Environmental monitoring of magnetic iron phases of urban water reservoir lake sediments (Taiaçupeba Lake,metropolitan region of São Paulo,Brazil) by using Mössbauer spectroscopy

In the present work, we investigate the iron oxides and oxyhydroxides behavior and evolution, related to the geochemical behavior of some metals, which could be retained as solid phases in the sediments from an urban water reservoir lake, placed in Taiaçupeba, Great São Paulo, Brazil. These tasks were performed by the establishment of a proceduring setting for environmental monitoring analysis through Mössbauer spectroscopy measurements associated to hysteresis loops measurements and chemical analysis [X-ray fluorescence (XRF)]. We inferred the possibility of goethite occurrence in broad particle size distribution (5–50 nm), and related to ferrihydrite, and small grain-size hematite (about 8 nm). The magnetometry results pointed to the paramagnetic/superparamagnetic behavior of the magnetic phases present in the samples and also suggested the occurrence of small grain-size magnetite. We also verified the presence of clay minerals related to Fe, as well as the occurrence of Fe³⁺ and/or Fe²⁺ in short-range structural order. Through a straight correlation among Mössbauer spectra data gained at T = 77 K and Al-metal, metal-Fe molar ratios, provided through XRF data, we found remarkable indications of interference on meta-stable phases evolution to its final products. Such results can be pointing for evidences about the possible isomorphic replacing and/or adsorption of Al and other metals in goethite and hematite.     

Optimal Precursor Perturbations of El Ni?o in the Zebiak-Cane Model for Different Cost Functions

Optimal precursor perturbations of El Ni?o in the Zebiak-Cane model were explored for three different cost functions. For the different characteristics of the eastern-Pacific(EP) El Ni?o and the central-Pacific(CP) El Ni?o, three cost functions were defined as the sea surface temperature anomaly(SSTA) evolutions at prediction time in the whole tropical Pacific, the Ni?o3 area, and the Ni?o4 area. For all three cost functions, there were two optimal precursors that developed into El Ni?o events, called Precursor I and Precursor Ⅱ. For Precursor Ⅰ, the SSTA component consisted of an east-west(positive-negative) dipole spanning the entire tropical Pacific basin and the thermocline depth anomaly pattern exhibited a tendency of deepening for the whole of the equatorial Pacific. Precursor I can develop into an EP-El Ni?o event, with the warmest SSTA occurring in the eastern tropical Pacific or into a mixed El Ni?o event that has features between EP-El Ni?o and CP-El Ni?o events. For Precursor Ⅱ, the thermocline deepened anomalously in the eastern equatorial Pacific and the amplitude of deepening was obviously larger than that of shoaling in the central and western equatorial Pacific. Precursor Ⅱ developed into a mixed El Ni?o event. Both the thermocline depth and wind anomaly played important roles in the development of Precursor Ⅰ and Precursor Ⅱ.     

华南冬季气温异常与ENSO的关系

利用1951一2012年华南192个测站逐月气温资料、NCEP/NCAR再分析月资料、NCC的ENSO监测资料,采用相关分析和合成分析等方法分析了华南冬季气温异常与ENSO的关系。结果表明:华南冬季气温对La Nina事件的响应比对E1 Nino事件显著,La Nina事件当年华南冬季气温以偏低为主,极强La Nina事件对应的华南冬季气温显著偏低,而中部型La Nina事件出现过华南冬季气温显著偏高的情况。当La Nina(El Nino)事件为东部型、Nino区海温异常的峰值月份出现在秋冬季,当年华南冬季气温易偏低(高)。从年际尺度上,当La Nina发生时,在对流层低层激发西太平洋异常气旋环流和北风异常,对应对流层中层北太平洋高压、乌拉尔山高压脊和东亚大槽南段均加强,西太平洋副热带高压减弱,东亚中高纬经向环流明显,冬季风偏强,导致我国大部分地区包括华南冬季气温偏冷,反之亦然。El Nino事件对华南冬季气温的影响具有年代际差异。对应华南冬季气温年代际变化的海温变化明显的区域位于北太平洋,而与ENSO关系不明显。     

A POSSIBLE IMPACT OF EL NIO MODOKI ON SEA SURFACE TEMPERATURE OF CHINA'S OFFSHORE AND ITS ADJACENT REGIONS

El Nio Modoki,similar to but different from canonical El Nio,has been observed since the late1970s.In this paper,using HadISST and NCEP/NCAR wind data,we analyze the relationship between El Nio Modoki and Sea Surface Temperature(SST)in the offshore area of China and its adjacent waters for different seasons.Our results show a significant negative correlation between El Nio Modoki in summer and SST in autumn in the offshore area of China and its adjacent waters,particularly for regions located in the east of the Kuroshio.It is also found that during El Nio Modoki period,anomalous northerlies prevail over the regions from the northern part of the Philippines to the offshore area of China,indicating that the northerlies are unfavorable for the transport of warm water from the western tropical Pacific to the mid-latitude area.Consequently,El Nio Modoki in summer may play a substantial role in cold SST anomalies in the offshore area of China and its adjacent waters in autumn through the influence of the Kuroshio,with a lagged response of the ocean to the atmospheric wind field.     

响应面法优化重组大肠杆菌生物合成别藻蓝蛋白(holo-apcA)的发酵条件

采用响应面法对重组大肠杆菌生物合成别藻蓝蛋白(holo-apc A)的发酵条件进行优化,提高了蛋白的表达量。以对重组别藻蓝蛋白α亚基在大肠杆菌中表达量影响较大的几种因素用于中心组合设计;中心组合设计试验结果表明诱导温度、培养基初始p H和诱导时机对诱导结果影响显著;经Design Expert 8.0软件优化后的最佳诱导条件为:诱导温度28℃,培养基初始p H 8.5,IPTG终浓度0.1 mmol/L,以及诱导时机3 h。最后验证试验得到的蛋白表达量在已有文献报道结果的基础上提高了70%~580%。中心组合设计-响应面法能够在有限的实验次数下,对影响生物过程的因子进行优化及对其交互作用进行评价,蛋白表达量达20.4 mg/L;IPTG用量由原来的1 mmol/L减少至现在的0.1 mmol/L,降低了发酵成本。     

Emission Line Profiles of Warped Disks in the Kerr Spacetime

The calculations of emission line pro?les of a warped disk in the Kerr spacetime have been discussed in this paper. The main content consists of two parts. In the ?rst part, the geodesic motion in the Kerr spacetime and the equations of motion in integral form, as well as the method to obtain the solution with the Weierstrass’ elliptic functions are presented. Using the Weierstrass’ elliptic functions, the Boyer-Lindquist (B-L) coordinates and the affine parameter o are semi-analytically expressed as the functions of a parameter p. Then a code named ynogk (Yunnan Observatory Geodesic Kerr) is introduced based on the above discussions to calculate very fast the null geodesic in the Kerr spacetime. As an application of ynogk, the emission line pro?les of warped disks are investigated in detail in the second part of this paper. Here the structure model of warped disks is based on the results of Bardeen and Petterson in 1975, and the line pro?les are computed with the ray tracing method. Finally, the discussions and conclusions of the calculated results are presented. It is indicated that the line pro?les are dependent mainly on the inclination and azimuthal angles of the observer, as well as the index of emissivity, and that they may have a triple-peaked even multi-peaked structure, different from the double-peaked structure in the line pro?les of a standard thin accretion disk.     

SHRIMP U–Pb zircon ages and whole-rock geochemistry for the Şapçı volcanic rocks,Biga Peninsula,Northwest Turkey: implications for pre-eruption crystallization conditions and source characteristics

Palaeogene and Neogene volcanic rocks are widespread on the Biga Peninsula of Northwest Turkey. These rocks were formed during the Eocene, Oligocene–Miocene, and late Miocene, and the early Miocene ?apç? volcanic rocks in the Bal?kesir area consist of andesitic lava flows and associated pyroclastics. Temperatures, pressures, and oxygen fugacities calculated for the hornblendes in these andesitic rocks are 903–930°C, 3.3–4.8 kbar, and –9.91 to –11.88, respectively, and for the biotites they are 755–788°C, 1.30–1.74 kbar, and –14.88 to –13.98, respectively. SHRIMP U–Pb dating of zircons from three andesite samples gave ages of 22.72 ± 0.19, 22.97 ± 0.23, and 18.72 ± 0.17 Ma (early Miocene), and these are regarded as crystallization ages. Geochemical analyses show that the volcanic rocks are mainly high-K and calc-alkaline, and have high contents of large-ion lithophile elements and low contents of high-field strength elements, revealing that they evolved from parental magmas that were derived from an enriched subcontinental lithospheric mantle source. The chondrite-normalized rare earth element patterns of the rocks are concave upwards with La_CN/Lu_CN = 11.9–21.2 and Eu_CN/Eu* = 0.84–0.92, implying significant fractional crystallization of hornblende during their evolution. According to the petrological data with regional geology, Neogene magmatic activity on the Biga Peninsula has a post-collisional feature, and was closely related to slab break-off geodynamic model after collision of Tauride–Anatolide Block and Sakarya continent.     

青藏高原东北缘若尔盖盆地晚新近纪沉积的岩石地层学

通过野外地质填图和系统取样,以岩石地层特征为基础,以新构造运动为背景,按照多重地层划分观点,本文首次对若尔盖盆地晚新近纪岩石地层的对比和划分做了深入的研究。对黄河干流、白河支流和黑河支流水系的河道堆积岩石的典型剖面的研究,表明更新-全新世的不同发展阶段具有不同的特征;相同时期不同水系的沉积物也不尽相同,反映出盆地晚新近纪地层的发育过程及空间上的差异。对冰川堆积终碛垄测年等研究反映出末次盛冰期和全新世中几次较强的寒冷事件,并划分出4套冰碛层。综合前人的古脊椎动物化石和¹⁴C、TL、OSL和ESR等同位素测年资料,将为进一步提出研究区晚新近纪年代地层的划分奠定基础。     

Sea surface temperature anomaly in the tropical North Atlantic during El Nino decaying years

基于1979年到2016年多种再分析资料,本文分析了El Ni?o衰减年热带北大西洋的海温异常.结果表明,热带北大西洋海温在此期间呈显著变暖趋势.10次El Ni?o事件的合成结果表明热带北大西洋海温异常在El Ni?o事件峰值之后的春季达到最大值,并持续到夏季.一般而言,这种异常与三个因子有关,即El Nino,北大西洋涛动和长期趋势,能分别导致局地海温上升0.4℃,0.3℃和0.35℃.1983年和2005年的对比分析表明,尽管El Ni?o强度对春季北大西洋海温起到决定性作用,与长期趋势密切相关的前冬海温也很重要.此外,超前-滞后相关结果表明北大西洋涛动超前海温约2-3个月.比较两个冬季相反位相北大西洋涛动的年份(即1992年和2010年),表明北大西洋涛动也能调制北大西洋海温异常.冬季负位相北大西洋涛动能显著增强El Ni?o的强迫影响,反之亦然.换言之,如果北大西洋涛动与El Ni?o位相相合,衰减年北大西洋海温异常才更为显著.因此,为全面理解热带北大西洋海温变化,除长期趋势外,还必须考虑El Ni?o和北大西洋涛动的综合影响.     

IMPACT OF LATENT HEAT FLUX ON INDIAN SUMMER MONSOON DURING EL NI?O/LA NI?A YEARS

El Nio or La Nia manifest in December over the Pacific and will serve as an index for the forecasting of subsequent Indian summer monsoon,which occurs from June to mid-September.In the present article,an attempt is made to study the variation of latent heat flux (LHF) over the north Indian Ocean during strong El Nio and strong La Nia and relate it with Indian monsoon rainfall.During strong El Nio the LHF intensity is higher and associated with higher wind speed and lower cloud amount.During El Nio all India rainfall is having an inverse relation with LHF.Seasonal rainfall is higher in YY+1 (subsequent year) than YY (year of occurrence).However there is a lag in rainfall during El Nio YY+1 from June to July when compared with the monthly rainfall.