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21.
Hilde Maritz H. C. C. Cloete Jacobus H. Elsenbroek 《Geostandards and Geoanalytical Research》2010,34(3):265-273
The Council for Geoscience (CGS, South Africa) has a statutory mandate to carry out regional geochemical mapping in South Africa that needs to be rapidly and accurately analysed. Both simultaneous X-ray fluorescence spectrometry (S-XRF) and a newly developed method using inductively coupled plasma-mass spectrometry (ICP-MS) were employed. Various trace elements that could not previously be analysed by S-XRF can now be analysed by ICP-MS for the regional geochemical mapping programme, e.g., Cd, Mo, Te and Li. Using both techniques, the CGS aims to report element distributions for some fifty elements. To ensure that element concentration levels correlate over map boundaries, quality control measures in the sampling, sample preparation and analyses were of critical importance. This paper aims to discuss the sample preparation and quality control measures as applied to the ∼5500 samples of the Giyani and Tzaneen 1:100000 scale map sheets sampled at a density of one soil sample per km2. ICP-MS batch- and instrumental drift-correction procedures will be discussed. As a final step, geochemical data were overlain over simplified geological maps using geographical information system software. These maps complement existing geological information of South Africa, help in the identification of exploration targets, test exploration models and initiate further geological research. 相似文献
22.
多维标度法在矿产预测中的应用 总被引:1,自引:0,他引:1
在矿产预测中常涉及一些定性变量,对这些变量的分析和应用,必须将定性描述的地质特征转化为用数值表示的变量,这就需要处理此问题的方法——多维标度法。笔者介绍了计量性的Torgerson法、准计量性的林知已夫数量化理论和非计量性多维标度法,并列举了其在矿产预测中的应用实例。 相似文献
23.
Early Miocene (ca.?21–18 Ma) volcanism in the Karacada? area comprises three groups of volcanic rocks: (1) calcalkaline suite (andesitic to rhyolitic lavas and their pyroclastics), (2) mildly-alkaline suite (alkali basalt, hawaiite, mugearite, benmoreite and trachydacite), and (3) a single trachyandesitic flow unit. Field observations, 40Ar/39Ar ages and geochemical data show that there was a progressive temporal transition from group 1 to 3 in a post-collisional tectonic setting. The calcalkaline suite rocks with medium-K in composition resemble those of subduction-related lavas, whereas the mildly-alkaline suite rocks having a sodic tendency (Na2O/K2O=1.5–3.2) resemble those of within-plate lavas. Incompatible element and Sr-Nd isotopic characteristics of the suites suggest that the lithospheric mantle beneath the Karacada? area was heterogeneously enriched by two processes before collision: (1) enrichment by subduction-related processes, which is important in the genesis of the calcalkaline volcanism, (2) enrichment by small degree melts from the astenosphere, which dominates the mildly alkaline volcanism. Perturbation of the enriched lithosphere by either delamination following collision and uplift or removal of the subducted slab following subduction and collision (i.e., slab breakoff) is the likely mechanism for the initiation of the post-collision volcanism. 相似文献
24.
《Geoforum》2017
This paper uses a Swedish micro-dataset containing 2,696,909 hires during the period 2002–2006 to assess the impact of job-related mobility on plant-level performance. The analysis classifies new recruits according to their work experience and level of formal qualification, as well as by the region of origin and of destination. New hires are divided into graduates and experienced workers and between high- and low-educated. The results point towards the importance of acknowledging both the experience and the skills of new recruits. The greatest benefits are related to hiring new workers from outside the region where the plant is located. The analysis also stresses the importance of geography, with plants in metropolitan regions gaining the most from labour mobility, while the benefits of mobility for plants in smaller, more peripheral regions are more diverse and dependent on both the type and origin of new workers. 相似文献
25.
Mohamed-Montassar Ben Slama Amara Masrouhi Mohamed Ghanmi Mohamed Ben Youssef Fouad Zargouni 《Comptes Rendus Geoscience》2009,341(7):547-556
In the northern part of Tunisia, close to Testour/Slouguia, new observations and updated biostratigraphy make it possible to highlight the relation between the Triassic saliferous mass and the surrounding Mesozoic beds (T. M.). Near the (T. M.) boundary, the formations observed consist dominantly of Triassic evaporites reworked in the Early and Late Albian deep-water sedimentary deposits. Throughout the studied area, Jurassic rocks are absent. We propose to interpret the Chitana-Ed Djebs structure originally emplaced as gravitational stretch masses in a passive margin in the same way as the salt bodies of widespread salt province in the Gulf of Mexico. A reconstructed schematic position of the Chitana-Ed Djebs salt body displays a scenario of setting of the salt mass on a submarine palaeo-slope. Moreover, the starting clues of the paroxysmal event of the Late Mesozoic tectonic inversion clearly fossilized through the discordance of the Middle Eocene–Early Lutetian limestone on the Albian series. 相似文献
26.
27.
生态安全和环境保护是世界各国都非常关心的问题。地质钻探和石油天然气钻采工作中产生大量废弃物,直接影响生态安全和环境保护,给经济建设和人民生活带来很大的负面影响。俄罗斯钻探工作者对此进行了研究,取得了一定效果。他们主要采用综合处理方法和磁化处理方法。利用这2种方法,废弃物不仅可以再生,而且还可以二次使用,有一定的创新和实际意义,值得引起我们的重视,建议对此进行研究与讨论。 相似文献
28.
Determination of Ga,Ge, Mo,Ag, Cd,In, Sn,Sb, W,Tl and Bi in USGS Whole‐Rock Reference Materials by Standard Addition ICP‐MS 下载免费PDF全文
Richard M. Gaschnig Roberta L. Rudnick William F. McDonough 《Geostandards and Geoanalytical Research》2015,39(3):371-379
A procedure for determining a wide range of chalcophile and siderophile elements in typical crustal rocks using standard addition and ICP‐SFMS (inductively coupled plasma sector field mass spectrometry) is presented. New results for Ga, Ge, Mo, Ag, Cd, In, Sn, Sb, W, Tl and Bi abundances in USGS whole‐rock reference materials AGV‐2, BHVO‐1, BIR‐1, G‐2, GSP‐1 and W‐2 are reported using this analytical procedure. Intermediate precision of means based on multiple dissolved aliquots of each USGS reference material was 10% RSD or better for Ga, Ge, In and Sn in all, and similarly good for Ag, Cd, Sb, Tl and Bi in most reference materials. Poorer intermediate precision of Mo and W measurements in several reference materials is probably due to higher analytical blanks on these elements and powder heterogeneity due to a sulfide‐related nugget effect in the specific case of Mo in GSP‐1. Results for all elements fell within the range of available published data with the exception of Ag, which yielded systematically higher concentrations than found in the literature for five of the six reference materials, likely reflecting interference from unresolved polyatomic species. 相似文献
29.
The volcanics exposed in the northeast Niğde area are characterized by pumiceous pyroclastic rocks present as ash flows and fall deposits and by compositions ranging from dacite to rhyolite. Xenoliths found in the volcanics are basaltic andesite, andesite and dacite in composition. These rocks exhibit linear chemical variations between end‐member compositions and a continuity of trace element behaviour exists through the basaltic andesite–andesite–dacite–rhyolite compositional range. This is consistent with the fractionation of ferromagnesian minerals and plagioclase from a basaltic andesite or andesite parent. These rocks are peraluminous and show typical high‐K calc‐alkaline differentiation trends with total iron content decreasing progressively with increasing silica content. Bulk rock and mineral compositional trends and petrographic data suggest that crustal material was added to the magmas by subducted oceanic crust and is a likely contaminant of the source zone of the Niğde magmas. The chemical variations in these volcanics indicate that crystal liquid fractionation has been a dominant process in controlling the chemistry of the northeast Niğde volcanics. It is also clear, from the petrographic and chemical features, that magma mixing with disequilibrium played a significant role in the evolution of the Niğde volcanic rocks. This is shown by normal and reverse zoning in plagioclase and resorption of most of the observed minerals. The xenoliths found in the Niğde volcanics represent the deeper part of the magma reservoir which equilibrated at the higher pressures. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
30.
Ablation Characteristic of Ilmenite using UV Nanosecond and Femtosecond Lasers: Implications for Non‐Matrix‐Matched Quantification 下载免费PDF全文
Zhen Li Zhaochu Hu Detlef Günther Keqing Zong Yongsheng Liu Tao Luo Wen Zhang Shan Gao Shenghong Hu 《Geostandards and Geoanalytical Research》2016,40(4):477-491
Ilmenite (FeTiO3) is a common accessory mineral and has been used as a powerful petrogenetic indicator in many geological settings. Elemental fractionation and matrix effects in ilmenite (CRN63E‐K) and silicate glass (NIST SRM 610) were investigated using 193 nm ArF excimer nanosecond (ns) laser and 257 nm femtosecond (fs) laser ablation systems coupled to an inductively coupled plasma‐mass spectrometer. The concentration‐normalised 57Fe and 49Ti responses in ilmenite were higher than those in NIST SRM 610 by a factor of 1.8 using fs‐LA. Compared with the 193 nm excimer laser, smaller elemental fractionation was observed using the 257 nm fs laser. When using 193 nm excimer laser ablation, the selected range of the laser energy density had a significant effect on the elemental fractionation in ilmenite. Scanning electron microscopy images of ablation craters and the morphologies of the deposited aerosol materials showed more melting effects and an enlarged particle deposition area around the ablation site of the ns‐LA‐generated crater when compared with those using fs‐LA. The ejected material around the ns crater predominantly consisted of large droplets of resolidified molten material; however, the ejected material around the fs crater consisted of agglomerates of fine particles with ‘rough' shapes. These observations are a result of the different ablation mechanisms for ns‐ and fs‐LAs. Non‐matrix‐matched calibration was applied for the analysis of ilmenite samples using NIST SRM 610 as a reference material for both 193 nm excimer LA‐ICP‐MS and fs‐LA‐ICP‐MS. Similar analytical results for most elements in ilmenite samples were obtained using both 193 nm excimer LA‐ICP‐MS at a high laser energy density of 12.7 J cm?2 and fs‐LA‐ICP‐MS. 相似文献