Improvement in the calculation of anti-Stokes energy transfer and experimental justification based on Er0.01YbxY1 - 0.01 - xVO4 crystal

The improvement on the calculation of anti-Stokes energy transfer rate is studied in the present work. The additional proportion coefficient between Stokes and anti-Stokes light intensities of quantum Raman scattering theory as compared with the classical Raman theory is introduced to successfully describe the anti-Stokes energy transfer. The theoretical formula for the improvement on the calculation of anti-Stokes energy transfer rate is derived for the first time in this study. The correctness of introducing coefficient exp{ΔE / kT} from well-known Raman scatter theory is demonstrated also. Moreover, the experimental lifetime measurement in Er_0.01Yb_xY_{1 - 0.01 - x}VO₄ crystal is performed to justify the validity of our important improvement in the original phonon-assisted energy transfer theory for the first time.     

南召县石鼓金矿地质特征及成因探讨

石鼓金矿位于北秦岭复杂褶皱带东段,乔端-瓦穴子断裂南侧,牧虎顶花岗岩体之北侧,矿脉的产出受断裂构造控制.矿脉数量多,规模大小不一,成矿与构造岩浆活动等关系密切.矿床类型为石英脉型.     

柱撑蛭石吸附去除废水中重金属离子的实验研究

分别利用有机柱化剂十二烷基磺酸钠(SDS)和无机柱化剂聚羟基铝(HA)对蛭石进行柱撑制得十二烷基磺酸钠柱撑蛭石(SDS-V erm icu lite)和聚羟基铝柱撑蛭石(HA-V erm icu lite),并通过XRD、红外光谱、ZETA电位等表征手段对柱撑蛭石进行表征,同时针对柱撑蛭石对Cu2 ,Cd2 ,C r3 3种重金属离子的吸附进行研究,结果表明:吸附去除率受反应时间、重金属离子的初始浓度、pH值等因素的影响,经柱撑后的蛭石对重金属离子吸附的吸附性能比蛭石原矿要强。柱撑蛭石吸附3种重金属离子的动力学吸附过程可用E lov icb方程和双常数方程进行较好的拟合。     

西藏申扎县甲岗雪山钨、钼、铋多金属矿床稳定同位素地球化学特征及矿床成因探讨

冈底斯成矿带是西藏重要的多金属成矿区之一,在该成矿带北部申扎县首次发现的甲岗雪山钨、钼、铋多金属矿床是不同于其南部斑岩型铜多金属矿床的成矿新类型,该矿床的发现是藏北地区内生金属矿找矿的重要突破.文章对该矿床矿石稳定同位素地球化学特征进行研究表明:成矿流体主要来源于岩浆岩,围岩(地层)可能只提供了少量成矿物质;该矿床硫的来源单一,属于岩浆硫范畴,矿石与围岩中的硫具有相同的来源;铅的来源以地壳铅为主,并混有少量地幔铅.根据上述研究,结合矿床地质特征及同国内外同类型矿床的对比,认为甲岗雪山多金属矿床是在大陆碰撞后陆内伸展构造背景下,形成于喜马拉雅中期中酸性岩浆活动阶段,矿质主要源自岩浆的石英大脉型钨、钼、铋多金属矿床.     

近区瞬变场的频率效应与大深度探测能力的研究

在时域中,磁源近区瞬变场的时间特性取决于场源所含低频谱的分数幂.对于磁感应强度Bz(t)∝∑iω3/2i,对于感应电势εz(t)∝∑iω5/2i.这表明,现有的瞬变电磁探测系统只适用于浅部勘查,对于大深度的勘查,需要研制超强能量且轻便化的场源(发送系统),同时完善超导磁强计(接收系统)的实用化.     

浅论赣北九瑞铜金矿集区的资源潜力

九瑞矿集区是长江中下游铜金成矿带的重要组成部分.数十年来,几代地质和矿山工作者为探明其矿产资源,作出了不懈的努力,取得了巨大成果.但近年来,随着勘探难度的加大,该区矿床勘查和研究处于"半停滞"状态.文章运用前人的科研资料,结合近期的工作成果,用"铜金矿集区"的概念和观点,阐述了矿集区的特征,总结了其控矿因素和成矿规律,分析了九瑞铜金矿集区的成矿系统和资源潜力.     

西部某水电站坝区采空区的工程效应研究

通过对西部某水电站的地质环境分析,揭示了采空区分布特征.对溢洪道进行数值模拟,研究采空区上覆岩层的影响范围,分析采空区对溢洪道的影响.最后综合分析采空区对水电站不同工程部位的危害,提出相应的处理措施.     

新疆彩霞山铅锌矿床硫、碳、氢、氧同位素地球化学

文章通过对彩霞山铅锌矿床硫、碳、氢、氧同位素的研究,探讨了矿床成矿流体来源及演化,揭示了成矿作用过程中的某些重要信息.初步认为矿石中的硫主要来自同化了海水硫酸盐的岩浆硫,同时有少量生物还原硫参与;碳、氧同位素组成指示碳来源于壳幔混合.成矿流体以建造水为主,早期有岩浆水参与.     

Polar constituents of organic matter rich marls from evaporitic series of the Mulhouse basin

A suite of marl samples from the evaporitic series of the Mulhouse basin (France; Lower Oligocene) was studied for its biomarker content, in particular its polar constituents. Novel series of 3-carboxyalkyl steranes and 15-oxo triaromatic ketones were identified by synthesis. The 3-carboxyalkyl steranes probably originate from highly polar precursors yet unreported in living organisms. Our data suggest that micro-algae could be the major source of these compounds which seem to be indicators of high algal input rather than characteristic of evaporitic environments. The 15-oxo triaromatic ketones could be oxidation products of triaromatic steroid hydrocarbons formed during diagenesis, although their formation during work-up procedure could not be excluded.     

滇东黔西晚二叠世早期辫状河三角洲沉积体系及其聚煤特征

滇东黔西上二叠统底部发育着一套玄武岩质砾岩，本文针对云南富源和贵州盘县一带的底砾岩进行综合研究，认为这套砾岩为辫状河三角洲沉积，并进一步识别出砾质辫状河道、砂质辫状河道、砾质河口坝、砂质河口坝等沉积类型。文中还对该辫状河三角洲的沉积序列、发育背景以及与聚煤作用关系等问题做了一定分析，认为三角洲朵体之间地区以及在衰退的三角洲朵体之上成煤较好。