基于高分辨率遥感影像的林地变化检测方法研究

本文采用2013年QuickBird和2017年GF-1卫星遥感影像,以黑龙江省五常市为研究区,利用遥感影像的光谱特征提取纯净森林像元,构建整合森林指数(Integrated Forest Z-Score,IFZ)对影像的森林和非森林区域进行区分,叠加对比分析两期影像提取结果,得到研究区内林地的变化区域.再将自动提取结果与人工判读图斑进行精度验证,面积误差为4.2％,图斑重叠率为85％.从精度结果可知,高分辨遥感影像可以准确地监测林地变化,对研究环境变化和森林经营管理具有决策性作用.     

凝结潜热释放对温带气旋相对涡度倾向的影响

潜热释放的作用在温带气旋的研究中一直是研究的重点。江苏省气象台沈阳等以一个产生极端降水的温带气旋为研究对象,基于全型涡度方程,计算了凝结潜热释放对气旋相对涡度倾向的贡献。结果表明,对流凝结潜热加热率最大可达稳定凝结潜热加热率的40倍。两类潜热加热中心均位于700 hPa以上,加热率垂直梯度在对流层低层为正,因而在加热中心下方形成正涡源中心。对流凝结潜热垂直梯度引发的涡度倾向比稳定凝结潜热高出1个数量级。虽然总的凝结潜热水平梯度引发的涡度倾向可以贡献气旋涡度实际增长值的65%,但对流凝结潜热垂直梯度的贡献高达其2倍。凝结潜热释放不仅能够直接引发涡度倾向,亦可通过改变位温梯度,进一步造成涡度倾向。     

“煤特征指数”与矿井瓦斯危险类型的关系

矿井瓦斯危险程度与煤层中瓦斯赋存状况及其泄出方式有关,并取决于多种地质条件和采掘工艺。其中,煤特征条件特别重要。本文分析了湖南省的5种矿井瓦斯危险类型以及相应的煤特征条件,提出了“煤特征指数(I_c)”这一概念。I_c是一项评价矿井瓦斯危险程度的综合指标。研究表明,矿井瓦斯危险愈严重,则其I_c值愈高。应用该项成果预测了16对矿井的瓦斯危险类型,取得了满意的效果。     

岩溶区集中式饮用水源地水质评价与保护——以毕节市倒天河水库和利民水库为例

采用SPSS软件，对2003年01月至2004年12月期间，倒天河水库和利民水库逐月水质监测数据进行数理统计分析，结果表明毕节市饮用水水质污染有较明显的季节变化和空间差异；且不同污染物对水体污染的贡献率各不相同，总磷和粪大肠菌群所占份额最大，方差累积贡献率达77％。在此基础上，利用加权综合污染指数对水体水质污染现状进行综合评价，结果显示倒天河水库和利民水库，水质污染总体较轻．饮用水水质符合《地表水环境质量标准（GB3838—2002）》中Ⅲ类水质标准；最后提出加大水环境保护的建议。     

论四川盆地三叠系地下水水文地质条件

四川盆地三叠系地下水可划分出碎屑岩孔隙裂隙和碳酸盐岩岩溶裂隙两大储集类型。按此处构造开启程度和埋深条件等的不同,下中三叠统地下水有沉积变质水和渗入淋滤水两种基本成因类型,水动力特征各异。沉积变质水处于深埋封闭条件,受地静压力驱动控制;渗入淋滤水分布于背斜露头区和浅部地区,受静水压力驱动控制。并由此控制了盆地三叠系盐类的保存条件。     

陕西省水工程勘察规划研究院

陕西省水工程勘察规划研究院始建于一九四九年。长期以来承担着全省地下水监测研究、地下水盗源调查评价、地下水开发利用规划、钻井技术设备研究、科技推广等专业按术工作和机井工程建设监督、质量管理，钻井施工资质管理等行业技术管理工作。具有国家甲级水文水资源调查评价、建设项目水资源论证、水文地质勘察、岩土工程资质．     

Mobility of heavy metals from tailings to stream waters in local zinc smelting activities contaminated site

It has been found that stream waters were severely contaminated with wastes from a long-time smelting factory in Hezhang, Guizhou, China. The main sources of contamination are the smelting wastes stored in the open air and abandoned in the vicinity of stream. A method of lead isotope was adopted in order to identify relations between tailings and water contamination. Representative samples of tailings and stream sediments were collected. Mineralogical characterizations were conducted using XRD and TEM/SEM, while acid digestion was carried out for determining metal contents. BCR sequential leaching tests were performed in order to assess metal mobility. The tremendous ‘actual＇ and ‘potential＇ mobility of heavy metals indicates that the smelting waste and stream sediments present a considerable threat to the environment. Besides the chemical remobilization of heavy metals from the sediments and the reworking of riverbed sediments act as a secondary source of pollution. Also groundwater and stream water were sampled in specific locations and were measured.     

Geochemistry of porewater and sulfate-reducing bacteria in sediment cores from the Chianan Plain, Taiwan

High concentrations of arsenic and humic substances in groundwater from the southwestern coastal plain of Taiwan were well known for their probable relationships with black-foot disease. In order to realize the relationships between the concentrations of humic substances and arsenic in this area, 24 well water samples were analyzed. After filtered through 0.45 μm glass fiber membrane in the field, samples were kept in the dark at 4℃ and then separated into six fractions with varying range of molecular weight （〈0.5, 0.5-1, 1-5, 5-10, 10-50 and 〉50 k Da） by ultrafiltration apparatus （Molecular/Por Stirred Cell system） in the lab. Concentrations of humic substances were measured by fluorescence spectrometer （HITACHI F-2000, ex=370, em=445） and arsenic by FIAS-AA （Perkin Elmer AAnalyst 100, FIAS-400）. On average, only 6.2% of the total arsenic in water existed in the fraction of 〉0.5 k Da. and the others were complexed with humic substances （including humic acid and fulvic acid）. The results demonstrated a distinct positive correlation between the concentrations of humic substances and arsenic.     

Possibility of degradation of phenylarsonic acid in the presence of ferrihydrite

Although inorganic species are predominant in natural systems, but there are many kinds of organoarsenic species such as methylated and phenylated arsenic compounds. Phenylarsonic acid （PA） is a degradation product of organoarsenics used for chemical warfare agents, which has been detected in well water at the disposal site of the agents in Japan. There are few reports studying behavior of PA in soil. In this study, PA was adsorbed onto ferrihydrite and its chemical forms were determined using high performance liquid chromatography connected to inductivity-coupled plasma mass spectrometry （HPLC-ICP-MS）. 100 mg/kg of PA was mixed with 0.03 g of 2-line ferrihydrite. For each suspension, pH was adjusted by HNO3 or NaOH. Each sample was incubated for more than 19 hours and the final pH was measured. After filtration, the chemical form of arsenic in the filtrate was measured using HPLC-ICP-MS. In addition, ferrihydrite separated by filtration was dissolved by 3 ml of 0.5 M HCI and the arsenic species in the solution was detected by HPLC-ICP-MS （column： Tosoh TSKgel SuperlC-AP, eluent： 0.01 M HNO3）. It was verified that PA is not degraded by heating in 0.5 M HCl solution. At pH 3.1, any arsenic compounds were not detected from the solution, because almost all arsenic species were adsorbed onto ferrihydrite at lower pH. At pH= 12, however, 7%-10% of inorganic arsenic was detected in the solution. In solid phase, there are some problems to determine the precise ratio of inorganic and organic species. When the solution includes Fe ion at 0.01 M level, the retention time of arsenic species drifted compared to those in standard solution, which makes it difficult to determine precisely the arsenic species adsorbed on ferrihydrite. Therefore, more study is needed to determine the ratio of inorganic and organic species in the system.     

Treatment of high fluoride concentration wastewater by layered double hydroxides： Mechanism studies

An appropriate concentration of fluoride in drinking water is required to prevent dental cavities, but long-term ingestion of water that contains more than a suitable level of fluoride can cause bone disease and mottling of the teeth. Fluoride ions can be found in wastewater from the fluoride chemical industry, as well as the semiconductor, metal processing, fertilizer, and glass-manufacturing industries. The discharge standard for fluoride in industrial wastewater in China is 10 mg/L. Efficient treatment of fluoride-containing wastewater is therefore of major concern in China, following the rapid development of the fluoride chemical industry. Several methods have been used to remove fluoride from water, such as adsorption, chemical precipitation, electrodialysis, ion exchange and electrochemical processes. Layered double hydroxides （LDHs） are anionic clays with high anion exchange capacities which are effective adsorbents for removal of a variety of anionic pollutants. LDHs have been studied as potential adsorbents for removing toxic anionic species such as CrO4^2-, TcO4^-, SeO3^2-, pesticides, and anionic surfactants from aqueous systems. One of the main attractions of using LDHs for fluoride removal, is that unlike other chemical treatment methods, no chemical sludge should be produced. In the present study, an attempt was made to investigate the mechanism of fluoride removal by LDHs under different conditions using batch methods. In addition, the release of fluoride adsorbed on LDHs by treatment with an aqueous solution of Na2CO3 was studied. The residual fluoride was found to be 10 mg/L in a solution with an initial concentration of 1000 mg/L, which meets the discharge standard for fluoride in industrial wastewater in China.