Application of210Pb in soils

The spectroscopic measurement of soil samples is described.²¹⁰Pb data from a soil survey in western-Europe are briefly reviewed. The average²¹⁰Pb flux from the atmosphere, as determined from²¹⁰Pb _exc soil inventories, is 90 Bq m^–2a^–1. A simple one-dimensional box-chain model is described. The model simulates the vertical, post depositional transport of natural and fall-out radionuclides in the soil. Simulation of measured²¹⁰Pb _exc ,¹³⁴Cs,¹³⁷Cs, and²⁴¹Am soil profiles shows that mixing (bioturbation) is a very efficient transport mechanism. Lead seems to be strongly fixed to organic and clay particles. It is transported by the displacement of the organic and clay carrier substances. The mean residence time of lead, caesium, plutonium and americium in organic rich forest soils is in the order of 250–1000 years. An applicability study in investigate the use of²¹⁰Pb in erosion problems showed erosion rates from 60–180 g m^–2a^–1 on organic rich forest and meadow sites with 10°–25° slopes.This is the eighth of a series of papers to be published by this journal following the 20 ^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P. G. Appleby is guest editing this series.     

Sedimentary response of Pagham Harbour, southern England to barrier breaching in AD 1910

This paper examines the evolution of Pagham Harbour, southern England following storm-induced breaching of a protective barrier in AD 1910. Stratigraphic studies of sediments collected from intertidal areas show the presence of a distinct stratigraphic horizon in the northeast of Pagham Harbour at ca. 0 to +1.0 m ordnance datum (OD). Radiometric data indicate that this horizon is a ‘reclamation surface’ formed after land claim in AD 1846. Following marine flooding in AD 1910, sediment has accreted relatively rapidly (at a broadly constant rate of between 4 and 8 mm a⁻¹), wave and/or tidal energy have decreased and extensive marshes have developed. An asymptotic reduction in sediment accretion rate through time, as predicted in various theoretical models of salt marsh accretion, is not observed. Over the entire Pagham Harbour area, the period between AD 1948 and AD 1986 has seen an average marsh loss of 0.0087 km² a⁻¹, which is relatively small in comparison with other more exposed sites in the local area. Historically breached sites such as Pagham Harbour are common around European coasts, and these provide important natural laboratories within which the medium-term (decadal to centennial) coastal response to barrier breaching, and to managed-realignment coastal protection schemes, can be assessed.     

The transport and mass balance of fallout radionuclides in Blelham Tarn, Cumbria (UK)

Although lake sediment archives are widely used for reconstructing historical records of atmospherically delivered pollutants, the quantitative relationship between fallout levels and their record in the sediments is complex and not well known. The original input signal from the atmosphere can be significantly distorted by mediating transport processes in the catchment, through the water column and within the sediments themselves. Since these processes also affect the fallout radionuclide ²¹⁰Pb commonly used to date sediments, a better understanding of their impact is also important to improving the accuracy and reliability of sediment dating. Blelham Tarn has been the subject of a number of palaeolimnological investigations using radiometric dating techniques since the early 1970s. More recently it was the site of a major study carried out within the EU Transuranics project concerning the long-term fate of fallout radionuclides in catchment/lake systems. This paper reviews the radiometric data from this study and uses the results to determine mass balances for fallout ²¹⁰Pb, ¹³⁷Cs and ^239+240Pu in Blelham Tarn, and their spatial distribution over the bed of the lake. Atmospheric fluxes were determined by measuring concentrations in rainwater and cumulative inventories in soil cores from non-eroding sites. Sediment records in a grid of 16 cores were used to determine the spatial distribution over the bed of the lake, and net inputs from the catchment. Mass balance calculations indicate that c. 47% of ²¹⁰Pb in the sediments derives from erosive inputs from the catchment. For ^239+240Pu the figure rises to 61%. Reduced amounts of ¹³⁷Cs in the sediments are attributed to greater losses of this radionuclide from the water column via the outflow due to its greater solubility. Inputs of radionuclides from the catchment are concentrated near one of the major input streams. Away from this part of the lake the sediment record is dominated by direct atmospheric fallout, though the detailed pattern is influenced by sediment focussing. A one parameter catchment/lake transport model is developed that incorporates the assumption that transport rates will decline with time as fallout on the catchment diffuses into the soil and becomes less available for removal. Values of the transport parameter were calculated for ²¹⁰Pb and ^239+240Pu and found to be comparable. The results suggest that it will take c. 11000 years to remove 50% of ^239+240Pu from the catchment to the lake.     

A comparison of measured 137Cs and excess 210Pb levels in the cultivated brown and cinnamon soils of the Yimeng Mountain area

This contribution analyzes the similarities and differences between the measured activities of 137Cs and excess 210pb （210Pbex） in the cultivated brown and cinnamon soils of the Yimeng Mountain area, discusses the influ- ence of soil texture on the measurement of 210Pbex, and presents differences between the two types of soils. Fields A and B were selected to represent the fields that contain cultivated brown and cinnamon soils, respectively. From either study field, one site of sectioned core and six bulk cores were collected to measure 137Cs levels, 210Pbex levels, and the particle-size composition of soil samples. Three undisturbed soil samples were collected to measure capillary and aeration porosities. The 137Cs inventories for the two study fields are very similar. The 137Cs is a man-made ra- dionuclide, which means that its measured levels for soils are unaffected by soil texture. In contrast, levels of the naturally occurring 210Pbex of soils from Field A were lower than those of Field B by about 50%. In contrast to aquatic sediments, levels of 210Pbex in terrestrial surface soils are affected by the emanation of 222Rn from the soils. It can be assumed that the coarser the soils, the greater the emanation of 222Rn; in addition, the lower the measured 210pbex, the greater the underestimate of this value. The cultivated brown soils in Field A are coarser than the culti- vated cinnamon soils in Field B. As a result, 222Rn in Field A will diffuse more easily into the atmosphere than that in Field B. As a consequence, the measured 210pbex in soils from Field A is much lower than the actual value, whereas the value measured for Field B is much closer to the actual value.     

Suspended sediment in rapid subsurface stormflow on a large field plot

The occurrence of rapid movement of suspended sediment in subsurface stormflow on a large field plot in California is described. Concentrations of over 1000mgl^?1 were recorded in storms of only low to moderate intensity. The observed sediment was composed of uniformly fine-sized particles 4 to 8 μm in diameter. The mode of transport seems different from processes previously reported. Differences in sediment concentrations in different events, levels of ¹³⁷Cs on the sediment, and several other types of evidence indicate that the sediment was detached and entrained at the ground surface by raindrop impact and that the water and sediment flow occurred mainly through macropores in the soil. As conditions similar to those at the study site are not uncommon, it seems probable that the phenomenon may occur in many regions.     

Remedial measures against radioactive Caesium in Swedish lake fish after Chernobyl

The aim of this work is to give a summary of the work on Cs-137 in Swedish lakes carried out mainly by our group (the Liming-mercury-caesium project) between 1986 and 1990. The focus is on results from extensive field experiments carried out in 41 lakes testing various remedial measures to speed up the natural recovery of Cs-137 in lakes: Lake liming and wet land liming with primary rock lime, sedimentary rock lime and so-called mixed lime, which also contains nutrients; potash treatment and intensive fishing. Selected results: The remedies have given the intended water-chemical response. None of the methods used works effectively as cure, i.e., no rapid and clear reduction in the concentrations of radioactive caesium in fish is obtained in comparison with lakes where the waterchemical or biological conditions are not changed. In lakes with long water turnover time and with low values of, foremost, conductivity, hardness and potassium, the fish had relatively higher concentrations at the same fallout levels. The differences present between the lakes as regards the continued magnitude of the change in concentration in fish can foremost be linked to factors controlling the secondary load (i.e., the internal loading and the input from the catchment). A successful potash treatment (in oligotrophic lakes) may imply that the natural recovery will be at the most 5% faster compared to no treatment. This would give quite positive implications in the long run since the ecological half-life for Cs-137 in pike (the top predator in these lake types) is very long. The time interval between the remedies and the latest fish analyses (about 2 years on average) is not sufficient to obtain (statistically) clear-cut results on these the small effects of the remedies. A longer time series of data is required for this.     

长江北支口门圆陀角附近潮滩沉积物粒度记录及其对环境变化的响应

江苏圆陀角位于长江口北支与江苏海岸交汇处,海岸沉积动力环境复杂,潮滩沉积物粒度变化记录了潮滩环境变化的信息。根据2007年4月采集的表层样和钻孔岩芯粒度分析,圆陀角附近YYb断面表层沉积物粒度在互花米草滩前缘较粗,大堤前岸滩最粗,光滩和互花米草滩粒度较细。YY孔岩芯沉积物粒度组成以砂质粉砂为主,粒度变化自下向上呈先由粗变细再变粗的特点,表层样和钻孔岩芯粒度变化反映了潮滩沉积物对风暴潮、潮汐海洋动力、大米草和互花米草种植以及大规模围垦的综合响应。137 Cs测年结果推算出YY孔岩芯1954年以来、1963年以来、1975年以来和1986年以来的平均沉积速率分别为2.38cm/a,2.23cm/a,2.44cm/a和1.24cm/a。岩芯沉积物的沉积速率总体随潮滩淤积增高而下降,1975~1986年间沉积速率的快速增加,主要与圆陀角附近互花米草的快速淤积有关。     

Caesium-137 in Southeast Asia: Is there enough left for soil erosion and sediment redistribution studies?

Low reference inventories of the fallout radionuclide ¹³⁷Cs in low latitudes may limit its present and future application for studies of soil erosion and sediment redistribution in Southeast Asia. ¹³⁷Cs reference inventories and concentrations in surface materials measured in nine and five areas, respectively, across Southeast Asia are here reported and reviewed. The compiled reference inventories decrease from north to south. Three global estimates of ¹³⁷Cs total fallout are also reviewed and compared to the measured data while taking into account factors that affect the fallout estimates and the reference inventory. The results are presented as a schematic regional distribution map of ¹³⁷Cs reference inventories for the year 2012. A relationship between a reference inventory and topsoil concentration is also provided. The measured ¹³⁷Cs concentrations suggest that a minimum detectable activity (MDA) less than 0.5 Bq/kg is required for detection of ¹³⁷Cs activity in topsoils in the lowest reference inventory areas. This sensitivity should allow, at present, ¹³⁷Cs to be a useful tool for analysis of soil erosion in Southeast Asia, should also be a useful chronometer, and will be a useful tracer at least where the reference inventory is more than 500–600 Bq/m². This level of MDA has been demonstrated in previous studies to be achievable by gamma-ray spectrometry using non-destructive sample treatment. As the nuclide decays, sufficient will remain to be useful until the middle of this century in most areas in Peninsular Malaysia and southern maritime Southeast Asia, and a few decades more in the rest of the region.     

Using sediment ‘fingerprints’ to assess sediment-budget errors,North Halawa Valley,Oahu, Hawaii, 1991–92

Reliable estimates of sediment-budget errors are important for interpreting sediment-budget results. Sediment-budget errors are commonly considered equal to sediment-budget imbalances, which may underestimate actual sediment-budget errors if they include compensating positive and negative errors. We modified the sediment ‘fingerprinting’ approach to qualitatively evaluate compensating errors in an annual (1991) fine (<63 μm) sediment budget for the North Halawa Valley, a mountainous, forested drainage basin on the island of Oahu, Hawaii, during construction of a major highway. We measured concentrations of aeolian quartz and ¹³⁷Cs in sediment sources and fluvial sediments, and combined concentrations of these aerosols with the sediment budget to construct aerosol budgets. Aerosol concentrations were independent of the sediment budget, hence aerosol budgets were less likely than sediment budgets to include compensating errors. Differences between sediment-budget and aerosol-budget imbalances therefore provide a measure of compensating errors in the sediment budget. The sediment-budget imbalance equalled 25 per cent of the fluvial fine-sediment load. Aerosol-budget imbalances were equal to 19 per cent of the fluvial ¹³⁷Cs load and 34 per cent of the fluvial quartz load. The reasonably close agreement between sediment- and aerosol-budget imbalances indicates that compensating errors in the sediment budget were not large and that the sediment-budget imbalance is a reliable measure of sediment-budget error. We attribute at least one-third of the 1991 fluvial fine-sediment load to highway construction. Continued monitoring indicated that highway construction produced 90 per cent of the fluvial fine-sediment load during 1992. Erosion of channel margins and attrition of coarse particles provided most of the fine sediment produced by natural processes. Hillslope processes contributed relatively minor amounts of sediment. © 1998 John Wiley & Sons, Ltd.     

Developing a sediment budget for a small drainage basin in Australia

A sediment budget was developed for the 1.7 km² Maluna Creek drainage basin located in the Hunter Valley, New South Wales, Australia, for the period 1971-86. the impact of viticulture, which commenced at Maluna in 1971, was studied using erosion plots, with caesium-137 as an indicator of both soil erosion and sedimentation. Two methods were used to estimate vineyard soil losses from caesium-137 measurements. Sediment output from the catchment was measured for three years, and extrapolated from readings taken at a nearby long-term stream flow gauging station for the remaining 13 years. Relative amounts of soil loss from forest (60 per cent basin area), grazing land (30 per cent) and vineyards (10 per cent) were calculated. Soil losses by rain splash detachment were ten times greater from bare/cultivated sufaces than from the forest. Erosion plots of area 2 m² showed no significant differences in soil loss between forest and grassland but, under bare soil, losses were 100 times greater. the ¹³⁷Cs method was employed to calculate net soil loss from all vineyard blocks using both a previously established calibration curve and a proportional model. the latter method gave estimates of soil loss which were 3-9 times greater than by the calibration curve, and indicated that average soil losses from the vineyard were equivalent to 62 t ha^?1 y^?1 (1971-86). It was estimated that the forest contributed 1-8 per cent, the grazing land 1.6 per cent, and the vineyard 96.6 per cent of the total soil loss during that period. Sediment storages within the fluvial system adjacent to the vineyard ws 9460 t for the period, whereas sediment output was equivalent to 215 t km^?1 y^?1. Independent measurements of soil erosion, storage, and output showed that 56 per cent of the eroded sediment remained in the catchment, and 34 per cent was transported out by Maluna Creek. the budget was able to be balanced to within 10 per cent.