柱撑蛭石吸附去除废水中重金属离子的实验研究

分别利用有机柱化剂十二烷基磺酸钠(SDS)和无机柱化剂聚羟基铝(HA)对蛭石进行柱撑制得十二烷基磺酸钠柱撑蛭石(SDS-V erm icu lite)和聚羟基铝柱撑蛭石(HA-V erm icu lite),并通过XRD、红外光谱、ZETA电位等表征手段对柱撑蛭石进行表征,同时针对柱撑蛭石对Cu2 ,Cd2 ,C r3 3种重金属离子的吸附进行研究,结果表明:吸附去除率受反应时间、重金属离子的初始浓度、pH值等因素的影响,经柱撑后的蛭石对重金属离子吸附的吸附性能比蛭石原矿要强。柱撑蛭石吸附3种重金属离子的动力学吸附过程可用E lov icb方程和双常数方程进行较好的拟合。     

The behaviour of dissolved organic material,iron and manganese in estuarine mixing

Fractionation by ultra-filtration of the dissolved organic material (DOM) in the River Beaulieu, with typical concentrations of dissolved organic carbon (DOC) of 7–8 mg C/l, showed it to be mainly in the nominal molecular weight range of 10³–10⁵, with 16–23% of the total DOC in the fraction > 10⁵. The molecular weight distribution of DOM in the more alkaline River Test (average DOC, 2 mg C/l) was similar. In the River Beaulieu water, containing 136–314 βg Fe/l in ‘dissolved’ forms, 90% or more of this Fe was in the nominal molecular weight fraction > 10⁵. Experiments showed that DOM of nominal molecular weight <10⁵ could stabilize Fe(III) in ‘dissolved’ forms. The concentrations of ‘dissolved’ Fe in the river water probably reflect the presence of colloidal Fe stabilized by organic material and this process may influence the apparent molecular weight of the DOM. Dissolved. Mn (100–136 βg/l) in the River Beaulieu was mainly in true solution, probably as Mn(II), with some 30% in forms of molecular weight greater than ca 10⁴.During mi xing in the Beaulieu Estuary, DOC and dissolved Mn behave essentially conservatively. This contrasts with the removal of a large fraction of the dissolved Fe (Holliday and LISS, 1976, Est. Coastal Mar. Sci. 4, 349–353). Concentrations of lattice-held Fe and Mn in suspended particulate material were essentially uniform in the estuary, at 3.2 and 0.012%, respectively, whereas the non-lattice held fractions decreased markedly with increase in salinity. For Mn the decrease was linear and could be most simply accounted for by the physical mixing of riverborne and marine participates, although the possibility that some desorption occurs is not excluded. The non-linear decrease in the concentration of non-lattice held Fe in particulates reflected the more complex situation in which physical mixing is accompanied by removal of material from the ‘dissolved’ fraction.     

Electrical resistivity and 57Fe Mössbauer spectra of Fe-bearing calcic amphiboles

Electrical resistivity and ⁵⁷Fe Mössbauer spectra are reported for three calcic amphiboles with different Fe concentrations. AC measurements (20?Hz–1?MHz) were performed, applying impedance spectroscopy between 100 and 785?°C in an N₂ gas atmosphere. It was found that up to three semiconducting charge transport processes can be distinguished, which in part changed slightly when several runs were carried out to higher temperatures. The extrapolated DC resistivity is much smaller for an amphibole with high Fe content than for the two with lower Fe concentrations. The derived activation energies are between ～0.48 and ～1.06?eV. For temperatures ≤600?°C the results are compatible with a charge transport mechanism due to electron hopping between Fe²⁺ and Fe³⁺. Above 600?°C, dehydrogenation and/or beginning amphibole decomposition obviously alter the conduction mechanism. From Mössbauer spectra it was established that in all amphibole samples Fe²⁺ and Fe³⁺ are simultaneously present. Mössbauer parameters were derived by fitting the observed spectra to models taking the occupation of various M sites into account.     

浙江雷甸淡水无光珠中球文石的首次确认

球文石（Vaterite)是CaCO3很不稳定的同质多象变体，在自然界里很少出现，通过光学显微镜在淡水无光珠中发现球文石尚属首次，本文研究了淡水无光珠内球文石的显微特征、X射线粉晶衍射特征及显微红外光谱特征，研究结果表明淡水无光珍珠内球文石粉晶衍射由强至弱五个强峰的d值为0.3266,0.2723,0.3553,0.1811,0.2057nm；其红外光谱特征波数为1489，1450,1420,1087,1050,876,830,762,743cm^-1。球文石的存在是影响淡水珍珠品质的主要内在因素之一。     

有机酸对长石溶解度影响的热力学研究

为明确认识有机酸（草酸、醋酸）对长石溶解度及储层次生孔隙发育的影响，本文利用热力学方法，计算了不同温度、酸度下钾长石在含有醋酸根0.05mol/L、草酸0.0055mol/L的溶液中的溶解度及草酸和醋酸对溶液酸度的影响，计算的结果表明醒酸根与铝的络合作用只发生在偏酸性的溶液体系中，并且随温度升高要求酸度增加，实际的络合能力降低，醋酸根的络合作用对长石溶解度的增加作用极及有限，最高时不足一倍；但醋酸能有效地缓冲溶液酸度，从而提高长石溶解度。草酸根与铝的络合作用发生在弱碱性至酸性条件下，温度升高，络合能力增加，络合效应对长石溶解度，草酸根上铝的络合作用发生在弱碱性至酸性条件下，温度升高，络合能力增加，络合效应对长石溶出量的增加最多可达2个数量级以上，草酸的浓度太低无法通过缓冲溶液在较高的酸度下来促进长石的溶解，草酸和醒酸能否促进储层次生孔隙的发育取决于盆地流体的酸度及组成流体的缓冲体系。     

节理岩体三维偶应力弹性理论

节理的存在使得岩体的力学特性十分复杂。偶应力理论考虑了介质内颗粒尺度的影响，它以具有一定尺度的微元体为研究对象，引进了偶应力及弯曲曲率的概念，从而考虑了弯曲效应对介质变形特性的影响，可以用来解决岩土工程中的地下洞室底鼓、顶板开裂及反倾向层状岩体的弯曲倾倒等弯曲变形及弯曲破坏问题。本文考虑了节理间距的影响，对节理岩体的空间间题提出了弹性偶应力理论并建立了有限元计算模式，最后通过算例说明用偶应力理论解决上述问题的有效性。     

普通铅同位素演化系统模式

已有的几种普通铅同位素模式仅反映了一些封闭体系铅同位素混合的特殊情况,不便于有效地应用于地质历史时期复杂的地质作用过程。本文应用概率论方法,从理论上分析包括开放体系在内的13种不同系统普通铅同位素混合的23种情况,讨论各种情况下铅同位素资料的地质年代学意义与地质事件发生年代的计算方法,从而建立多阶段铅同位素演化的系统模式。应用读系统模式研究燕山地区的成岩成矿时代,所得结果与其它方法测出的年龄一致。     

1:25万斯诺乌山幅、狮泉河幅地质调查成果与进展

地层方面,在测区札达陆块厘定出念青唐古拉岩群;在措勤-申扎地层分区发现坚扎弄组在测区的存在,新建淌那勒组;将则弄群火山岩解体;根据化石,则弄群弧火山岩的形成时间为早白垩世;确认狮泉河蛇混岩带的形成时间是晚侏罗世—早白垩世;将才里群解体。岩石方面,在测区不同时代地层中发现火山岩系,填绘出了一系列火山机构;将中新生代深成侵入岩划分为拉轨岗日花岗岩带和冈底斯花岗岩带两个岩浆带;发现浆混岩系。构造方面,发现雅鲁藏布江结合带南北支在图区的存在;证实狮泉河带内存在洋脊蛇绿岩套,狮泉河带存在俯冲;确认班-怒带的南支向北与狮泉河带斜接。     

1:25万帕度错幅、昂达尔错幅成果与进展

新建9个正式岩石地层单位、4个非正式地层单位;将上三叠统日干配错群解体为6个岩石地层单元;解体中上侏罗统雁石坪群;将色哇组分为三段;将班公湖-怒江带木嘎岗日群解体为4个岩石地层单元;在西藏首次发现(上三叠统姜钟组)纳拉菁耳羽叶;在羌塘盆地首次发现(下—中侏罗统色哇组)辐鳍鱼类化石;新建8个侵入岩填图单位,时代为晚侏罗世—新近纪末期;在班-怒结合带塔仁本一带首次发现了洋岛型玄武岩;新发现了一系列新生代岩浆岩;在班-怒带及南羌塘盆地中发现一些呈串珠状分布的小型斑岩体;发现班-怒带上时代最新的枕状玄武岩。     

1:25万毕节县幅、遵义市幅地质调查成果与进展

在毕节青场桐梓组顶部至石炭系中发现有大量的暴露构造现象;发现毕节地区中二叠世茅口期存在两条走向北北东、宽10~50km的“黑区带”;在威信县城第四系中发现大量象牙、牙齿及骨骼化石;在凤冈琊川、遵义茅坡及威信鱼井等新发现多个志留纪植物化石;对黔中隆起进行了研究。