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691.
The Solubility of Sulphur in Hydrous Rhyolitic Melts 总被引:1,自引:1,他引:1
Experiments performed at 2 kbar, in the temperature range 8001000°C,with fO2 between NNO2·3 and NNO+2·9 (whereNNO is the nickelnickel oxide buffer), and varying amountsof sulphur added to hydrous metaluminous rhyolite bulk compositions,were used to constrain the solubility of sulphur in rhyolitemelts. The results show that fS2 exerts a dominant control onthe sulphur solubility in hydrous silicate melts and that, dependingon fO2, a rhyolitic melt can reach sulphur contents close to1000 ppm at high fS2. At fO2 below NNO+1, the addition of ironto a sulphur-bearing rhyolite magma produces massive crystallizationof pyrrhotite and does not enhance the sulphur solubility ofthe melt. For a given fO2, the melt-sulphur-content increaseswith fS2. For fixed fO2 and fS2, temperature exerts a positivecontrol on sulphur solubilities, at least for fO2 below NNO+1.The mole fraction of dissolved sulphur exhibits essentiallylinear dependence on fH2S at low fO2 and, although the experimentalevidence is less clear, on fSO2 at high fO2. The minimum insulphur solubility corresponds to the redox range where bothfH2S and fSO2 are approximately equal. A thermodynamic modelof sulphur solubility in hydrous rhyolite melts is derived assumingthat total dissolved sulphur results from the additive effectsof H2S and SO2 dissolution reactions. The model reproduces wellthe minimum of sulphur solubility at around NNO+1, in additionto the variation of the sulphide to sulphate ratio with fO2.A simple empirical model of sulphur solubility in rhyoliticmelts is derived, and shows good correspondence between modeland observations for high-silica rhyolites. KEY WORDS: sulphur; solubility; rhyolite; thermodynamics; fO2; fS2 相似文献
692.
Crustal Growth by Magmatic Accretion Constrained by Metamorphic P-T Paths and Thermal Models of the Kohistan Arc, NW Himalayas 总被引:2,自引:0,他引:2
Magmatic accretion is potentially an important mechanism inthe growth of the continental crust and the formation of granulites.In this study, the thermal evolution of a magmatic arc in responseto magmatic accretion is modeled using numerical solutions ofthe one-dimensional heat conduction equation. The initial andboundary conditions used in the model are constrained by geologicalobservations made in the Kohistan area, NW Himalayas. Takingconsideration of the preferred intrusion locations for basalticmagmas, we consider two plausible modes of magmatic accretion:the first involves the repeated intrusion of basalt at mid-crustaldepths (intraplate model), and the second evaluatesthe simultaneous intrusion of basalt and picrite at mid-crustaldepths and the base of the crust respectively (double-platemodel). The results of the double-plate model accountfor both the inferred metamorphic PT paths of the Kohistanmafic granulites and the continental geotherm determined frompeak PT conditions observed for granulite terranes. Thedouble-plate model may be applicable as a key growth processfor the production of thick mafic lower crust in magmatic arcs. KEY WORDS: thermal model; magmatic underplating; PT path; granulite; lower crust 相似文献
693.
The Significance of Multiple Saturation Points in the Context of Polybaric Near-fractional Melting 总被引:1,自引:0,他引:1
Experimental petrologists have successfully located basalticliquid compositions parental to mid-ocean ridge basalt thatare, within experimental resolution, multiply saturated withthree-phase harzburgite or four-phase lherzolite assemblageson their liquidus at some elevated pressure. Such an experimentalresult is a necessary consequence of any paradigm in which eruptedbasalts derive from single-batch primary liquids that equilibratewith a mantle residue and undergo no subsequent magma mixingbefore differentiation and eruption. Here we investigate whether,conversely, such evidence of multiple saturation is sufficientto exclude dynamic melting models wherein increments of meltare mixed after segregation from residues, during melt transportor in magma chambers. Using two independent models of crystalliquidequilibria to simulate polybaric near-fractional peridotitemelting, we find that aggregate liquids from such melting processescan display near-intersections of liquidus surfaces too closeto distinguish experimentally from exact multiple saturationpoints. Given uncertainties in glass compositions, fractionationcorrections, experimental temperature and pressure conditions,and achievement of equilibrium, these results suggest that polybaricmixtures can in fact masquerade as mantle-equilibrated single-batchprimary liquids. Multiple saturation points on the liquidussurfaces of primitive basalts do, however, preserve informationabout the average pressure of extraction of their constituentincrements of liquid. KEY WORDS: mantle melting; basaltic volcanism; experimental igneous petrology; thermodynamic modelling; inverse method 相似文献
694.
A suite of pyroxenites from the Beni Bousera peridotite massif,northern Morocco, have been analysed for ReOs and LuHfisotopic compositions. Measured sections of the massif indicatethat pyroxenite layers make up between 1 and 9% by volume ofthe total outcrop. Clinopyroxenes from two Cr-diopside pyroxeniteshave unradiogenic Hf isotope compositions ( 相似文献
695.
The Shape and Volume of the Skaergaard Intrusion, Greenland: Implications for Mass Balance and Bulk Composition 总被引:6,自引:0,他引:6
Re-examination of the Skaergaard intrusion in the context ofits regional setting, combined with new data from explorationdrilling, has resulted in a revised structural model for theintrusion. It is modelled as an irregular box, c. 11 km fromnorth to south, up to 8 km from east to west, and 3·44km from the lower to the upper contact. The walls of the intrusionare inferred to follow pre-existing and penecontemporaneoussteep faults, and the floor and roof seem largely controlledby bedding planes in the host sediments and lavas, similar toregional sills. The suggested shape and volume are in agreementwith published gravimetric modelling. Crystallization alongall margins of the intrusion concentrated the evolving meltin the upper, central part of the intrusion, best visualizedas an onion-skin structure inside the box. Thetotal volume is estimated to c. 280 ± 23 km3, of which13·7% are referred to the Upper Border Series (UBS),16·4% to the Marginal Border Series (MBS) and 69·9%to the Layered Series (LS). In the LS, the Lower Zone (LZ) isestimated to constitute 66·8%, the Middle Zone (MZ) 13·5%and the Upper Zone (UZ) 19·7%. The new volume relationshipsprovide a mass balance estimate of the major and trace elementbulk composition of the intrusion. The parental magma to theSkaergaard intrusion is similar to high-Ti East Greenland tholeiiticplateau basalts with Mg number c. 0.45. The intrusion representsthe solidification of contemporary plateau basalt magma trappedand crystallized under closed-system conditions in a crustalreservoir at the developing East Greenland continental margin. KEY WORDS: bulk composition; emplacement; mass proportions; Skaergaard intrusion; structure 相似文献
696.
CLIFFORD TOM N.; BARTON ERIKA S.; STERN RICHARD A.; DUCHESNE JEAN-CLAIR 《Journal of Petrology》2004,45(4):669-691
The O'okiep Copper District is underlain by voluminous 10351210Ma granite gneiss and granite with remnants of metamorphosedsupracrustal rocks. This assemblage was intruded by the 1030Ma copper-bearing Koperberg Suite that includes jotunite, anorthosite,biotite diorite and hypersthene-bearing rocks ranging from leuconoriteto hypersthenite. New sensitive high-resolution ion microprobeage data demonstrate the presence of 17002000 Ma zirconas xenocrysts in all of the intrusive rocks, and as detritalzircon in the metasediments of the Khurisberg Subgroup. Thesedata are consistent with published SmNd model ages ofc. 1700 Ma (TCHUR) and c. 2000 Ma (TDM) of many of the intrusivesthat support a major crust-forming event in Eburnian (Hudsonian)times. In addition, UThPb analyses of zirconsfrom all major rock units define two tectono-magmatic episodesof the Namaquan Orogeny: (1) the O'okiepian Episode (11801210Ma), represented by regional granite plutonism, notably theNababeep and Modderfontein Granite Gneisses and the Concordiaand Kweekfontein Granites that accompanied and outlasted (e.g.Kweekfontein Granite) regional tectonism [F2(D2)] and granulite-faciesmetamorphism (M2); (2) the Klondikean Episode (10201040Ma), which includes the intrusion of the porphyritic RietbergGranite and of the Koperberg Suite that are devoid of regionalplanar or linear fabrics. Klondikean tectonism (D3) is reflectedby major eastwest-trending open folds [F3(D3a)], andby localized eastwest-trending near-vertical ductilefolds [steep structures; F4(D3b)] whose formationwas broadly coeval with the intrusion of the Koperberg Suite.A regional, largely thermal, amphibolite- to granulite-faciesmetamorphism (M3) accompanied D3. This study demonstrates, interalia, that the complete spectrum of rock-types of the KoperbergSuite, together with the Rietberg Granite, was intruded in ashort time-interval (<10 Myr) at c. 1030 Ma, and that therewere lengthy periods of about 150 Myr of tectonic quiescencewithin the Namaquan Orogeny: (1) between the O'okiepian andKlondikean Episodes; (2) from the end of the latter to the formalend of Namaquan Orogenesis 800850 Ma ago. KEY WORDS: UPb, zircon; O'okiep, Namaqualand; granite plutonism; granulite facies; Koperberg Suite; Namaquan (Grenville) Orogeny 相似文献
697.
NEKVASIL H.; DONDOLINI A.; HORN J.; FILIBERTO J.; LONG H.; LINDSLEY D. H. 《Journal of Petrology》2004,45(4):693-721
Experimental simulation of incremental crystal fractionationof a hy-normative hawaiite indicates that the spectrum of compositionsfrom mildly alkalic hawaiite to sodic rhyolite found in silica-saturatedalkalic suites of the ocean islands and continental hotspotsand rifts can be produced by fractionation at 9·3 kbarwith bulk water contents > 相似文献
698.
The basement of Sardinia represents a nearly complete sectionof a segment of the Variscan belt that experienced a polyphasetectono-metamorphic evolution and Barrovian metamorphism. Thisbasement is well suited to investigate the relationship betweentectono-metamorphic evolution and argon isotope records in whitemica. Micaschists from the garnet zone (maximum T of up to 520560°C)contain two texturally and chemically resolvable generationsof white mica: (1) deformed celadonite-rich flakes, defininga relict S1 foliation preserved within the main S2 foliationor enclosed in rotated albite porphyroblasts; (2) celadonite-poorwhite micas aligned along the main S2 foliation. The S1 foliationdeveloped earlier and at a deeper crustal level with respectto that at which the thermal peak was reached. From the staurolitezone (T of up to 590625°C) to the sillimanite + K-feldsparzone, white mica is nearly uniform in composition (muscovite)and is predominantly aligned along the S2 foliation or is oflater crystallization. In situ 40Ar39Ar laser analysesof white mica yielded ages of 相似文献
699.
Mantle Xenoliths from the Southeastern Slave Craton: Evidence for Chemical Zonation in a Thick, Cold Lithosphere 总被引:7,自引:3,他引:7
We present the first data on the petrology of the mantle lithosphereof the Southeastern (SE) Slave craton, Canada. These are basedon petrographic, mineralogical and geochemical studies of mantlexenoliths in Pipe 5034 of the Cambrian Gahcho Kué kimberlitecluster. Major types of mantle xenoliths include altered eclogite,coarse garnet or spinel peridotite, and deformed garnet peridotite.The peridotites belong to the low-temperature suite and formedat T=6001300°C and P= 2580 kbar in a thick(at least 220250 km), cool lithosphere. The SE Slavemantle is cooler than the mantle of other Archaean cratons andthat below other terranes of the Slave craton. The thick lithosphereand the relatively cool thermal regime provide favourable conditionsfor formation and preservation of diamonds beneath the SE Slaveterrane. Similar to average Archaean mantle worldwide, the SESlave peridotite is depleted in magmaphile major elements andcontains olivine with forsterite content of 9193·5.With respect to olivine composition and mode, all terranes ofthe Slave mantle show broadly similar compositions and are relativelyorthopyroxene-poor compared with those of the Kaapvaal and Siberiancratons. The SE Slave spinel peridotite is poorer in Al, Caand Fe, and richer in Mg than deeper garnet peridotite. Thegreater chemical depletion of the shallow upper mantle is typicalof all terranes of the Slave craton and may be common for thesubcontinental lithospheric peridotitic mantle in general. Peridotiticxenoliths of the SE Slave craton were impregnated by kimberliticfluids that caused late-stage recrystallization of primary clinopyroxene,spinel, olivine and spinel-facies orthopyroxene, and formationof interstitial clinopyroxene. This kimberlite-related recrystallizationdepleted primary pyroxenes and spinel in Al. The kimberliticfluid was oxidizing, Ti-, Fe- and K-rich, and Na-poor, and introducedserpentine, chlorite, phlogopite and spinel into peridotitesat P < 35 kbar. KEY WORDS: kimberlite xenolith; lithosphere; mantle terrane; chemical zoning; thermobarometry; Slave craton 相似文献
700.
East African Rift System (EARS) Plume Structure: Insights from Quaternary Mafic Lavas of Turkana, Kenya 总被引:6,自引:2,他引:6
FURMAN TANYA; BRYCE JULIA G.; KARSON JEFFREY; IOTTI ANNAMARIA 《Journal of Petrology》2004,45(5):1069-1088
Quaternary mafic lavas from Lake Turkana (northern Kenya) provideinformation on processes operating beneath the East AfricanRift in an area of anomalous lithospheric and crustal thinning.Inferred depths of melting beneath Turkana (1520 km)are shallower than those recorded elsewhere along the rift,consistent with the anomalously thin crustal section. The maficlavas have elevated incompatible trace element contents whencompared with mid-ocean ridge basalts, requiring an enrichmentevent in the source region. Basalts with low Sr isotopic ratios( 相似文献