Geochemistry of Jinman Copper Vein Deposit West Yunnan province,China—Ⅱ.Fluid Inclusion and Stable Isotope Geochemical Characteristics

The Jinman deposit is a Ag-bearing copper vein deposit located at the north margin of the Lanping-Simao back-arc basin in West Yunnan. Systematic studies of fluid inclusions and stable isotopes are presented in this paper. The filling-replacement stage and the boiling-exhalative precipitation stage of mineralization took place atT ₁ = 140–280°3 andT ₂ = 94–204°C under pressure of (600 – 1200) x 10⁵ Pa. The salinity of ore-forming solutions ranges from 5 wt% –20.8 wt% (NaCl). Sulphide δ³⁴S(CDT) values are in the range of -9.6%.– +11.03%. with a range of 22. 66%. showing an apparent “pagoda”-shaped distribution in histogram. Meanwhile, the δ³⁴S values of the various sulphides are consistent with the characters of isotope equilibrium fractionation, i.e., δ³⁴ S_Py>δ³⁴S_Cp>δ³⁴S_Bn. The TS/TOC ratios of the ores are widely variable between 0.16 and 5.54 with no correlation of any kind can be established. According to the model of Ohmoto, the oxidation-reduction ratios of sulfur species in ore-forming solutions at the two mineralization stages were calculated to be R′₁ = 2.16 x 10^-17 and R′₂ = 1.55 x 10⁴. δ¹³Coo₂(PDB) values obtained from fluid inclusions in calcite and quartz are between -8.12%.-3.18%., averaging -5.26%., which are comparable with the isotopic composition of mantle-derived CO₂. Inclusions in quartz yield δ¹³CCH₄ (PEB) between -32. 11%. and -22.04%. (averaging -26.69%.), similar to that of methane in modern geothermal gases. For the ore-forming solutions, δ¹⁸ OH₂O (SMOW) values are between -10.57%. and +9.77%. and δDH₂O (SMOW) are between -51%. and -135%. Considering the effect of isotope exchange during water-rock reactions, most of the data are plotted along or close to the line defined by the reaction of meteoric water with clastic rocks, while a small part of the points fall near the reaction line of magmatic water with clastic rocks. In δ¹³C vs. δ18O diagram, the ore-forming solutions are plotted for the most part into the mixing area between the meteoric fluid and the deep-seated fluid and partially on the mixing line of P = 1. This project was founded by the “Eighth Five-Year Plan Period” State Key Program (85–901) and the Open Lab. of Ore Deposit Geochemistry, Chinese Academy of Sciences.     

南海深海柱状沉积物中孢粉和藻类研究及古环境意义

对南海东南部323站深海柱状剖面高分辨率孢粉和藻类进行了研究，将323站从下至上划分为4个孢粉组合带，依次为：1带：Polypodiaceae-Piaceae-Pinus-Quercus（常绿）－Dacrydium-Gramineae；2带：Dicranopteris-Quercus(常绿）－Pinus-Polypodiaceae-Cyathea；3带：Polyodiaceae-Pinus-Cyperaceae-Quercus（常绿）－Lycopodium；4带：Dicranopteris-Pteridinium-Pinus-Cyathea-Polypodiaceae。并相应恢复了南海75000a以来4个植被、气候演替阶段，依次为：暖热而稍干的热带北缘半常绿季雨林－炎热、湿润的热带季雨林－暖热而稍干的热带北缘半常绿季雨林－炎热、湿润的热带季雨林，结合氧同位素测年资料，对323站地层时代划分作了讨论，为南海古气候、古环境演变研究提供了科学的依据。     

脱羧法测定硫酸多糖911的含量

该文采用氧瓶燃烧法测定了硫酸多糖 911的硫 ( S% )含量 ,根据所测硫含量确定了硫酸多糖 911的平均单体式量 ,然后在此基础上应用脱羧法对硫酸多糖 911样品的含量进行了测定。     

春末黄东海域溶解氧垂直结构及氧最大值初步分析

根据1987年5～6月中日合作对黄东海域进行综合调查的溶解氧资料,讨论了该海区溶解氧垂直结构及氧最大值分布。指出在南黄海北部、中部及东海北部和中部的中层存在明显的溶解氧垂直分布最大值,它总是和冷水同存。并对氧最大值及垂直结构同温跃层及冷暖水之间关系进行了初步分析。     

去眼柄对凡纳滨对虾(Litopenaeus vannamei)稚虾耗氧率昼夜节律的影响

采用流水装置测定去眼柄对凡纳滨对虾稚虾 (Litopenaeusvannamei)耗氧率昼夜节律的影响。实验水温为 2 5℃± 0 .5℃ ,实验虾规格为 (2 .2 6 6± 0 .0 13) g。实验结果表明 :1、去眼柄对凡纳滨对虾稚虾耗氧率的高峰和低峰发生的时间产生影响。正常组对虾耗氧率的高峰多发生在夜间 ,低峰多发生在日间 ;去眼柄后 ,对虾耗氧率的高峰和低峰则大都发生在日间 ;2、去眼柄对虾的日间和夜间的平均耗氧率差异不显著 (P >0 .0 5 ) ,而正常对虾夜间平均耗氧率显著高于日间 34.79% (P <0 .0 5 ) ;3、去眼柄对对虾的平均耗氧率未产生显著的影响(P >0 .0 5 )。     

光度法测定低含量有机硫化合物

提出用氧瓶燃烧－光度法来测定有机物中硫含量的定量分析方法，在低硫酸根浓度范围内（４～２５ｍｇ／ｌ），在浓碱条件下ＭＴＢ（甲基百里酚蓝）的吸光度与硫酸根浓度在４６０ｎｍ波长处呈正相关，而在６００ｎｍ（或６１０ｎｍ）处Ｂａ－ＭＴＢ络合物的吸光度与硫酸根浓度呈负相关。该方法标准偏差低于０．５ｍｇ，／ｌ．变异系数低于３％，回收率为９５－１０７％。     

采用孔隙水的氧同位数分馏和δ^18O异常估算天然气水合物含量

大西洋西部布莱克海岭ODP164航次994，997钻孔沉积物孔隙水δ^18O值在上部200mbsf为0.3--0.5‰（SMOW），随深度增加而出现下降趋势；然后在含水合物带（200-450mbsf)出现明显的正异常波动，△=0.2-0.5‰，最后随深度从-0.4‰增加到700mbsf时的-0.2‰。含流水作业事物带δ^18OIW的正偏移可能是沉积物岩心中水合物分解造成的，天然气水合物样品富δ^18O,δ^18O值为2.7-3.5‰，水合物和其周围孔隙水的δ^18O值算得，在12-16℃，31MPa(海平面下3km)条件下的其分馏系数为1.0034-1.0040。根据该分馏系数和布莱克海岭水合物带同位数异常推算，该沉积物孔隙中水合物的饱和度为6-12%。     

RY-3溶氧仪测试结果分析

给出了作者研制的ＲＹ－３溶解氧测试仪的银极电位与美国ＹＳＩ－５８溶氧仪的银极电位（在海水中均以甘汞电极为参比电极）对比测试的误差分析，对ＲＹ－３溶氧仪与ＹＳＩ－５８溶氧仪现场对比测试的结果进行误差分析。并介绍了国家标准物质研究中心和青岛计量测试所对ＲＹ－３溶氧仪的测试结果。     

太平洋三海区热液烟囱物的氧同位素

使用氧同位素方法,测试了西太平洋马里亚纳岛弧、马里亚纳海槽、冲绳海槽和东太平洋加拉帕戈斯裂谷的海底热液烟囱和硫化物全岩样品.结果表明马里亚纳岛弧上的埃斯梅拉尔达破火山口的热液硫化物的形成温度最高(达275℃),而成为高温产物的代表;冲绳海槽和加拉帕戈斯裂谷烟囱,表现为中高温类型,其氧同位素温度在150℃