Microwave-assisted extraction of organochlorine pesticides from sediments and determination by gas chromatograph with electron capture detection

A simple and rapid procedure to extract organochlorine pesticides （OCPs） from sediments by means of microwave energy is proposed. Sediment samples were irradiated with microwaves in a closed vessel system while immersed in hexane-acetone （1 ： 1, v/v）. The sample extracts were cleaned up using solid phase extraction with Florisil as adsorbent. Pesticides were eluted with hexane-ethyl acetate （80 ： 20, v/v） and determined by gas chromatographic separation with electron capture detection. Three oven programs were assayed with two different solvent mixtures in order to achieve adequate experimental conditions for the complete extraction of organochlorine pesticides from the matrix. Different variables such as the composition of extraction solvent,     

Speciation analysis and significance of ecological geochemistry

Different species of one element have different activities, so it has different effects on environment and human health. To analyze qualitatively and quantitatively the speciation of a special element in sample, which is the important basis for appraising the toxicity and studying the rule of transfer and translation of elements. Since the 1970＇s, the scheme of sequential extraction has already been used at many laboratories both at home and abroard, to get the information about heavy metals＇ activity in polluted soils. Because this method has the experimental nature, many schemes of problem has taken place, the absence of consistency of these sequential extraction have been formed. Thus the complexity of the schemes, the lack of selectivity of reagent, the lack of quality control, the result mainly related to the extraction scheme used, and so on. In the face of these problems, the study of experimental methods of sequential extraction on three different soils, sediment in Dongting Lake, soil in Jiangsu Province and loess in Shanxi Province was made. Reference materials of heavy metal speciation following sequential extraction in soil and sediment had been developed. Nowadays two kinds of sequential extraction methods which are widely used are BCR （three steps） and improved Tessier methods （seven steps）. Based on three steps of BCR, water-soluble speciation and the residual speciation were increased in our research. BCR701 was determined eight times at different laboratories using BCR three steps. The results showed that determined data obtained eight times were identical to the standard value, and it is indicated that this method has good reproducibility. The stability and homogeneity experiments indicated that the preparation of three types of candidates accorded with our requirements. Eight laboratories had afforded the determined values of 12 heavy metal elements （Cu, Pb, Zn, Mn, Co, Ni, Cd, Cr, Mo, As, Sb, Hg, Se et al.） using BCR three steps. Also, these three candidates afforded the determined values by seven steps, and 12 laboratories had participated.     

Methylmercury and human biomarkers： Questioning the evidence

Methylmercury （MeHg） is a powerful neurotoxicant in humans. In terms of biomarkers of MeHg exposure, hair and blood have long been used in epidemiological studies as the biomarkers of choice. In fact, total hair mercury （Hg） content as well as organic blood Hg concentrations reflects exposure to organic Hg from food consumption. Extensive studies, establishing a constant and linear relation between MeHg intake versus Hg levels in hair and blood, were conducted by governmental officials to establish guidelines on safe levels of MeHg exposure, which were translated into threshold daily fish consumption rates （usually expressed as μg MeHg per kg bodyweight）. Nowadays, in most epidemiologic studies blood or hair mercury （Hg） level is commonly used as a valid proxy to estimate human exposure to methylmercury （MeHg） through fish consumption without relating this signal to actual fish consumption patterns among populations. Human variability in mercury toxicokinetics was identified and measurement error has been pointed out to be a substantial contributor to observed variability, particularly where dietary information is retrospective and self-reported. However, experimental evidence indicates that significant variability among individuals may exist in the biokinetics of mercury. Also recent findings from previous population-based studies through COMERN initiative also revealed that MeHg metabolic processes might greatly vary across populations. In fact, it is unlikely that the magnitude of the difference measured between observed and expected levels of mercury, given the reported intake, can be entirely explained by laboratory measurement errors or reporting bias.     

大湾铀矿田铀-镭平衡系数及迁移富集特征研究

从分析大湾铀矿田各矿床(点)的铀镭平衡系数变化特征出发,结合放射性同位素比值特征分析铀镭迁移富集行为,指出了各矿床(点)氧化带的深度,以了解各铀矿床(点)潜在的工业价值.     

云南元-磨公路某高堑坡灾害发生机制及防治对策

论文根据现场地质调查,应用地质力学分析方法,分析了元-磨公路K235 160~600段高堑坡地质条件、病害发生机制和诱发因素。堑坡所在区域位于红河深大断裂与哀牢山深大断裂所夹持的哀牢山褶皱带内,属强烈侵蚀切割的低中山区,河流下切严重,河流阶地不发育。南溪河及其支流小曼萨河、叉河依附于不同时期生成的构造发育而成,堑坡位于小曼萨河注入南溪河的交汇部位小曼萨河的左岸。小曼萨河及南溪河所夹持的山体,尤其是堑坡所在的部位,已严重破碎、松弛,岩石似大块石堆垒状,坡面上的树木均明显地向小曼萨河方向倾倒。经地质力学配套分析,堑坡所依附的山梁形成于红河深大断裂生成期(γ4),堑坡岩体受多期构造活动的作用,其中NW65/°SW64°及NW63/°SW35°两组倾向临空的构造面控制坡体的稳定。堑坡具备发生变形破坏的地质条件,分析认为由于组成坡体的岩土强度不足而引起既有构造面的大型坍塌。连续降雨及温差是诱发因素。基于目前国内边坡防治技术、施工能力,提出了以“治”或“避”为主的防治对策。     

桩锚支挡体系在广西寨-任二级公路高边坡治理工程中的应用

(六)寨-(水)任二级公路施工后,滑坡、坍塌、崩塌现象甚多,边坡治理迫在眉睫。桩锚支挡体系是一项主动性加固边坡技术,具结构轻巧、用材合理、施工简单、工期短、费用低等特点。论文通过其在(六)寨-(水)任二级公路K56段高边坡治理工程中的应用,对桩锚支挡体系的设计及施工要点作了介绍。     

华南下寒武统镍钼矿层中铜铅锌矿物的发现及意义

华南扬子地块是我国古热水沉积成矿作用最为发育的地区之一,其热水沉积特性最早引起我国学者的关注。华南下寒武统黑色岩系中赋存多个与热水沉积成矿作用相关的大型、超大型重晶石矿床与N i-Mo-U-V多金属富集层。进一步研究分布在华南扬子地块黑色岩系中的金属、非金属矿床成因及其地球化学特征,对认识华南乃至全球晚震旦—早寒武世生物与环境演化有着十分重要的意义。本文对华南下寒武统镍-钼富集层矿石进行电子探针研究,识别出黄铜矿、黝铜矿等铜的独立矿物;闪锌矿等锌的独立矿物;方铅矿、白铅矿等铅的独立矿物。研究表明,在镍-钼矿石中这些矿物的发现为镍-钼矿层是热水沉积作用产物提供了直接的矿物学证据。     

青海南部杂多-治多一带发现早石炭世Eostaffella动物群

在青海省南部治多-杂多一带1:25万区域地质填图中,于杂多群中首次发现筵类化石2属13种(含未定种、比较种).生物群以个体较小的Eostaffella属为主,地质时代为早石炭世大塘期-德坞期,与华南、藏东、塔里木盆地、西秦岭、俄罗斯等地同期生物群可很好地对比,属于低纬度暖水型特提斯生物群.     

高分辨率格网空间重力异常的精密确定

介绍高分辨率格网空间重力异常精密确定的方法,并利用深圳及周边地区5 213个高精度实测重力值、高分辨率数字地形模型和WDM94地球重力场模型,采用移去-恢复技术和加权平均法计算深圳市1 km和2 km分辨率的格网空间重力异常.计算结果表明:该地区1 km和2 km分辨率的格网空间重力异常的精度分别为±1.560 mGal和±4.442 mGal.1 km分辨率的格网空间重力异常成果已应用于该地区似大地水准面的精化,产生了较大的经济效益和社会效益.