Photoinduced toxicity single and binary mixtures of four polycyclic aromatic hydrocarbons to the marine diatom Skeletonema costatum

Diatom Skeletonema costatum Cleve is one of the main predominant phytoplankton species in the Changjiang Estuary in China. In order to provide some basic information for future assessment of the potential risk on phytoplankton communities in this estuary caused by polycyclic aromatic hydrocarbons(PAHs), this alga was selected as a representative to investigate the photoinduced toxicity of PAHs, in single and mixture. Four PAHs including three-ring phenanthrene and anthracene, four-ring fluoranthene and pyrene were tested in the laboratory. The single toxicity of each PAH on this microalga was compared with and without the simulated solar UV radiation. The results showed that this microalga was sensitive to PAH's photoinduced toxicity. Ratios of the 72 h median effect concentration obtained for fluorescent and UV light tests were about 8.4 for phenanthrene, 13.0 for anthracene, 6.5 for fluoranthene, and 5.7 for pyrene, indicating that UV light enhanced the PAH toxicity to this alga significantly. Under the fluorescent radiation (lacking UV), the dose-response curves based on chemical concentrations revealed that the order of toxic strength was fluoranthene greater than pyrene greater than anthracene greater than phenanthrene; while under the UV radiation (476 μW/cm2 for UVA, 6.5 μW/cm2 for UVB) it became fluoranthene approximately equaling anthracene greater than pyrene greater than phenanthrene, indicating that the UV light also changed its relative toxicity to this alga. The photoinduced toxicity of PAHs to the marine diatom S. costatum might be a synergistic effect of photosensitization reactions (e.g., generation of single-state oxygen) and photomodification (photooxidation and/or photolysis).The combined effects of six binary mixtures on the marine diatom S. costatum were investigated using the additive-index method. Four binary-mixtures (phenanthrene plus anthracene; phenanthrene plus pyrene; anthracene plus fluoranthene; anthracene plus pyrene) were found to be synergistic joint action mode, while two binary-mixtures (phenanthrene plus fluoranthene; fluoranthene plus pyrene) displayed antagonist, revealing a complex pattern of possible interactions. The combined action mode of PAHs might be related to various factors such as the mixture compounds, mixture ratios and test conditions, etc.     

海洋生物-光学算法研究──南黄海叶绿素浓度的估算

根据１９９５年９月中日合作南黄海现场观测资料，对南黄海生物－光学算法进行研究。首先对南黄海现场多光谱反射比数据进行因子分析，解反射比协方差矩阵的特征问题；解出特征值和对应的特征向量，求出主因子，然后建立叶绿素α对主因子的多元线性回归方程，并对算法进行回报和预报检验。计算结果表明，该算法具有较高精度，同时也显示出天气条件对估算精度产生较大影响。     

南海尖峰海山多金属结壳地球化学

南海尖峰海山多金属结壳富含30多种元素,其锰铁矿物主要由钡镁锰矿,δ-MnO_2和FeOOH·xH_2O组成。与其它海区的结壳相比,尖峰海山结壳富含Cu、Ni、Ba、Zn、Pb等元素,而Co、Ti、稀土元素(REE)、Sr等元素相对较贫。研究表明,HREE亏损,具明显的Ce正异常,较明显的Tb正异常和Yb负异常。这是氧化弱碱性海洋环境所致。结壳是水成作用的产物,它的形成受南海独特的古海洋环境所控制,海底火山热液作用,可能也是影响因素之一。     

陆架边缘的多波束测量

大陆架边缘和大陆坡的水深变化较快，在中国东海陆架边缘水深从100m左右快速地变化到陆坡的几千米。从系统的测程和精度考虑，在陆架边缘和陆坡区同时使用浅水型和深水型多波束系统进行测量是一种合理的作业模式。深、浅水多波束系统在i作频率、发射更新率、信号取样率以及波束宽度上都有较大的不同，这些因素直接影响到海底地形测量成果。对用Simrad EM950浅水型多波束系统和SeaBeam2112深水型多波束系统在同一陆架边缘的测量结果进行了比较。     

珠江三角洲网河区水位变化趋势研究

根据珠江三角洲网河区29个验潮站的实测验潮记录,应用傅氏变换与最平滤波器串联的方法来消除月均序列的周期波动对确定水位变化趋势的影响,由低通序列一元线性回归分析确定各站水位的变化趋势;结果表明,周期波动对确定海平面变化趋势的影响是显著的.应用经验正交函数(EOF)对网河区的水位变化场进行分解,由相互独立的时间函数和空间特征函数表征网河区区域的水位变化特征;应用时间特征函数计算区域水位的平均变化率为0.02mm/a.根据验潮站的水位变化趋势,探讨网河区水位变化与河床冲淤的关系.     

台湾海峡1999年8月表层温盐的走航式观测

利用1999年8月台湾海峡的调查资料中走航式温盐仪的资料，对该海区的表层温盐分布进行分析。分析结果表明：调查期间在该海区存在多处上升流和冲淡水。台湾海峡调查海区的上升流区大致可分为两类：（1）海峡西部沿岸上升流区：平潭上升流区、东山上升流区和南澳上升流区；92）台湾浅滩附近的上升流区。冲淡水主要有九龙江冲淡水、珠江冲淡水和闽江冲淡水，此外还有粤东沿岸水。     

地形坡度对多金属结核分布的控制作用

选取我国东太平洋多金属结核开辟区内的一个区域作为研究区,利用人工神经网络中应用最为广泛的BP网络,建立控制多金属结核分布的地质因素与多金属结核分布之间的映射关系,探讨地形坡度对多金属结核分布的控制作用.结果表明,在经度、纬度、水深、坡度四个因素中,坡度对结核分布影响程度最大;多金属结核主要分布于坡度小于5°的地方;当坡度小于5°时,丰度与地形坡度呈正相关,品位与地形坡度呈负相关,丰度与品位呈负相关;品位与坡度似呈指数关系,坡度增大,品位降低.     

深海矿产资源政策法规研究及意义

本文介绍了国内外关于深海矿产资源勘探开发及相关因素的立法状况及意义。     

分潮波模型多资料数值计算方法研究 Ⅱ.有限差分最小二乘方法

对含多资料的分潮波模型的超定问题进行探讨，建立一种有限差分—最小二乘方法，该方法使得岸边资料直接进入了计算方程，并保证岸界法向流速为零条件。通过对渤海的四大分潮的试算，证实本方法可行。     

多管藻内生真菌Chaetomium globosum.苯甲醛类次生代谢成分研究

从采自青岛近海的红藻多管藻(Polysiphonia urceolata)中分离到一株毛壳霉属真菌球毛壳菌(Chaetomium globosum.),对其发酵代谢产物的化学成分进行了研究。采用溶剂提取、分配,硅胶柱层析、葡聚糖凝胶柱层析以及制备薄层层析等技术已分离获得6个单体化合物,通过一维、二维超导核磁共振技术、质谱技术等鉴定了其中4个化合物的结构,均为苯甲醛类衍生物,分别为2-(1-庚烯基)-3、6-二羟基-5-(3-甲基-2-丁烯基)苯甲醛(Ⅰ)、2-庚基-3、6-二羟基-5-(3-甲基-2-丁烯基)苯甲醛(Ⅱ)、2-(3、5-庚二烯基)-3、6-二羟基-5-(3-甲基-2-丁烯基)苯甲醛(Ⅲ)、2-(1、3、5-庚三烯基)-3、6-二羟基-5-(3-甲基-2-丁烯基)苯甲醛(Ⅳ)。