Jahn-Teller configurations in natural spinels

The local configurations and related hyperfine interactions of the tetrahedrally coordinated Fe²⁺ in two natural spinels were investigated. A special fitting procedure of the Mössbauer spectra is proposed in order to cover the involved mechanisms over the whole temperature range. The behavior of the quadrupole splitting vs temperature was successfully explained in terms of the split of the electronic 3d ground state doublet under a non-cooperative Jahn-Teller effect also providing estimates of the splitting energy for each configuration.     

Point defects and cation tracer diffusion in (Ti x Fe 1?x ) 3?δ O4 1. Non-stoichiometry and point defects

 The deviation from stoichiometry, δ, in spinel solid solutions of the type (Ti _x Fe _1−x )_3−δ O₄ with x=0.1, 0.2 and 0.25 was studied thermogravimetrically as a function of oxygen activity, a _O2, at 1100, 1200 and 1300 ^∘C. The experimental results, S-shaped curves for δ vs. log a_O2, are presented and discussed with regard to the type of point defects prevailing under different conditions in the deviation from stoichiometry. It is concluded that cation vacancies are the predominant point defects at high oxygen activities, while cation interstitials prevail at low oxygen activities. The temperature and composition dependencies of point defect concentrations are also discussed. Received: 1 October 1996 / Accepted: 15 September 2002 Acknowledgements The authors thank the US Department of Energy for support of this work under Grant no. DE-FGO2–88ER45357. This work made use of the Cornell Center of Materials Shared Experimental Facilities, supported through the National Science Foundation Materials Research Science and Engineering Centers program (DMR-0079992).     

Distribution of Fe2+ and Fe3+ and next-nearest neighbour effects in natural chromites: comparison between results of QSD and Lorentzian doublet analysis

The Mössbauer spectra of one chromite at 298 K and one chromite at 298, 200, 170, 140 and 90 K have been analyzed in this study. A Voigt-based quadrupole splitting distribution (QSD) method was used to analyze the spectra. The tetrahedral site Fe²⁺ and the octahedral site Fe³⁺ quadrupole splitting distributions (QSDs) were obtained from the Mössbauer spectra of chromites, and the multiple tetrahedral site Fe²⁺ Gaussian QSD components and the large widths σ _Δ of the Gaussian QSD components of the tetrahedral site Fe²⁺ QSDs for chromites were attributed to next-nearest neighbor effects. In addition, temperature dependences of the isomer shift and the quadrupole splitting were presented and discussed. Comparisons between the Mössbauer parameters for thickness-corrected folded spectra and raw-folded spectra of chromites were made, and the results show that the two sets of the Mössbauer parameters and ratios of ferric to total iron as well as χ² are very close to each other. This is because of the small absorber thickness of chromites in this study. Comparisons between the Mössbauer parameters of chromites obtained using the Voigt-based QSD method and a Lorentzian doublet method were also made. The results show that there are some differences between the two sets of the Mössbauer parameters and ratios of ferric to total iron, but not significant. However, much larger χ² were obtained when the Lorentzian doublet method was used to fit the spectra of chromites. This indicates that the Voigt-based QSD method is more adequate to analyze the Mössbauer spectra of chromites from the point of view of statistics.     

黄土状盐渍土的工程特点及地基处理方法

黄土状盐渍土在西北地区诸省均有分布。通过工程实例分析，论述了黄土状盐渍土的工程特点，指出了在西部大开发过程中对黄土状盐渍土的勘察设计应该注意的问题，并提出相应的处理方法。     

Just a train-ride away, but still worlds apart: Prospects for the Øresund region as a binational city

This article considers whether the cities of Copenhagen, Denmark and Malmö, Sweden, recently joined by the Øresund bridge, ought to be considered as one binational city. Working from the assumption that the project of constructing this binational city is a top-down endeavor whose success ultimately rests on the degree of support it receives from regional inhabitants, I focus on public opinion survey data collected one year after the opening of the bridge. Analysis shows that there are sharp national differences in the amount of support for the construction of a binational greater metropolitan region. I discuss how these differences may lead to an asymmetrical development for the emerging binational city, with Malmö eclipsed by the Danish capital Copenhagen, as well as how the heavily multi-cultural population of Malmö can impact Danish-Swedish cooperation on the Øresund.     

沉积物中~（210）Pb的测量方法

本文介绍了一种测定积物中２１０Ｐｂ的方法．沉积物中的２１０Ｐｂ用ＨＮＯ３和ＨＦ消化，然后２１０Ｐｏ在８５～９０℃下从０．５ｍｏｌＨＣｌ介质中自沉积在银片上；其全程放化回收率为８５．０±４．９×１０－２     

El Niño/Southern Oscillation (ENSO) Related Variations in Particulate Export Fluxes in the Western and Central Equatorial Pacific

Time-series data from sediment trap moorings intermittently deployed during 1991–1999 show that the fluxes of biogenic material (carbonate, opal and organic matter, including amino acids) and other related parameters are temporally and spatially distinct across the Western Pacific Warm Pool (WPWP). These variations resulted from the El Niño and La Niña conditions, which alternately prevailed over the equatorial Pacific Ocean during the mooring deployments. The westernmost WPWP (a hemipelagic region) recorded relatively high average total mass and amino acid fluxes during the El Niño event. This was in sharp contrast to the eastern part of the WPWP (oligotrophic and weak upwelling regions) which recorded higher flux values during the La Niña event. Settling particulate organic matter was rich in labile components (amino acids) during La Niña throughout the study area. Relative molar ratios of aspartic acid to β-alanine together with relative molar content of non-protein amino acids β-alanine and γ-aminobutyric acid) suggested that organic matter degradation was more intense during La Niña relative to that during El Niño in the WPWP. This study clearly shows that during an El Niño event the well documented decrease in export flux in the easternmost equatorial Pacific is accompanied by a significant increase in export flux in the westernmost equatorial Pacific Ocean.     

导航型GPS在海上地球物理勘探中的应用──卫导数据随机噪声处理

分析了导航型GPS在海上地球物理勘探应用中存在的问题，着重研究了卡尔曼滤波对号航数据中航向和航速的处理；提出两种滤波模型，对模拟的导航数据和真实航行数据进行计算，并将结果用于重力测量数据的Eotvos改正，对出现的问题进行了讨论。文章提出适当的处理方法，使导航型GPS适应海上地球物理勘探的要求，提高了导航精度和满足测量了精度。     

Ocean variability North of New Guinea derived from TRITON buoy data

We investigated variability in the ocean surface-subsurface layer north of New Guinea using Triangle Trans-Ocean Buoy Network (TRITON) buoys at 2°N, 138°E and 0°N, 138°E during the period from October 1999 to July 2004. Both North and South Pacific waters were observed below the subsurface at these stations. The variability in the subsurface waters was particularly high at 2°N, 138°E. Clear interannual variability occurred near the surface; the water type differed before and after onset of the 2002–03 El Niño. Before summer 2001, water that appeared to be advected from the central equatorial Pacific occupied the near surface layer. After autumn 2001, waters advected by the New Guinea Coastal Current were observed near the surface. Intraseasonal and seasonal variations were also observed below the subsurface. With regard to seasonal variability, the salinity of the subsurface saline water, the South Pacific Tropical Water, was generally high during the boreal summer-autumn, when the New Guinea Coastal Undercurrent was strong. Intraseasonal fluctuations on a scale of 20 to 60 days were also seen and may have been associated with intrinsic oceanic variability, such as ocean eddies, near the stations. Ocean variability in the thermocline layer between 100 and 200 m greatly affects the surface dynamic height variability; water variability before 2001 and variability in the pycnocline depth after 2002 are important factors affecting the thermocline.