Carbon isotopic fractionation by desorption of shale gases

Geochemical studies of shale gas and conventional reservoirs within the Triassic Yanchang Formation of Xiasiwan and Yongning Field, Ordos Basin show that methane is isotopically depleted in ¹³C as compared to δ¹³C₁ calculated by the Ro based on the relationship between δ¹³C₁ and Ro. Geochemical fractionation during the adsorption/desorption process of shale system may play a significant part in influencing δ¹³C₁ values of shale gas. Two shale core samples from confined coring of the Yanchang Formation were adopted segmented desorption experiments to examine this phenomenon. The results show that the δ¹³C₁ of desorbed gas changes little in the first few phases of the experiments at low desorption levels, but become less negative rapidly when the fraction of desorbed methane exceeds 85%. The desorption process for the last 15% fraction of the methane from the shale samples shows a wide variation in δ¹³C₁ from −49‰ to −33.9‰. Moreover, δ¹³C₁ of all desorbed methane from the shale samples is substantially depleted in ¹³C than that calculated by Ro, according to Stahl and Carey's δ¹³C₁–Ro equation for natural gas generated from sapropelic organic matter. This shows some gases with isotopically enriched in ¹³C cannot be desorbed under the temperature and pressure conditions of the desorption experiments. This observation may be the real reason for the δ¹³C₁ of shale gases and conventional reservoirs becomes more negative in Xiasiwan and Yongning Fields, Ordos Basin. The magnitude of the deviation between the δ¹³C₁ of shale gas and that calculated by Ro may be related to the adsorption capacity of shale or the proportion of absorbed gases. In this way, we may be able to evaluate the relative adsorption capacity of shale in geological conditions by δ¹³C₁ of the shale gas, or by δ¹³C₁ of conventional gas which generated by the shale with certainty. The δ¹³C₁ of conventional gas in Dingbian and Yingwang Fields have no deviation because the TOC value of the hydrocarbon source rock is relatively low.     

Notions of justice held by stakeholders of the Newfoundland fishery

Justice is an important and contested issue in the governance of fish stocks threatened by overexploitation. This study identifies the notions of justice held by stakeholders of the fishery in Newfoundland, Canada, using qualitative interviews, and interprets these notions in light of established justice theories. The interviews are analysed using inductive and deductive coding. A central result is that inshore fishers are seen as the main claim holders, with a claim to participate and be listened to, and the opportunity to make a living from the fishery. Moreover, rules play an important role in the justice notions of the interview partners, and their justice notions are clearly plural. The stakeholder notions of justice in the Newfoundland fishery resonate with the emphasis on recognition, participation and distribution as important aspects of justice within the environmental justice approach [59-61] (Schlosberg 2004, 2007, 2013).     

双拱初始缺陷海底管线水平向整体屈曲数值模拟分析

为了研究具有双拱反对称初始缺陷海底管线的整体屈曲特性,采用模态分析法将最可能出现的缺陷形态引入数值分析模型中。针对管线在高温高压作用下发生整体屈曲的动态变形特征,运用显式动力数值模拟方法研究了管线整体屈曲过程中水平向变形与轴向变形随温度和内压的变化规律,建立了在整体屈曲过程中屈曲管段与滑动管段轴力的变化过程与初始缺陷形态的关系。将数值模拟结果同经典解析解和室内模型实验结果进行对比,验证了本方法的可靠性。工程算例的分析结果表明,管线整体屈曲的发生是一个由低阶向高阶发展的过程,具有双拱缺陷的管线首先发生二阶模态的整体屈曲,而后过渡到四阶模态;管线整体屈曲的变形包括屈曲段的水平向变形和滑动管段的轴向缩进,其中水平变形释放了管壁内的轴力,轴力的释放量随初始缺陷尖锐程度的降低而增大;轴向缩进变形由于受到地基土的摩阻力使滑动管段内的轴力发生累积,轴力的累积量随初始缺陷的尖锐程度的降低而增加。以上研究成果对指导实际工程具有现实意义。     

基于主成分分析的相对重力观测零漂和固体潮提取

利用主成分分析PCA提取2014-08-15~23CG-5相对重力仪静态相对观测的零点漂移和固体潮。结果显示,PCA提取的零点漂移值与最小二乘线性拟合结果非常一致,其差仅在10-2μGal/d量级;PCA估算的固体潮值与CG-5重力仪内部软件提供的固体潮模型计算值统计结果基本一致,两者之差均小于8μGal,均方根均小于5μGal。     

大光斑波形数据在土地覆盖分类的适用性分析

针对GLAS地学激光测高系统是冰、云和陆地高程卫星(ICESat)的唯一监测工具,能够记录地表光斑内的地物信息,是否能应用于黄土高原土地覆盖分类的问题进行了研究。利用粒子群和最小二乘法相结合的方法对GLAS波形数据进行高斯分解,获取高斯波个数、波形总能量、波形信号起始和信号结束位置4个波形参数;基于波形自动分类方法对黄土高原水体、森林、城市用地、其他地类(裸地、低矮植被等)进行分类。通过基于覆盖相同研究区域的30 m地表覆盖数据(Globe Land30),验证分类的准确性。结果表明,GLAS大光斑波形数据对黄土高原的4种地类能够很好地进行区分,总分类精度高达87.68%,Kappa系数为65.79%。研究表明,GLAS波形数据可以作为获取土地覆盖信息的有效数据源,为研究黄土高原土地覆盖变化提供更丰富的数据支持。     

基于珞珈一号与DMSP/OLS数据的辽宁省城市空间扩张分析

基于珞珈一号和DMSP/OLS夜间灯光数据,提取辽宁省城市空间用地信息并监测分析了2003—2018年城市空间扩张特征。结果表明:1)利用辽宁省DMSP/OLS长时间序列夜间灯光数据提出了一种适合校正长时间序列DMSP/OLS数据的校正方法,提高了数据的连续性和可对比性;2)弥补了统计数据在空间属性的不足,消除了过去单纯依靠统计数据分析城市空间扩张的弊端,为其他省市分析城市扩张提供新的遥感监测分析方法;3)在2003—2018年间,辽宁省城市空间扩张存在城市空间扩张与南方省份相比发展比较缓慢及协调性欠佳等问题。     

闪电和固、液态降水关系差异的数值模拟

为了进一步认识闪电和固、液态降水的关系,本文利用三维雷暴云动力-电耦合数值模式,通过设置敏感性试验组,模拟了一次雷暴过程,分析雷暴中闪电和降水的特征,以及闪电和固、液态降水对垂直风速的依赖关系,探讨闪电与固、液态降水的时空分布关系和单次闪电表征的降水量(RPF:rainyields per flash)。结果表明:对流云降水中,液态降水占主要部分,但固态降水比液态降水对于垂直风速的依赖性更强。随着对流的增强,固态降水在总降水中占的比重越来越大。首次放电时间不断提前,闪电峰值落后垂直风速峰值,总闪数一开始随对流的增强而增加,对流一旦增强到一定程度,总闪数则逐渐减小。固态降水和液态降水的开始时间和峰值时间均随着对流的增强而不断提前,而液态降水出现时间和峰值时间均提前于固态降水。雷暴云首次放电的时间滞后于液态降水,而闪电峰值提前固态降水峰值或与固态降水峰值同时产生。雷暴云中的放电活动集中在强降水区域前缘的较弱降水区,强降水区对应的闪电较少,对流的增强会使降水区域面积、降水量和降水强度增加。由于液态降水总量远大于固态降水总量,固、液态RPF的数值相差达到一个量级,但单位时间内固态降水和液态降水增加的速率相近。在单位时间内闪电次数越多,RPF则越小,而固态RPF和闪电次数的线性相关性明显好于液态RPF,所以利用固态降水可以更好地预报闪电。这些结果有助于进一步认识闪电和降水的关系,并可为闪电预报提供新的思路。     

The Project Siberian High in CMIP5 Models

The Siberian high(SH)experienced a decline from the 1970s to 1990s and a recovery in recent years.The evolution of the SH under global warming is unclear.In this study,41 Coupled Model Intercomparison Project Phase 5(CMIP5)climate models are evaluated in terms of their ability to simulate the temporal evolution of the SH in the 19th and 20th centuries and the spatial pattern of the SH during 1981–2005.The results show that 12models can capture the temporal evolution of the SH center intensity(SHCI)for 1872–2005.The linear correlation coefficient between the SHCI from the Twentieth Century Reanalysis and the simulated SHCI from the multi-model ensemble(MME)of the 12 models is 0.3 on annual and inter-annual scales(above the 99%confidence level).On decadal and multi-decadal time scales,the MME also captures the pronounced reduction(between 1981–2000and 1881–1900 period)and the recovery(during1991–2005)of the SH intensity.Finally,the future evolution of the SH is investigated using the MME of the 12models under the+4.5 and+8.5 W m-2 Representative Concentration Pathway(RCP)scenarios(RCP4.5 and RCP8.5).It is shown that the SHCI,similar to the SHCI in the 20th century,has no significant long-term trend in the 21st century under global warming(RCP8.5 scenario).At the end of 21st century(2081–2100),the SH shows stronger interannual variability than the SH at the end of20th century(1981–2000).The increased interannual variability likely favors the increased interannual variability in winter air temperature over midlatitude Eurasia at the end of 21st century.     

The Effects of Land Cover Change on Regional Climate over the Eastern Part of Northwest China

A regional climate model(Reg CM4) is employed to investigate the impacts of land use/cover change(LUCC) on the climate over the eastern part of Northwest China(ENW) in the periods of 2001 and 2011. The results indicated that the LUCC in ENW, which was characterized by desert retreat, reforestation, and farmland expansion, led to significant local changes in surface air temperature(within ~0.3°C) and slight regional changes in precipitation(within ~15%) in summer. In the desert retreat area, the net absorbed shortwave radiation had a greater influence than evaporative cooling, leading to increases in the daily mean and maximum temperature. Besides, the daily mean and maximum temperatures increased in the reforestation area but decreased in the farmland expansion area. As surface albedo showed no significant change in these regions, the temperature increase in the reforestation area can be attributed to a decrease in evaporation, while the opposite effect appears to have been the case in the farmland expansion area.     

利用TMI资料估计西北太平洋热带气旋强度的客观方法

利用2007—2009年热带降雨测量卫星(TRMM)微波成像仪(TMI)观测的亮温资料,建立一种西北太平洋热带气旋强度(Tropical Cyclone,TC)的估计模型,对2010年热带气旋进行独立估计试验,并对估计误差进行分析。结果表明:该模型对强度小于强台风TC的拟合效果较好,均方根误差约为5 m/s,平均绝对误差约为4 m/s;对强台风和超强台风TC的拟合误差较大,均方根误差分别为9.65和6.60 m/s,平均绝对误差分别为7.76和5.49 m/s;对强台风及以上强度的TC,模型的拟合误差在日(夜)间减小(增大),误差最小(大)值为6.00 m/s(11.96 m/s),说明估计值在日(夜)间偏大(小)。