Ocean adjoins the passive-transform continental margin of the Laptev Sea. South of 80°N, the oceanic basement of the Eurasia Basin and continental basement of the Laptev Sea outer margin are covered by 1.5 to 8 km of sediments. Two structural sequences are distinguished in the sedimentary cover within the Laptev Sea outer margin and at the continent/ocean crust transition: the lower rift sequence, including mostly Upper Cretaceous to Lower Paleocene deposits, and the upper post-rift sequence, consisting of Cenozoic sediments. In the adjoining Eurasia Basin of the Arctic Ocean, the Cenozoic post-rift sequence consists of a few sedimentary successions deposited by several submarine fans. Based on the multichannel seismic reflection data, the structural pattern was determined and an isopach map of the sedimentary cover and tectonic zoning map were constructed. A location of the continent/ocean crust transition is tentatively defined. A buried continuation of the mid-ocean Gakkel Ridge is also detected. This study suggests that south of 78.5°N there was the cessation in the tectonic activity of the Gakkel Ridge Rift from 33–30 until 3–1 Ma and there was no sea-floor spreading in the southernmost part of the Eurasia Basin during the last 30–33 m.y. South of 78.5°N all oceanic crust of the Eurasia Basin near the continental margin of the Laptev Sea was formed from 56 to 33–30 Ma.     

The Agulhas Ridge, South Atlantic: The Peculiar Structure of a Fracture Zone

The Agulhas Ridge is a prominent topographic feature that parallels the Agulhas-Falkland Fracture Zone (AFFZ). Seismic reflection and wide angle/refraction data have led to the classification of this feature as a transverse ridge. Changes in spreading rate and direction associated with ridge jumps, combined with asymmetric spreading within the Agulhas Basin, modified the stress field across the fracture zone. Moreover, passing the Agulhas Ridge’s location between 80 and 69 Ma, the Bouvet and Shona Hotspots may have supplied excess material to this part of the AFFZ thus altering the ridge’s structure. The low crustal velocities and overthickened crust of the northern Agulhas Ridge segment indicate a possible continental affinity that suggests it may be formed by a small continental sliver, which was severed off the Maurice Ewing Bank during the opening of the South Atlantic. In early Oligocene times the Agulhas Ridge was tectono-magmatically reactivated, as documented by the presence of basement highs disturbing and disrupting the sedimentary column in the Cape Basin. We consider the Discovery Hotspot, which distributes plume material southwards across the AAFZ, as a source for the magmatic material.     

东南印度洋中脊澳大利亚-南极洲不整合带地区岩浆供应与构造作用沿洋脊的变化

We analyzed seafloor morphology and geophysical anomalies of the Southeast Indian Ridge(SEIR) to reveal the remarkable changes in magma supply along this intermediate fast-spreading ridge. We found systematic differences of the Australian-Antarctic Discordance(AAD) from adjacent ridge segments with the residual mantle Bouguer gravity anomaly(RMBA) being more positive, seafloor being deeper, morphology being more chaotic, M factors being smaller at the AAD. These systematic anomalies, as well as the observed Na_(8.0) being greater and Fe_(8.0) being smaller at AAD, suggest relatively starved magma supply and relatively thin crust within the AAD.Comparing to the adjacent ridges segments, the calculated average map-view M factors are relatively small for the AAD, where several Oceanic Core Complexes(OCCs) develop. Close to 30 OCCs were found to be distributed asymmetrically along the SEIR with 60% of OCCs at the northern flank. The OCCs are concentrated mainly in Segments B3 and B4 within the AAD at ～124°–126°E, as well as at the eastern end of Zone C at ～115°E. The relatively small map-view M factors within the AAD indicate stronger tectonism than the adjacent SEIR segments.The interaction between the westward migrating Pacific mantle and the relatively cold mantle beneath the AAD may have caused a reduction in magma supply, leading to the development of abundant OCCs.     

The Mid-atlantic Ridge (31°S–34°30′S): Temporal and spatial variations of accretionary processes

The ridge located between 31° S and 34°30′S is spreading at a rate of 35 mm yr⁻¹, a transitional velocity between the very slow (≤20 mm yr⁻¹) opening rates of the North Atlantic and Southwest Indian Oceans, and the intermediate rates (60 mm yr⁻¹) of the northern limb of the East Pacific Rise, and the Galapagos and Juan de Fuca Ridges. A synthesis of multi-narrow beam, magnetics and gravity data document that in this area the ridge represents a dynamically evolving system. Here the ridge is partitioned into an ensemble of six distinct segments of variable lengths (12 to 100 km) by two transform faults (first-order discontinuities) and three small offset (< 30 km) discontinuities (second-order discontinuities) that behave non-rigidly creating complex and heterogeneous morphotectonic patterns that are not parallel to flow lines. The offset magnitudes of both the first and second-order discontinuities change in response to differential asymmetric spreading. In addition, along the fossil trace of second-order discontinuities, the lengths of abyssal hills located to either side of a discordant zone are observed to lengthen and shorten creating a saw-toothed pattern. Although the spreading rate remains the same along the length of the ridge studied, the morphology of the spreading segments varies from a deep median valley with characteristics analogous to the rift segments of the North Atlantic to a gently rifted axial bulge that is indistinguishable from the shape and relief of the intermediate rate spreading centers of the East Pacific Rise (i.e., 21°N). Like other carefully surveyed ridge segments at slow and fast rates of accretion, the along-axis profiles of each ridge segment are distinctly convex upwards, and exhibit along-strike changes in relief of 500m to 1500 between the shallowest portion of the segment (approximate center) and the segment ends. Such spatial variations create marked along-axis changes in the morphology and relief of each segment. A relatively low mantle Bouguer anomaly is known to be associated with the ridge segment characterized by a gently rifted axial bulge and is interpreted to indicate the presence of focused mantle upwelling (Kuo and Forsyth, 1988). Moreover, the terrain at the ends of each segment are known to be highly magnetized compared to the centers of each segment (Carbotte et al, 1990). Taken together, these data clearly establish that these profound spatial variations in ridge segment properties between adjoining segments, and along and across each segment, indicate that the upper mantle processes responsible for the formation of this contrasting architecture are not solely related to passive upwelling of the asthenosphere beneath the ridge axis. Rather, there must be differences in the thermal and mechanical structure of the crust and upper mantle between and along the ridge segments to explain these spatial variations in axial topography, crustal structure and magnetization. These results are consistent with the results of investigations from other parts of the ridge and suggest that the emplacement of magma is highly focused along segments and positioned beneath the depth minimum of a given segment. The profound differences between segments indicate that the processes governing the behavior of upwelling mantle are decoupled and the variations in the patterns of axis flanking morphology and rate of accretion indicate that processes controlling upwelling and melt production vary markedly in time as well. At this spreading rate and in this area, the accretionary processes are clearly three-dimensional. In addition, the morphology of a ridge segment is not governed so much by opening rate as by the thermal structure of the mantle which underlies the segment.     

超慢速扩张环境下超镁铁质岩系统的热液硫化物成矿机理以及启示

西南印度洋63.5°E热液区是在超慢速扩张洋脊发现的首个超镁铁质岩热液系统。对取自该区的热液硫化物样品进行了系统的矿物学和地球化学分析,矿物学分析结果表明:该热液区硫化物为富Fe型高温硫化物,且经历了较深程度的氧化蚀变,大量中间态的Fe氧化物充填在硫化物矿物间的孔隙及内部解理中;这些硫化物相以白铁矿为主,其次是等轴古巴矿和少量铜蓝,缺乏黄铁矿、闪锌矿。据推断,该区的热液成矿作用分为4个阶段:低温白铁矿阶段→高温等轴古巴矿阶段→自形白铁矿阶段→后期海底风化阶段（少量铜蓝以及大量的Fe的羟氧化物）。与之相对应,地球化学分析结果表明这些硫化物的Fe含量较高（31.57%~44.59%）,Cu含量次之（0.16%~7.24%）,而Zn含量普遍较低（0.01%~0.11%）;微量元素较为富集Co（328×10-6~2 400×10-6）和Mn（48.5×10-6~1 730×10-6）。该区硫化物中较高含量的Fe、Co与超镁铁质岩热液系统相似,明显高于镁铁质岩热液系统。独特的热液硫化物矿物学特征和元素组成可能与该区普遍出露的地幔岩、橄榄岩蛇纹石化作用以及拆离断层的广泛发育的环境有关。     

Mineralogical characteristics of polymetallic sulfides from the Deyin-1 hydrothermal field near 15°S,southern Mid-Atlantic Ridge

A seafloor hydrothermal field, named Deyin-1 later, near 15°S southern Mid-Atlantic Ridge(SMAR) was newly found during the 22 nd cruise carried out by the China Ocean Mineral Resources Research Development Association(COMRA). Sulfide samples were collected at three stations from the hydrothermal field during the26 th cruise in 2012. In this paper, mineralogical characteristics of the sulfides were analyzed with optical microscope, X-ray diffractometer, scanning electron microscope and electron microprobe to study the crystallization sequence of minerals and the process of hydrothermal mineralization. According to the difference of the ore-forming metal elements, the sulfide samples can be divided into three types:(1) the Ferich sulfide, which contains mainly pyrite and chalcopyrite;(2) the Fe-Cu-rich sulfide consisting predominantly of pyrite, chalcopyrite and isocubanite, with lesser amount of sphalerite, marmatite and pyrrhotine; and(3) the Fe-Zn-rich sulfide dominated by pyrite, sphalerite and marmatite, with variable amounts of chalcopyrite, isocubanite, pyrrhotine, marcasite, galena and gratonite. Mineral precipitations in these sulfides are in the sequence of chalcopyrite(isocubanite and possible coarse pyrite), fine pyrite,sphalerite(marmatite), galena, gratonite and then the minerals out of the dissolution. Two morphologically distinct generations(Py-I and Py-II) of pyrite are identified in each of the samples; inclusions of marmatite tend to exist in the coarse pyrite crystals(Py-I). Sphalerite in the Fe-Zn-rich sulfide is characterized by a"chalcopyrite disease" phenomenon. Mineral paragenetic relationships and a wide range of chemical compositions suggest that the environment of hydrothermal mineralization was largely changing. By comparison, the Fe-rich sulfide was formed in a relatively stable environment with a high temperature, but the conditions for the formation of the Fe-Cu-rich sulfide were variable. The Fe-Zn-rich sulfide was precipitated during the hydrothermal venting at relatively low temperature.     

九州-帕劳海脊南段铁锰结壳物质组成特征及成因机制

铁锰结壳（又称富钴结壳、多金属结壳）富含Co、Cu、Mn、Ni、Ti、V、REE、Y和Zn等人类日常生活和高新技术产业亟需的关键金属,是一种重要的战略性矿产资源。本文对九州-帕劳海脊南段水深1900～2600 m处获得的9个站位铁锰结壳样品进行了矿物学和地球化学研究,分析了铁锰结壳的矿物组成、主微量元素和稀土元素含量,并进一步探讨了铁锰结壳的成因类型。结果表明,研究区铁锰结壳的矿物组成以水羟锰矿为主,同时含有大量非晶态铁氧/氢氧化物;Mn、Fe、Co、Ni、Cu平均含量分别为16.15%、15.38%、0.32%、0.33%、0.10%;CaO/P2O5均值为5.93,表明九州-帕劳海脊南段铁锰结壳样品均未发生磷酸盐化作用;铁锰结壳明显富集稀土元素（含Y,REYs）,平均含量为1194 μg/g,轻稀土显著富集,稀土元素经后太古代澳大利亚页岩（PAAS）标准化后配分模式整体相对平坦,呈现Ce正异常而Eu无异常,与海水呈现镜像关系,说明铁锰结壳稀土元素主要来源于海水。铁锰结壳的矿物组成和元素判别图均表明九州-帕劳海脊南段铁锰结壳属于水成型,未受明显的成岩作用影响。     

西南印度洋中脊50°E基性超基性岩石地球化学特征及其成因初探

西南印度洋中脊是典型的慢速扩张洋中脊之一。对采自西南印度洋中脊50°E附近的7件玄武岩和蛇纹石化橄榄岩样品所作的分析表明,基性玄武岩类SiO2含量为43.72%～48.40%,TiO2含量较少,为1.14%～1.52%;MgO含量为5.96%～10.98%;TFe2O3含量为4.55%～5.2%;Mg#值为0.53～0.64,里特曼指数σ为2.34～20.10。微量元素Zr/Nb和Y/Nb比值为显示N-MORB的性质,但是其他微量元素的比值(Ba/Nb,Ba/Th,La/Nb,Nb/U,Nb/Pb)均不显示正常洋中脊玄武岩的特征,微量元素原始地幔标准化蛛网图显示强烈富集K和Pb,亏损Nb,稀土元素显示较为平缓的分配模式。超基性蛇纹石化橄榄岩的主量元素特征为SiO2为38.91～45.49;TiO2含量为0.02～0.28;MgO含量很高,为36.87～40.61,TFe2O3含量为2.82～3.91,Mg#值为0.92～0.94。微量元素中Ni,Cr的含量很高,原始地幔标准化蛛网图显示橄榄岩强烈富集K和Pb,Ba,Th,La,Ce,Ti中等程度富集,而亏损Nb,Sr。稀土元素总量较低,标准化曲线显示轻稀土元素富集模式。结合地球化学特征及前人研究资料分析认为,西南印度洋中脊的基性岩和超基性岩属同源性质,其原始地幔物质可能为部分正常洋中脊亏损地幔混染了陆壳或远洋沉积物的结果。